Abstract
Poly(ethylene terephthalate) (PET)/carbon black (CB) composite fibers with improved mechanical properties in tensile modulus and tensile strength are prepared by eletrospinning. Stable dispersions suitable for electrospinning are obtained by dispersing melt pre-compounded PET/CB composites in hexafluoroisopropanol. The fiber morphology and CB dispersion are investigated by FESEM and TEM. The addition of CB has no obvious effect on fiber diameter, and the average fiber diameters for all the samples are around 2–3 μm. CB in the fibers is in the form of submicron-sized clusters. The thermal properties of the PET/CB composite fibers are evaluated by DSC, showing almost unchanged melting temperature and crystallinity. Uniaxial tensile tests are used to measure the mechanical properties of the PET/CB composite fiber mats. The fiber mats containing 1 wt%–8.5 wt% CB have significantly improved tensile modulus compared to neat PET fiber mat, showing reinforcing effect of CB. The electrical conductivity of the fiber mats has also been tested.
Similar content being viewed by others
References
Hwang, J., Muth, J. and Ghosh, T., J. Appl. Polym. Sci., 2007, 104(4): 2410
Chuangchote, S., Sirivat, A. and Supaphol, P., Nanotechnology, 2007, 18(14): 145705
Tiwari, M.K., Yarin, A.L. and Megaridis, C.M., J. Appl. Phys., 2008, 103(4): 044305
Im, J.S., Kang, S.C., Lee, S.H. and Lee, Y.S., Carbon, 2010, 48(9): 2573
Im, J.S., Kim, J.G. and Lee, Y.S., Carbon, 2009, 47(11): 2640
Wang, G., Dong, Q., Ling, Z., Pan, C., Yu, C. and Qiu, J.S., J. Mater. Chem., 2012, 22(41): 21819
Sujith, K., Asha, A.M., Anjali, P., Sivakumar, N., Subramanian, K.R.V., Nair, S.V. and Balakrishnan, A., Mater. Lett., 2012, 67(1): 376
Threepopnatkul, P., Murphy, D., Mead, J. and Zukas, W., Rubber. Chem. Technol., 2007, 80(2): 231
Marek, P., Senecal, K., Nida, D., Magnone, J. and Senecal, A., J. Nanobiotechnology, 2011, 9(1): 1
Pedicini, A. and Farris, R.J., J. Polym. Sci., Part B: Polym. Phys., 2004, 42(5): 752
Schiffman, J.D., Blackford, A.C., Wegst, U.G.K. and Schauer, C.L., Carbohyd. Polym., 2011, 84(4): 1252
Kessick, R. and Tepper, G., Sensor. Actuat. B-Chem., 2006, 117(1): 205
Wang, C., Lee, M.F. and Jao, C.H., Eur. Polym. J., 2014, 52: 127
Mazinani, S., Ajji, A. and Dubois, C., J. Polym. Sci., Part B: Polym. Phys., 2010, 48(19): 2052
Chen, H.P., Liu, Z. and Cebe, P., Polymer, 2009, 50(3): 872
Chen, C.Z., Wang, L.G. and Huang, Y., Chem. Eng. J., 2009, 150(1): 269
Ma, Z., Kotaki, M., Yong, T., He, W. and Ramakrishna, S., Biomaterials, 2005, 26(15): 2527
Cai, Y.B., Ke, H.Z., Lin, L., Fei, X.Z., Wei, Q.F., Song, L., Hu, Y. and Fong, H., Energ. Convers. Manage., 2012, 64: 245
Chen, C.Z., Wang, L.G. and Huang, Y., Sol. Energ. Mat. Sol. C., 2008, 92(11): 1382
Hadjizadeh, A., Ajji, A. and Bureau, M.N., J. Mech. Behav. Biomed. Mater., 2011, 4(3): 340
Veleirinho, B., Rei, M.F. and Lopes-DA-Silva, J.A., J. Polym. Sci., Part B: Polym. Phys., 2008, 46(5): 460
ÖZçAm, A.E., Roskov, K.E., Genzer, J. and Spontak, R.J., ACS Appl. Mater. Interfaces, 2012, 4(1): 59
Özçam, A.E., Roskov, K.E., Spontak, R.J. and Genzer, J., J. Mater. Chem., 2012, 22(12): 5855
Chronakis, I.S., Jakob, A., Hagström, B. and Ye, L., Langmuir, 2006, 22(21): 8960
Mckee, M.G., Wilkes, G.L., Colby, R.H. and Long, T.E., Macromolecules, 2004, 37(5): 1760
Chronakis, I.S., Milosevic, B., Frenot, A. and Ye, L., Macromolecules, 2006, 39(1): 357
Wang, C., Lee, M.F. and Wu, Y.J., Macromolecules, 2012, 45(19): 7939
Hunley, M.T., Pötschke, P. and Long, T.E., Macromol. Rapid Commun., 2009, 30(24): 2102
Wang, L., Yan, Y.B., Yang, Q.Q., Yu, J. and Guo, Z.X., J. Mater. Sci., 2012, 47(4): 1702
Ristolainen, N., Heikkilä, P., Harlin, A. and Seppälä, J., Macromol. Mater. Eng., 2006, 291(2): 114
Ji, L., Saquing, C., Khan, S.A. and Zhang, X.W., Nanotechnology, 2008, 19(8): 085605
Sun, Y., Bao, H.D., Guo, Z.X. and Yu, J., Macromolecules, 2008, 42(1): 459
Xiong, Z.Y., Zhang, B.Y., Wang, L., Guo, Z.X. and Yu, J., Carbon, 2014, 70: 233
Lu, J.W., Zhang, Z.P., Ren, X.Z., Chen, Y.Z., Yu, J. and Guo, Z.X., Macromolecules, 2008, 41(11): 3762
Bao, H.D., Guo, Z.X. and Yu, J., Polymer, 2008, 49(17): 3826
Bhardwaj, N. and Kundu, S.C., Biotechnol. Adv., 2010, 28(3): 325
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Xiong, Zy., Kong, Xy., Guo, Zx. et al. Poly(ethylene terephthalate)/carbon black composite fibers prepared by electrospinning. Chin J Polym Sci 33, 1234–1244 (2015). https://doi.org/10.1007/s10118-015-1674-3
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10118-015-1674-3