Skip to main content

Advertisement

Log in

Flash pyrolysis of biomass: a review of recent advances

  • Review
  • Published:
Clean Technologies and Environmental Policy Aims and scope Submit manuscript

Abstract

To assuage global consumer demand for energy, there is a need for increased biofuel production. Flash pyrolysis is an important technique for biomass conversion into eco-friendly biofuels. This review discusses the research progress and key findings made over the years on the flash pyrolysis of biomass. Flash pyrolysis oil yields can be as high as 60–75 wt% at optimised conditions. For the process to be effective, temperature, heating rate and residence time would be within the range of 450–600 °C, \({10}^{3}- {10}^{4}\) °C/s and < 1 s. Flash pyrolysis oil is characterised by high water content (usually > 15 wt%). The main pyrolysis products of lignin part biomass are phenols. The phenolic part includes phenols, hydroxylphenols, meothoxyphenols, dimethoxyphenols. Flash pyrolysis products of biomass (as with other pyrolysis types) must be upgraded before use. They are unstable, re-polymerised and are not miscible with hydrocarbons. The future of the technology is promising as products obtained can serve as better feedstock for other re-refining processes (compared to other pyrolysis process types). Furthermore, it is faster and can handle higher feedstock volumes at similar reactor volumes and process intricacies. Due to the advantages of product yield, it is an important technology that should be explored for energy conversion of biomass and can also serve as a solid waste management technique.

Graphical abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1

Zaman et al. (2017).

Fig. 2

Sun et al. (2010).

Fig. 3
Fig. 4

Similar content being viewed by others

Data Availability

The manuscript has no associated dataset.

References

  • Acikgoz C, Kockar O (2007) Flash pyrolysis of linseed (Linum usitatissimum L.) for production of liquid fuels. J Anal Appl Pyrolysis 78:406–412

    CAS  Google Scholar 

  • Adeniyi AG, Ighalo JO (2020) Computer-aided modeling of thermochemical conversion processes for environmental waste management. In: Hussain CM (ed) Handbook of Environmental Materials Management. Springer, Switzerland

    Google Scholar 

  • Adeniyi AG, Otoikhian KS, Ighalo JO (2019) Steam Reforming of Biomass Pyrolysis Oil: A Review. Int J Chem React Eng. https://doi.org/10.1515/ijcre-2018-032817

    Article  Google Scholar 

  • Adeniyi AG, Ighalo JO, Adeoye AS, Abdulazeez DE (2020) Numerical Investigation of the Effects of Temperature and Biomass Density On the Products Evolution from Wood Pyrolysis Acta Technica Corviniensis - Bulletin of. Engineering 13:73–77

    CAS  Google Scholar 

  • Al Chami Z, Amer N, Smets K, Yperman J, Carleer R, Dumontet S, Vangronsveld J (2014) Evaluation of flash and slow pyrolysis applied on heavy metal contaminated Sorghum bicolor shoots resulting from phytoremediation. Biomass Bioenerg 63:268–279

    CAS  Google Scholar 

  • Alvarez J, Amutio M, Lopez G, Barbarias I, Bilbao J, Olazar M (2015) Sewage sludge valorization by flash pyrolysis in a conical spouted bed reactor. Chem Eng J 273:173–183

    CAS  Google Scholar 

  • Amutio M, Lopez G, Aguado R, Artetxe M, Bilbao J, Olazar M (2011) Effect of vacuum on lignocellulosic biomass flash pyrolysis in a conical spouted bed reactor. Energy Fuels 25:3950–3960

    CAS  Google Scholar 

  • Amutio M, Lopez G, Aguado R, Bilbao J, Olazar M (2012a) Biomass oxidative flash pyrolysis: autothermal operation, yields and product properties. Energy Fuels 26:1353–1362

    CAS  Google Scholar 

  • Amutio M, Lopez G, Artetxe M, Elordi G, Olazar M, Bilbao J (2012b) Influence of temperature on biomass pyrolysis in a conical spouted bed reactor Resources. Conserv Recycl 59:23–31

    Google Scholar 

  • Amutio M, Lopez G, Alvarez J, Moreira R, Duarte G, Nunes J, Olazar M, Bilbao J (2013) Flash pyrolysis of forestry residues from the Portuguese Central Inland Region within the framework of the BioREFINA-Ter project. Bioresour Technol 129:512–518

