Abstract
To assuage global consumer demand for energy, there is a need for increased biofuel production. Flash pyrolysis is an important technique for biomass conversion into eco-friendly biofuels. This review discusses the research progress and key findings made over the years on the flash pyrolysis of biomass. Flash pyrolysis oil yields can be as high as 60–75 wt% at optimised conditions. For the process to be effective, temperature, heating rate and residence time would be within the range of 450–600 °C, \({10}^{3}- {10}^{4}\) °C/s and < 1 s. Flash pyrolysis oil is characterised by high water content (usually > 15 wt%). The main pyrolysis products of lignin part biomass are phenols. The phenolic part includes phenols, hydroxylphenols, meothoxyphenols, dimethoxyphenols. Flash pyrolysis products of biomass (as with other pyrolysis types) must be upgraded before use. They are unstable, re-polymerised and are not miscible with hydrocarbons. The future of the technology is promising as products obtained can serve as better feedstock for other re-refining processes (compared to other pyrolysis process types). Furthermore, it is faster and can handle higher feedstock volumes at similar reactor volumes and process intricacies. Due to the advantages of product yield, it is an important technology that should be explored for energy conversion of biomass and can also serve as a solid waste management technique.
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References
Acikgoz C, Kockar O (2007) Flash pyrolysis of linseed (Linum usitatissimum L.) for production of liquid fuels. J Anal Appl Pyrolysis 78:406–412
Adeniyi AG, Ighalo JO (2020) Computer-aided modeling of thermochemical conversion processes for environmental waste management. In: Hussain CM (ed) Handbook of Environmental Materials Management. Springer, Switzerland
Adeniyi AG, Otoikhian KS, Ighalo JO (2019) Steam Reforming of Biomass Pyrolysis Oil: A Review. Int J Chem React Eng. https://doi.org/10.1515/ijcre-2018-032817
Adeniyi AG, Ighalo JO, Adeoye AS, Abdulazeez DE (2020) Numerical Investigation of the Effects of Temperature and Biomass Density On the Products Evolution from Wood Pyrolysis Acta Technica Corviniensis - Bulletin of. Engineering 13:73–77
Al Chami Z, Amer N, Smets K, Yperman J, Carleer R, Dumontet S, Vangronsveld J (2014) Evaluation of flash and slow pyrolysis applied on heavy metal contaminated Sorghum bicolor shoots resulting from phytoremediation. Biomass Bioenerg 63:268–279
Alvarez J, Amutio M, Lopez G, Barbarias I, Bilbao J, Olazar M (2015) Sewage sludge valorization by flash pyrolysis in a conical spouted bed reactor. Chem Eng J 273:173–183
Amutio M, Lopez G, Aguado R, Artetxe M, Bilbao J, Olazar M (2011) Effect of vacuum on lignocellulosic biomass flash pyrolysis in a conical spouted bed reactor. Energy Fuels 25:3950–3960
Amutio M, Lopez G, Aguado R, Bilbao J, Olazar M (2012a) Biomass oxidative flash pyrolysis: autothermal operation, yields and product properties. Energy Fuels 26:1353–1362
Amutio M, Lopez G, Artetxe M, Elordi G, Olazar M, Bilbao J (2012b) Influence of temperature on biomass pyrolysis in a conical spouted bed reactor Resources. Conserv Recycl 59:23–31
Amutio M, Lopez G, Alvarez J, Moreira R, Duarte G, Nunes J, Olazar M, Bilbao J (2013) Flash pyrolysis of forestry residues from the Portuguese Central Inland Region within the framework of the BioREFINA-Ter project. Bioresour Technol 129:512–518
Burhenne L, Messmer J, Aicher T, Laborie M-P (2013) The effect of the biomass components lignin, cellulose and hemicellulose on TGA and fixed bed pyrolysis. J Anal Appl Pyrolysis 101:177–184
Carmo Freitas Md, Canha N, Martinho M, Almeida-Silva M, Marta S, Pegas P, Alves C, Pio C, Trancoso M, Sousa R, Mouro F, Contreiras T (2011) Indoor air quality in primary schools. In: Moldoveanu A (ed) Advanced topics in environmental health and air pollution case studies. InTech, Chennai
Darmstadt H, Garcia-Perez M, Chaala A, Cao N-Z, Roy C (2001) Co-pyrolysis under vacuum of sugar cane bagasse and petroleum residue: properties of the char and activated char products. Carbon 39:815–825
Das P, Sreelatha T, Ganesh A (2004) Bio oil from pyrolysis of cashew nut shell-characterisation and related properties. Biomass Bioenergy 27:265–275
