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Three-dimensional ZnS/reduced graphene oxide/polypyrrole composite for high-performance supercapacitors and lithium-ion battery electrode material

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Abstract

In this work, three-dimensional ZnS/reduced graphene oxide/polypyrrole ternary composites were synthesized. The as-prepared composites are investigated as electrode materials for supercapacitors and lithium-ion batteries. For the application of supercapacitor in three electrode system, its discharge specific capacitance and energy density at 1 A/g are 1175.8 F/g and 80.0 Wh/kg after 5000 cycles, respectively. Meanwhile, its cycle stability at 1 A/g is up to 151% during 5000 loops. For the application of lithium-ion battery, its discharge specific capacitance and energy density at 100 mA/g can be up to 1446.9 mAh/g and 955.6 Wh/kg after 200 cycles, respectively. The cycle stability of the ternary composite is up to 157% at 100 mA/g during 200 loops. The excellent electrochemical performance of the composites could be ascribed to the three-dimensional structure which facilitates the penetration of the electrolyte and the insertion/extraction process of Li+ and the synergistic effect between organic and inorganic materials. The results indicate that the ZnS/reduced graphene oxide/polypyrrole composite are promising electrode materials for high-performance supercapacitors and lithium-ion batteries.

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Funding

This work was supported by the National Natural Science Foundation of China (Nos. 21403130; 21403129; 21576158), the Natural Science Foundation of Shandong Province (ZR2014BQ028, 2015ZRB01765).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Shandong University of Technology, Zibo, 255000, People’s Republic of China

    Zichen Xu, Zhiqiang Zhang, Mingyu Li, Huiling Yin, Hongtao Lin, Jin Zhou & Shuping Zhuo

Authors
  1. Zichen Xu
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  2. Zhiqiang Zhang
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  3. Mingyu Li
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  4. Huiling Yin
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  5. Hongtao Lin
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  6. Jin Zhou
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  7. Shuping Zhuo
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Correspondence to Hongtao Lin.

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Supporting Information

The characterization information and preparation of pristine materials. The Energy Dispersive Spectrometer (EDS) images of ZnS/RGO/PPy-70. The SEM images of ZnS/RGO/PPy-x (x = 30, 50, 70, and 90, x represents the mass ratio of PPy). The electrochemical performance of ZnS/RGO/PPy-x include CV curves at 5 mV/s, GCD plots at 1 A/g and Nyquist plots from 100 kHz to 0.01 Hz for application of SCs. The Nyquist plots of the different cycles of ZnS/RGO/PPy-70 electrode for application for LIBs, and calculate the effective capacitance value through the EIS data.

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Xu, Z., Zhang, Z., Li, M. et al. Three-dimensional ZnS/reduced graphene oxide/polypyrrole composite for high-performance supercapacitors and lithium-ion battery electrode material. J Solid State Electrochem 23, 3419–3428 (2019). https://doi.org/10.1007/s10008-019-04434-y

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  • DOI: https://doi.org/10.1007/s10008-019-04434-y

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