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Oleogel classification, physicochemical characterization methods, and typical cases of application in food: a review

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Abstract

The harmful effects of trans and saturated fatty acids have attracted worldwide attention. Edible oleogels, which can structure liquid oils, are promising healthy alternatives to traditional fats. Active research on oleogels is focused on the interaction between unsaturated oils with different fatty acid compositions and low molecular weight or polymer oleogels. The unique network structure inside oleogels has facilitated their application in candies, spreads, meat, and other products. However, the micro- and macro-properties, as well as the functional properties of oleogels vary by preparation method and the system composition. This review discusses the characteristics of oleogels, serving as a reference for the application of oleogels in food products. Specifically, it (i) classifies oleogels and explains the influence of gelling factors on their gelation, (ii) describes the methods for measuring the physicochemical properties of oleogels, and (iii) discusses the current applications of oleogels in food products.

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Abbreviations

3D:

Three-dimensional

3ITT:

Three-interval thixotropy test

AFM:

Atomic force microscopy

BW:

Beeswax

BWO:

Beeswax oleogel

CA:

Cluster analysis

CB:

Cocoa butter

CW:

Carnauba wax

CWO:

Carnauba wax oleogel

Cryo-TEM:

Cryo-transmission electron microscopy

DFA:

Discriminant factor analysis

EC:

Ethyl cellulose

ECO:

Ethyl cellulose oleogel

FTIR:

Fourier transform infrared spectroscopy

G′:

Storage modulus

G′′:

Loss modulus

HMWPO:

High molecular weight polymer oleogel

HPMC:

Hydroxypropyl methyl cellulose

LDA:

Linear discriminant analysis

LMMWO:

Low multicomponent/composite molecular weight oleogel

LMWO:

Low molecular weight oleogel

LSMWO:

Low single molecular weight oleogel

MAG:

Monoacylglycerol

MAGO:

Monoacylglycerol oleogel

MO:

Monoglyceryl stearate oleogel

Mw:

Molecular weight

OBC:

Oil binding capacity

p-AV:

p-Anisidine value

PCA:

Principal component analysis

PLM:

Polarized light microscopy

pNMR:

Proton nuclear magnetic resonance spectroscopy

PV:

Peroxide value

P/Y:

Phytosterol + γ-oryzanol

RBW:

Rice bran wax

S/L:

β-Sitosterol + lecithin

S/LO:

β-Sitosterol + lecithin oleogel

SEM:

Scanning electron microscopy

SFA:

Saturated fatty acid

SAXS:

Small-angle X-ray scattering

SW:

Sunflower wax

TAG:

Triglyceride

TBARS:

Thiobarbituric acid-reactive substances

TFA:

Trans Fatty acid

TPA:

Texture profile analysis

XRD:

X-ray diffraction

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Acknowledgements

The authors acknowledge the support of the “Key R&D Program of the Northeast Cold Region Beef Cattle Science and Technology Innovation Engineering Research Center” through Project 111 (Project no. D20034).

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The authors confirm that this manuscript has not been published elsewhere and is not under consideration by any other journal. The authors have no potential conflicts of interest to disclose.

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Correspondence to Hua Zhang or Jong-Bang Eun.

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Qiu, H., Zhang, H. & Eun, JB. Oleogel classification, physicochemical characterization methods, and typical cases of application in food: a review. Food Sci Biotechnol 33, 1273–1293 (2024). https://doi.org/10.1007/s10068-023-01501-z

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