Fahmy TY, Fahmy Y, Mobarak F, El-Sakhawy M, Abou-Zeid RE (2020) Biomass pyrolysis: past, present, and future. Environ Dev Sustain 22:17–32
Guida M, Hannioui A (2017) Properties of bio-oil and bio-char produced by sugar cane bagasse pyrolysis in a stainless steel tubular reactor. Prog Agric Eng Sci 13:13–33
Heo HS, Park HJ, Park Y-K, Ryu C, Suh DJ, Suh Y-W, Yim J-H, Kim S-S (2010) Bio-oil production from fast pyrolysis of waste furniture sawdust in a fluidized bed. Bioresour Tech 101:S91–S96
Ighalo JO, Adeniyi AG (2021) Modelling the Valorisation of Cassava Peel (Manihot Esculenta) Waste via Pyrolysis and In-line Steam Reforming. Environ Proc 8:267–285
Ighalo JO, Adeniyi AG, Marques G (2020) Application of Linear Regression Algorithm and Stochastic Gradient Descent in Machine Learning Environment for Predicting Biomass Higher Heating Value. Biofuels Bioprod Bioref 14:1286–1295
Ighalo JO, Iwuozor KO, Ogunfowora LA, Abdulsalam A, Iwuchukwu FU, Itabana B, Bright CE, Igwegbe CA (2021) Regenerative desulphurisation of pyrolysis oil: A paradigm for the circular economy initiative. J Environ Chem Eng 9:106864
Imran A, Bramer EA, Seshan K, Brem G (2014) High quality bio-oil from catalytic flash pyrolysis of lignocellulosic biomass over alumina-supported sodium carbonate. Fuel Proc Tech 127:72–79
Imran A, Bramer EA, Seshan K, Brem G (2016) Catalytic flash pyrolysis of biomass using different types of zeolite and online vapor fractionation. Energies 9:187
Ingram L, Mohan D, Bricka M, Steele P, Strobel D, Crocker D, Mitchell B, Mohammad J, Cantrell K, Pittman CU Jr (2008) Pyrolysis of wood and bark in an auger reactor: physical properties and chemical analysis of the produced bio-oils. Energy Fuels 22:614–625
Kan T, Strezov V, Evans TJ (2016) Lignocellulosic biomass pyrolysis: a review of product properties and effects of pyrolysis parameters. Renew Sustain Energy Rev 57:1126–1140
Koçkar ÖM, Onay Ö, Pütün AE, Pütün E (2000) Fixed-bed pyrolysis of hazelnut shell: A study on mass transfer limitations on product yields and characterization of the pyrolysis oil. Energy Sour 22:913–924
Kumar V, Nanda M (2016) Biomass Pyrolysis-Current status and future directions Energy Sources. Part a: Recovery, Utilization Environ Eff 38:2914–2921
Lédé J (2010) Biomass pyrolysis: comments on some sources of confusions in the definitions of temperatures and heating rates. Energies 3:886–898
Lédé J, Blanchard F, Boutin O (2002) Radiant flash pyrolysis of cellulose pellets: products and mechanisms involved in transient and steady state conditions. Fuel 81:1269–1279
Lédé J, Broust F, Ndiaye F-T, Ferrer M (2007) Properties of bio-oils produced by biomass fast pyrolysis in a cyclone reactor. Fuel 86:1800–1810
Li L, Rowbotham JS, Greenwell CH, Dyer PW (2013) An introduction to pyrolysis and catalytic pyrolysis: versatile techniques for biomass conversion. Elsevier, Amsterdam
Madhu P, Kanagasabapathy H, Manickam IN (2016) Cotton shell utilization as a source of biomass energy for bio-oil by flash pyrolysis on electrically heated fluidized bed reactor J Mater Cycles. Waste Manage 18:146–155
Makibar J, Fernandez-Akarregi AR, Amutio M, Lopez G, Olazar M (2015) Performance of a conical spouted bed pilot plant for bio-oil production by poplar flash pyrolysis. Fuel Proc Tech 137:283–289
Maliutina K, Tahmasebi A, Yu J, Saltykov SN (2017) Comparative study on flash pyrolysis characteristics of microalgal and lignocellulosic biomass in entrained-flow reactor energy Convers. Manage 151:426–438
Mani T, Murugan P, Abedi J, Mahinpey N (2010) Pyrolysis of wheat straw in a thermogravimetric analyzer: effect of particle size and heating rate on devolatilization and estimation of global kinetics. Chem Eng Res Des 88:952–958
Marcilla A, León M (2012) García AnN, Bañón E, Martínez P Upgrading of Tannery Wastes under Fast and Slow Pyrolysis Conditions. Ind Eng Chem Res 51:3246–3255
Nyazika T, Jimenez M, Samyn F, Bourbigot S (2019) Pyrolysis modeling, sensitivity analysis, and optimization techniques for combustible materials: a review. J Fire Sci 37:377–433
Nzihou A, Stanmore B, Lyczko N, Minh DP (2019) The catalytic effect of inherent and adsorbed metals on the fast/flash pyrolysis of biomass: a review. Energy 170:326–337
Oasmaa A, Kuoppala E, Solantausta Y (2003) Fast pyrolysis of forestry residue. 2. Physicochem Compos Prod Liq Energy Fuels 17:433–443
