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Effect of crystallinity on capacity and cyclic stability of Na1.1V3O7.9 nanoplates as lithium-ion cathode materials

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Abstract

High-crystalline Na1.1V3O7.9 nanoplates were synthesized by a facile sol-gel reaction followed by calcination. The microstructure and crystallinity of the nanoplates were primarily determined by calcination temperature. The maximum crystallinity Na1.1V3O7.9 sample was calcined at 500 °C was calculated by XRD, and the DSC demonstrated that the amorphous transformation temperature begins at 550 °C. The XPS spectrum confirmed the presence of Na1.1V3O7.9 and consistent with the XRD test results. The SEM/TEM test illustrated the crystal particle growth of the Na1.1V3O7.9 nanoplates. Electrochemical results showed that the maximum crystallinity Na1.1V3O7.9 sample prepared at 500 °C exhibited the optimum performance when evaluated as a cathode material for lithium-ion batteries: the discharge capacity was maintained at 195 mAh g−1 after 150 cycles at a current of 100 mA g−1.

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Funding

This work was supported by the Natural Science Foundation of Shandong Province (ZR2018LE003).

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Authors and Affiliations

  1. Key Laboratory of Processing and Testing Technology of Glass & Functional Ceramics of Shandong Province, School of Material Science and Engineering, QiLu University of Technology (Shandong Academy of Sciences), Jinan, 250353, People’s Republic of China

    Huifeng Zhuang, Yue Xu & Ping Zhao

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  1. Huifeng Zhuang
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  2. Yue Xu
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  3. Ping Zhao
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Correspondence to Yue Xu or Ping Zhao.

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Zhuang, H., Xu, Y. & Zhao, P. Effect of crystallinity on capacity and cyclic stability of Na1.1V3O7.9 nanoplates as lithium-ion cathode materials. J Solid State Electrochem 24, 217–223 (2020). https://doi.org/10.1007/s10008-019-04482-4

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