Abstract
The fabrication and characterisation of potentiometric chalcogenide glass electrodes with selectivity for iodide in aqueous media are reported. While such probes are already known for the determination of a number of cations using various fabrication technologies, this is not yet the case for anions. Specifically, the fabrication process of the novel glasses and their investigation by means of a number of physico-chemical methods as well as their fabrication into usable sensors and their testing are described.
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References
Mikhelson KN (2013) Ion-selective electrodes. Springer, Berlin, Heidelberg
Eisenman G (ed) (1967) Glass electrodes for hydrogen and other cations. Dekker, New York
Baker CT, Trachtenberg I (1971) Ion-selective electrochemical sensors - Fe3+, Cu2+. J Electrochem Soc 118:571–576
Kratz L (1950) Die Glaselektrode und ihre Anwendungen. D. Steinkopff, Darmstadt
Lai CZ, Joyer MM, Fierke MA, Petkovich ND, Stein A, Bühlmann P (2009) Subnanomolar detection limit application of ion-selective electrodes with three-dimensionally ordered macroporous (3DOM) carbon solid contacts. J Solid State Electrochem 13:123–128
Yin T, Pan D, Qin W (2012) A solid-contact Pb2+-selective polymeric membrane electrode with Nafion-doped poly(pyrrole) as ion-to-electron transducer. J Solid State Electrochem 16:499–504
Ansari R, Delavar AF, Mohammad-khah A (2012) Solid-state ion selective electrode based on polypyrrole conducting polymer nanofilm as a new potentiometric sensor for Zn2+ ion. J Solid State Electrochem 16:3315–3322
Shvedene NV, Abashev MN, Arakelyan SA, Otkidach KN, Tomilova LG, Pletneval IV (2019) Highly selective solid-state sensor for iodide based on the combined use of platinum (IV) phthalocyanine and solidified pyridinium ionic liquid. J Solid State Electrochem 23:543–552
Vonau W, Gabel J, Jahn H (2005) Potentiometric all solid-state pH glass sensors. Electrochimica Acta 50:4981–4987
Shultz MM, Pisarevskii AM, Volkov SE, Artemjev JM, Nilolaev JI (1981) Elektrod, Sostavlennyi is steklo s ionnoi i ionno-elektronnoi provodimostyami. Fizika I Khimiya Stekla 7:426–432
Vonau W, Gerlach F, Ahlborn K (2013) Glass-based redox sensor. J Solid State Electrochem 17:969–976
König C (1993) Entwicklung und Charakterisierung einer Chalkogenidglas-Elektrode zur Detektion von Eisen(III)ionen. PhD Thesis, Frankfurt/ Main
Schubert J, Schöning MJ, Schmidt C, Siegert M, Mesters S, Zander W, Koprdos P, Lüth H, Legin A, Mourzina YG, Seleznev B (1999) Chalcogenide-based thin film sensors prepared by pulsed laser deposition technique. Appl Phys A 69:803–805
Enseleit U, Berthold M, Feller C, Partsch U, Körner S, Vonau W (2018) Chalcogenide glass based heavy metal sensors. Sens Transducers 219:1–8
Vlasov YG, Bychkov EA (1987) Electrochemical ion-selective sensors based on chalcogenide glasses. Sens Actuators 12:275–283
Vlasov YG, Moskvin LN, Bychkov EA, Golikov DV (1989) Silver bromide based chalcogenide glassy-crystalline ion-selective electrodes. Analyst 114:185–190
Miloshova M, Bychkov E, Tsegelnik V, V. Strykanov V, Klewe-Nebenius H, Bruns M, Hoffmann W, Papet P, Sarradin J, Pradel A, Ribes M, (1999) Tracer and surface spectroscopy studies of sensitivity mechanism of mercury ion chalcogenide glass sensors. Sens Actuators B 57:171–178
Schöning MJ, Kloock JP (2007) About 20 years of silicon-based thin-film sensors with chalcogenide glass materials for heavy metal analysis: technological aspects of fabrication and miniaturisation. Electroanalytics 19:2029–2038
Vlasov YG, Bychkov EA, Medvedev AM (1986) Copper ion-selective chalcogenide glass electrodes: analytical characteristics and sensing mechanism. Anal Chim Acta 185:137–158
Vlasov YG, Bychkov EA, Legin AV (1992) Mechanism studies on lead ion-selective chalcogenide glass sensors. Sens Actuators B 10:55–60
Funding
The presented work is based on a project supported by the Federal Ministry of Economic Affairs and Energy (BMWi) through the German Federation of Industrial Research Associations “Otto von Guericke” e.V. (AiF) within the program “Zentrales Innovations programm Mittelstand” (ZIM) cooperation, grant number ZF 4088707AW9. Both institutes are co-financed by tax funds on the basis of the budget passed by the Saxon State Parliament.
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Enseleit, U., Feller, C., Partsch, U. et al. Iodide determination with chalcogenide glass electrodes. J Solid State Electrochem 25, 2293–2300 (2021). https://doi.org/10.1007/s10008-021-05000-1
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DOI: https://doi.org/10.1007/s10008-021-05000-1