    CAS  Google Scholar 

  • Burhenne L, Messmer J, Aicher T, Laborie M-P (2013) The effect of the biomass components lignin, cellulose and hemicellulose on TGA and fixed bed pyrolysis. J Anal Appl Pyrolysis 101:177–184

    CAS  Google Scholar 

  • Carmo Freitas Md, Canha N, Martinho M, Almeida-Silva M, Marta S, Pegas P, Alves C, Pio C, Trancoso M, Sousa R, Mouro F, Contreiras T (2011) Indoor air quality in primary schools. In: Moldoveanu A (ed) Advanced topics in environmental health and air pollution case studies. InTech, Chennai

    Google Scholar 

  • Darmstadt H, Garcia-Perez M, Chaala A, Cao N-Z, Roy C (2001) Co-pyrolysis under vacuum of sugar cane bagasse and petroleum residue: properties of the char and activated char products. Carbon 39:815–825

    CAS  Google Scholar 

  • Das P, Sreelatha T, Ganesh A (2004) Bio oil from pyrolysis of cashew nut shell-characterisation and related properties. Biomass Bioenergy 27:265–275

    CAS  Google Scholar 

  • Fahmy TY, Fahmy Y, Mobarak F, El-Sakhawy M, Abou-Zeid RE (2020) Biomass pyrolysis: past, present, and future. Environ Dev Sustain 22:17–32

    Google Scholar 

  • Guida M, Hannioui A (2017) Properties of bio-oil and bio-char produced by sugar cane bagasse pyrolysis in a stainless steel tubular reactor. Prog Agric Eng Sci 13:13–33

    Google Scholar 

  • Heo HS, Park HJ, Park Y-K, Ryu C, Suh DJ, Suh Y-W, Yim J-H, Kim S-S (2010) Bio-oil production from fast pyrolysis of waste furniture sawdust in a fluidized bed. Bioresour Tech 101:S91–S96

    CAS  Google Scholar 

  • Ighalo JO, Adeniyi AG (2021) Modelling the Valorisation of Cassava Peel (Manihot Esculenta) Waste via Pyrolysis and In-line Steam Reforming. Environ Proc 8:267–285

    CAS  Google Scholar 

  • Ighalo JO, Adeniyi AG, Marques G (2020) Application of Linear Regression Algorithm and Stochastic Gradient Descent in Machine Learning Environment for Predicting Biomass Higher Heating Value. Biofuels Bioprod Bioref 14:1286–1295

    CAS  Google Scholar 

  • Ighalo JO, Iwuozor KO, Ogunfowora LA, Abdulsalam A, Iwuchukwu FU, Itabana B, Bright CE, Igwegbe CA (2021) Regenerative desulphurisation of pyrolysis oil: A paradigm for the circular economy initiative. J Environ Chem Eng 9:106864

    CAS  Google Scholar 

  • Imran A, Bramer EA, Seshan K, Brem G (2014) High quality bio-oil from catalytic flash pyrolysis of lignocellulosic biomass over alumina-supported sodium carbonate. Fuel Proc Tech 127:72–79

    CAS  Google Scholar 

  • Imran A, Bramer EA, Seshan K, Brem G (2016) Catalytic flash pyrolysis of biomass using different types of zeolite and online vapor fractionation. Energies 9:187

    Google Scholar 

  • Ingram L, Mohan D, Bricka M, Steele P, Strobel D, Crocker D, Mitchell B, Mohammad J, Cantrell K, Pittman CU Jr (2008) Pyrolysis of wood and bark in an auger reactor: physical properties and chemical analysis of the produced bio-oils. Energy Fuels 22:614–625

    CAS  Google Scholar 

  • Kan T, Strezov V, Evans TJ (2016) Lignocellulosic biomass pyrolysis: a review of product properties and effects of pyrolysis parameters. Renew Sustain Energy Rev 57:1126–1140

    CAS  Google Scholar 

  • Koçkar ÖM, Onay Ö, Pütün AE, Pütün E (2000) Fixed-bed pyrolysis of hazelnut shell: A study on mass transfer limitations on product yields and characterization of the pyrolysis oil. Energy Sour 22:913–924

    Google Scholar 

  • Kumar V, Nanda M (2016) Biomass Pyrolysis-Current status and future directions Energy Sources. Part a: Recovery, Utilization Environ Eff 38:2914–2921

    CAS  Google Scholar 

  • Lédé J (2010) Biomass pyrolysis: comments on some sources of confusions in the definitions of temperatures and heating rates. Energies 3:886–898

