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An overview of degradation in solid oxide fuel cells-potential clean power sources

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Abstract

Solid oxide fuel cells (SOFCs) have emerged as the potential power generating devices, being profoundly effective, biofuel-based, and causing negligible harm to the environment. The commercialization of this device would introduce a new revolution in the field of electronic devices and power age. The performance of SOFCs is subject to the efficient working of its significant segments like anode, cathode, electrolyte, interconnect, and sealant. The mechanism of working of a SOFC, the kinetics and thermodynamics involved, as well as the composition of the fuel utilized are other vital variables in-charge of the performance of SOFCs. The serious issue with these devices has been the degradation of the components at high temperatures because of both intrinsic and extrinsic factors. Plenty of researchers have attempted to address this issue of degradation. Despite the fact that there are a large number of articles and reviews on corrosion, very few comprehensive reports have been published. In this review, various aspects of degradation have been covered including the mechanism, remedies, and alternatives as proposed by various researchers. It is a comprehensive review of degradation in SOFCs covering the most recent advances in the study of degradation and its mitigation measures.

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Abbreviations

XPS:

X-ray photoelectron spectroscopy

AFM:

Atomic force microscopic

TEM:

Transmission electron microscopy

EDS:

Energy dispersive spectroscopy

SOFC:

Solid oxide fuel cells

Liq.:

Liquid

TPB:

Triple phase boundary

XRD:

X-ray diffraction

ASR:

Area specific resistance

IT:

Intermediate temperature

Atm p:

Atmospheric pressure

↑:

Increases

SEM:

Scanning electron microscope

YCSB:

Yttria-ceria double- doped bismuth oxide

EIS:

Electrochemical impedance spectra

LT:

Low temperature

SYN:

Strontium yttrium nickel

Conc.:

Concentration

SSZ:

Scandia-stabilized zirconia

YSZ:

Yttria-stabilized zirconia

GDC:

Gadolinia-Doped Ceria

IGCC:

Integrated gasification combined cycle

YDC:

Yttria-doped ceria

SDC:

Samarium-doped ceria

ORR:

Oxygen reduction reaction

T:

Temperature

P:

Pressure

Rxn.:

Reaction

↓:

Decreases

EPMA:

Electron probe micro analyzer

OCV:

Open circuit voltage

EDX:

Energy dispersive X- ray analysis

MPD:

Maximum power density

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Acknowledgments

The authors would like to thank Council of Scientific and Industrial Research (CSIR), Govt. of India and BITS Pilani Hyderabad Campus for their support.

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  1. Department of Chemical Engineering, BITS Pilani Hyderabad Campus, Hyderabad, 500078, India

    I. Sreedhar, Bhawana Agarwal, Priyanka Goyal & Ankita Agarwal

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Sreedhar, I., Agarwal, B., Goyal, P. et al. An overview of degradation in solid oxide fuel cells-potential clean power sources. J Solid State Electrochem 24, 1239–1270 (2020). https://doi.org/10.1007/s10008-020-04584-4

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