Onay O, Kockar OM (2003) Slow, fast and flash pyrolysis of rapeseed. Renew Energy 28:2417–2433
Patel A, Agrawal B, Rawal B (2020) Pyrolysis of biomass for efficient extraction of biofuel Energy Sources. Part a: Recovery Utilization Environ Eff 42:1649–1661
Pokorna E, Postelmans N, Jenicek P, Schreurs S, Carleer R, Yperman J (2009) Study of bio-oils and solids from flash pyrolysis of sewage sludges. Fuel 88:1344–1350
Raja SA, Kennedy ZR, Pillai B, Lee CLR (2010) Flash pyrolysis of jatropha oil cake in electrically heated fluidized bed reactor. Energy 35:2819–2823
Rogers J, Brammer JG (2012) Estimation of the production cost of fast pyrolysis bio-oil. Biomass Bioenergy 36:208–217
Scott DS, Piskorz J (1982) The flash Pyrolysis of Aspen-Poplar wood. Can J Chem Eng 60:666–674
Shuangning X, Zhihe L, Baoming L, Weiming Y, Xueyuan B (2006) Devolatilization characteristics of biomass at flash heating rate. Fuel 85:664–670
Singh YD, Mahanta P, Bora U (2017) Comprehensive characterization of lignocellulosic biomass through proximate, ultimate and compositional analysis for bioenergy production. Renew Energy 103:490–500
Sohaib Q, Muhammad A, Younas M (2017) Fast pyrolysis of sugarcane bagasse: Effect of pyrolysis conditions on final product distribution and properties Energy Sources. Part a: Recovery, Utilization Environ Eff 39:184–190
Sowmya Dhanalakshmi C, Madhu P (2021) Biofuel production of neem wood bark (Azadirachta indica) through flash pyrolysis in a fluidized bed reactor and its chromatographic characterization Energy Sources. Part a: Recovery, Utilization Environ Eff 43:428–443
Stals M, Thijssen E, Vangronsveld J, Carleer R, Schreurs S, Yperman J (2010) Flash pyrolysis of heavy metal contaminated biomass from phytoremediation: influence of temperature, entrained flow and wood/leaves blended pyrolysis on the behaviour of heavy metals. J Anal Appl Pyrolysis 87:1–7
Stephanidis S, Nitsos C, Kalogiannis K, Iliopoulou EF, Lappas AA, Triantafyllidis K (2011) Catalytic upgrading of lignocellulosic biomass pyrolysis vapours: effect of hydrothermal pre-treatment of biomass. Catal Today 167:37–45
Sun S, Tian H, Zhao Y, Sun R, Zhou H (2010) Experimental and numerical study of biomass flash pyrolysis in an entrained flow reactor. Bioresour Tech 101:3678–3684
Tsai W, Lee M, Chang Y (2007) Fast pyrolysis of rice husk: Product yields and compositions. Bioresour Tech 98:22–28
Uddin M, Techato K, Taweekun J, Rahman MM, Rasul M, Mahlia T, Ashrafur S (2018) An overview of recent developments in biomass pyrolysis technologies. Energies 11:3115
Umenweke G, Ighalo JO, Anusi M, Itabana B, Ekeh L (2021) Selected thermo-chemical biorefining: evaluation of the current trends and progressions. Eur J Sustain Devel Res 5:em0154
Urban B, Shirazi Y, Maddi B, Viamajala S, Varanasi S (2017) Flash pyrolysis of oleaginous biomass in a fluidized-bed reactor. Energy Fuels 31:8326–8334
Uzun BB, Sarioğlu N (2009) Rapid and catalytic pyrolysis of corn stalks. Fuel Proc Tech 90:705–716
Varma AK, Mondal P (2017) Pyrolysis of sugarcane bagasse in semi batch reactor: effects of process parameters on product yields and characterization of products. Ind Crops Prod 95:704–717
Wang J, Zhang M, Chen M, Min F, Zhang S, Ren Z, Yan Y (2006) Catalytic effects of six inorganic compounds on pyrolysis of three kinds of biomass. Thermochim Acta 444:110–114
Xu R, Ferrante L, Briens C, Berruti F (2011) Bio-oil production by flash pyrolysis of sugarcane residues and post treatments of the aqueous phase. J Anal Appl Pyrolysis 91:263–272
Zaman CZ, Pal K, Yehye WA, Sagadevan S, Shah ST, Adebisi GA, Marliana E, Rafique RF, Johan RB (2017) Pyrolysis: a sustainable way to generate energy from waste vol 1. IntechOpen Rijeka, Croatia.
Zhang H, Xiao R, Huang H, Xiao G (2009) Comparison of non-catalytic and catalytic fast pyrolysis of corncob in a fluidized bed reactor. Biores Technol 100:1428–1434
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Ighalo, J.O., Iwuchukwu, F.U., Eyankware, O.E. et al. Flash pyrolysis of biomass: a review of recent advances. Clean Techn Environ Policy 24, 2349–2363 (2022). https://doi.org/10.1007/s10098-022-02339-5
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DOI: https://doi.org/10.1007/s10098-022-02339-5