    Google Scholar 

  • Lédé J, Blanchard F, Boutin O (2002) Radiant flash pyrolysis of cellulose pellets: products and mechanisms involved in transient and steady state conditions. Fuel 81:1269–1279

    Google Scholar 

  • Lédé J, Broust F, Ndiaye F-T, Ferrer M (2007) Properties of bio-oils produced by biomass fast pyrolysis in a cyclone reactor. Fuel 86:1800–1810

    Google Scholar 

  • Li L, Rowbotham JS, Greenwell CH, Dyer PW (2013) An introduction to pyrolysis and catalytic pyrolysis: versatile techniques for biomass conversion. Elsevier, Amsterdam

    Google Scholar 

  • Madhu P, Kanagasabapathy H, Manickam IN (2016) Cotton shell utilization as a source of biomass energy for bio-oil by flash pyrolysis on electrically heated fluidized bed reactor J Mater Cycles. Waste Manage 18:146–155

    CAS  Google Scholar 

  • Makibar J, Fernandez-Akarregi AR, Amutio M, Lopez G, Olazar M (2015) Performance of a conical spouted bed pilot plant for bio-oil production by poplar flash pyrolysis. Fuel Proc Tech 137:283–289

    CAS  Google Scholar 

  • Maliutina K, Tahmasebi A, Yu J, Saltykov SN (2017) Comparative study on flash pyrolysis characteristics of microalgal and lignocellulosic biomass in entrained-flow reactor energy Convers. Manage 151:426–438

    CAS  Google Scholar 

  • Mani T, Murugan P, Abedi J, Mahinpey N (2010) Pyrolysis of wheat straw in a thermogravimetric analyzer: effect of particle size and heating rate on devolatilization and estimation of global kinetics. Chem Eng Res Des 88:952–958

    CAS  Google Scholar 

  • Marcilla A, León M (2012) García AnN, Bañón E, Martínez P Upgrading of Tannery Wastes under Fast and Slow Pyrolysis Conditions. Ind Eng Chem Res 51:3246–3255

    CAS  Google Scholar 

  • Nyazika T, Jimenez M, Samyn F, Bourbigot S (2019) Pyrolysis modeling, sensitivity analysis, and optimization techniques for combustible materials: a review. J Fire Sci 37:377–433

    Google Scholar 

  • Nzihou A, Stanmore B, Lyczko N, Minh DP (2019) The catalytic effect of inherent and adsorbed metals on the fast/flash pyrolysis of biomass: a review. Energy 170:326–337

    CAS  Google Scholar 

  • Oasmaa A, Kuoppala E, Solantausta Y (2003) Fast pyrolysis of forestry residue. 2. Physicochem Compos Prod Liq Energy Fuels 17:433–443

    CAS  Google Scholar 

  • Onay O, Kockar OM (2003) Slow, fast and flash pyrolysis of rapeseed. Renew Energy 28:2417–2433

    CAS  Google Scholar 

  • Patel A, Agrawal B, Rawal B (2020) Pyrolysis of biomass for efficient extraction of biofuel Energy Sources. Part a: Recovery Utilization Environ Eff 42:1649–1661

    Google Scholar 

  • Pokorna E, Postelmans N, Jenicek P, Schreurs S, Carleer R, Yperman J (2009) Study of bio-oils and solids from flash pyrolysis of sewage sludges. Fuel 88:1344–1350

    CAS  Google Scholar 

  • Raja SA, Kennedy ZR, Pillai B, Lee CLR (2010) Flash pyrolysis of jatropha oil cake in electrically heated fluidized bed reactor. Energy 35:2819–2823

    CAS  Google Scholar 

  • Rogers J, Brammer JG (2012) Estimation of the production cost of fast pyrolysis bio-oil. Biomass Bioenergy 36:208–217

    CAS  Google Scholar 

  • Scott DS, Piskorz J (1982) The flash Pyrolysis of Aspen-Poplar wood. Can J Chem Eng 60:666–674

    CAS  Google Scholar 

  • Shuangning X, Zhihe L, Baoming L, Weiming Y, Xueyuan B (2006) Devolatilization characteristics of biomass at flash heating rate. Fuel 85:664–670

    Google Scholar 

  • Singh YD, Mahanta P, Bora U (2017) Comprehensive characterization of lignocellulosic biomass through proximate, ultimate and compositional analysis for bioenergy production. Renew Energy 103:490–500

    CAS  Google Scholar 

  • Sohaib Q, Muhammad A, Younas M (2017) Fast pyrolysis of sugarcane bagasse: Effect of pyrolysis conditions on final product distribution and properties Energy Sources. Part a: Recovery, Utilization Environ Eff 39:184–190

    CAS  Google Scholar 

  • Sowmya Dhanalakshmi C, Madhu P (2021) Biofuel production of neem wood bark (Azadirachta indica) through flash pyrolysis in a fluidized bed reactor and its chromatographic characterization Energy Sources. Part a: Recovery, Utilization Environ Eff 43:428–443

    CAS  Google Scholar 

  • Stals M, Thijssen E, Vangronsveld J, Carleer R, Schreurs S, Yperman J (2010) Flash pyrolysis of heavy metal contaminated biomass from phytoremediation: influence of temperature, entrained flow and wood/leaves blended pyrolysis on the behaviour of heavy metals. J Anal Appl Pyrolysis 87:1–7

    CAS  Google Scholar 

  • Stephanidis S, Nitsos C, Kalogiannis K, Iliopoulou EF, Lappas AA, Triantafyllidis K (2011) Catalytic upgrading of lignocellulosic biomass pyrolysis vapours: effect of hydrothermal pre-treatment of biomass. Catal Today 167:37–45

    CAS  Google Scholar 

  • Sun S, Tian H, Zhao Y, Sun R, Zhou H (2010) Experimental and numerical study of biomass flash pyrolysis in an entrained flow reactor. Bioresour Tech 101:3678–3684

    CAS  Google Scholar 

  • Tsai W, Lee M, Chang Y (2007) Fast pyrolysis of rice husk: Product yields and compositions. Bioresour Tech 98:22–28

    CAS  Google Scholar 

  • Uddin M, Techato K, Taweekun J, Rahman MM, Rasul M, Mahlia T, Ashrafur S (2018) An overview of recent developments in biomass pyrolysis technologies. Energies 11:3115

    CAS  Google Scholar 

  • Umenweke G, Ighalo JO, Anusi M, Itabana B, Ekeh L (2021) Selected thermo-chemical biorefining: evaluation of the current trends and progressions. Eur J Sustain Devel Res 5:em0154

    Google Scholar 

  • Urban B, Shirazi Y, Maddi B, Viamajala S, Varanasi S (2017) Flash pyrolysis of oleaginous biomass in a fluidized-bed reactor. Energy Fuels 31:8326–8334

    CAS  Google Scholar 

  • Uzun BB, Sarioğlu N (2009) Rapid and catalytic pyrolysis of corn stalks. Fuel Proc Tech 90:705–716

    CAS  Google Scholar 

  • Varma AK, Mondal P (2017) Pyrolysis of sugarcane bagasse in semi batch reactor: effects of process parameters on product yields and characterization of products. Ind Crops Prod 95:704–717

    CAS  Google Scholar 

  • Wang J, Zhang M, Chen M, Min F, Zhang S, Ren Z, Yan Y (2006) Catalytic effects of six inorganic compounds on pyrolysis of three kinds of biomass. Thermochim Acta 444:110–114

    CAS  Google Scholar 

  • Xu R, Ferrante L, Briens C, Berruti F (2011) Bio-oil production by flash pyrolysis of sugarcane residues and post treatments of the aqueous phase. J Anal Appl Pyrolysis 91:263–272

    CAS  Google Scholar 

  • Zaman CZ, Pal K, Yehye WA, Sagadevan S, Shah ST, Adebisi GA, Marliana E, Rafique RF, Johan RB (2017) Pyrolysis: a sustainable way to generate energy from waste vol 1. IntechOpen Rijeka, Croatia.

  • Zhang H, Xiao R, Huang H, Xiao G (2009) Comparison of non-catalytic and catalytic fast pyrolysis of corncob in a fluidized bed reactor. Biores Technol 100:1428–1434

    CAS  Google Scholar 

Download references

Acknowledgements

We acknowledge the researchers in the research area who have published important papers over time to advance knowledge.

Funding

There was no external funding for the study.

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Joshua O. Ighalo or Chinenye Adaobi Igwegbe.

Ethics declarations

Conflict of interest

The authors declare that there are no conflicts of interest.

Ethical Approval

This article does not contain any studies involving human or animal subjects.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ighalo, J.O., Iwuchukwu, F.U., Eyankware, O.E. et al. Flash pyrolysis of biomass: a review of recent advances. Clean Techn Environ Policy 24, 2349–2363 (2022). https://doi.org/10.1007/s10098-022-02339-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10098-022-02339-5

Keywords

Navigation