Abstract
The self-assembled hierarchical MnCO3/MWCNT nanoarchitectures are prepared by a facile solvothermal method and used as anode material for lithium-ion batteries. The results of SEM and TEM show that the hierarchical nanorods are made of the primary MnCO3 nanocrystals. The hierarchical nanorods MnCO3 are heterogeneously distributed among retiform MWCNTs. Those MnCO3/MWCNT nanoarchitectures are able to buffer the physical aggregation of the MnCO3 nanorods and volume expansion of MnCO3 in the charge/discharge process. The self-assembled hierarchical MnCO3/MWCNT nanocomposite delivers a reversible capacity of 704 mAh g−1 after 110 cycles at a current density of 100 mA g−1. The excellent electrochemical performance is attributed to the self-assembled hierarchical MnCO3/MWCNT nanoarchitectures and the high conductivity of MWCNTs.
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Jin RC, Jiang H, Sun YX (2016) Fabrication of NiFe2O4 /C hollow spheres constructed by mesoporous nanospheres for high performance lithium-ion batteries. Chem Eng J 303:501–510
Yu L, Guan BY, Xiao W (2015) Formation of yolk-shelled Ni–Co mixed oxide nanoprisms with enhanced electrochemical performance for hybrid supercapacitors and lithium ion batteries. Adv Energy Mater 5:1500981
Jin RC, Ma YQ, Sun YX (2017) Manganese cobalt oxide (MnCo2O4) hollow spheres as high capacity anode materials for lithium-ion batteries. Energy Technol 5(2):293–299
Jin RC, Wang QY, Cui YM (2017) MFe2O4 (M ¼ Ni, Co) Nanoparticles anchored on amorphous carboncoated multiwalled carbon nanotubes as anode materials for lithiumion batteries. Carbon 123:448–459
Abbas SM, Ali S, Niaz NA (2014) Superior electrochemical performance of mesoporous Fe3O4/CNT nanocomposites as anode material for lithium ion batteries. J Alloys Compd 611:260–266
Aragon MJ, Perez-Vicente C, Tirado JL (2007) Submicronic particles of manganese carbonate prepared in reverse Micelles: a new electrode material for lithium-ion batteries. Electrochem Commun 9(7):1744–1748
Mu YL, Wang L, Zhao Y (2017) 3D flower-like MnCO3 microcrystals: evolution mechanisms of morphology and enhanced electrochemical performances. Electrochim Acta 251:119–128
Kesavan T, Suresh S, Arulraj I (2014) Facile synthesis of hollow sphere MnCO3: a cheap and environmentally benign anode material for li-ion batteries. Mater Lett 136:411–415
Yan Y, Zhu YC, Yu Y (2012) MnCO3 Microstructures assembled with nanoparticles: shape-controlled synthesis and their application for li-ion batteries. J Nanosci Nanotechnol 12(9):7334–7338
Devaraj S, Liu HY, Balaya P (2014) MnCO3: a novel electrode material for supercapacitors. J Mater Chem A 2(12):4276–4281
Gao MW, Cui XW, Wang RF (2015) Graphene-wrapped mesoporous MnCO3 single crystals synthesized from dynamic floating electrodeposition method for high performance lithium-ion storage. J Mater Chem A 3(27):14126–14133
Zhang L, Mei T, Wang XB (2015) Hierarchical architectured MnCO3 microdumbbells: facile synthesis and enhanced performance for lithium ion batteries. CrystEngComm 17(33):6450–6455
Zhao SQ, Feng F, Yu FQ (2015) Flower-to-petal structural conversion and enhanced interfacial storage capability of hydrothermally crystallize MnCO3 via the in situ mixing of graphene oxide. J Mater Chem A 3(47):24095–24102
Zhou LK, Kong XH, Gao M (2014) Hydrothermal fabrication of MnCO3 @rGO composite as an anode material for high-performance lithium ion batteries. Inorg Chem 53(17):9228–9234
Wang K, Shi YH, Li HH (2016) Assembly of MnCO3 nanoplatelets synthesized at low temperature on graphene to achieve anode materials with high rate performance for lithium-ion batteries. Electrochim Acta 215:267–275
Zhong YR, Yang M, Zhou XL (2015) Orderly packed anodes for high-power lithium-ion batteries with super-long cycle life: rational design of MnCO3/large-area graphene composites. Adv Mater 27(5):806–812
Zhang F, Zhang RH, Liang GM (2013) Carboxylated carbon nanotube anchored MnCO3 nanocomposites as anode materials for advanced lithium-ion batteries. Mater Lett 111:165–168
Liu XM, Huang ZD, Oh SW (2012) Carbon nanotube (CNT)-based composites as electrode material for rechargeable li-ion batteries: a review. Compos Sci Technol 72(2):121–144
Abbas SM, Hussain ST, Ali S (2013) Synthesis of carbon nanotubes anchored with mesoporous Co3O4 nanoparticles as anode material for lithium-ion batteries. Electrochim Acta 105:481–488
Ke QQ, Tang CH, Yang ZC (2015) 3D Nanostructure of carbon nanotubes decorated Co3O4 nanowire arrays for high performance supercapacitor electrode. Electrochim Acta 163:9–15
Shao LY, Shu J, Ma R (2013) Electrochemical characteristics and intercalation mechanism of manganese carbonate as anode material for lithium-ion batteries. Int J Electrochem Sci 8:1170–1180
Pourmortazavi SM, Nasrabadi MR, Dehaghani AAD (2012) Statistical optimization of experimental parameters for synthesis of manganese carbonate and manganese oxide nanoparticles. Mater Res Bull 47(4):1045–1050
Zhang Y, Liu H, Zhu ZH (2013) A green hydrothermal approach for the preparation of graphene/α-MnO2 3D network as anode for lithium ion battery. Electrochim Acta 108:465–471
Zheng MT, Zhang HR, Gong XB (2013) A simple additive-free approach for the synthesis of uniform manganese monoxide nanorods with large specific surface area. Nanoscale Res Lett 8(1):166–172
Wang SS, Li QH, Pu WH (2016) Development of monodispersed MnCO3/graphene nanosheet composite as anode for lithium-ion battery by hydrothermal synthesis. Ionics 22(6):771–778
Feng XY, Shen Q, Shi YC (2016) One-pot hydrothermal synthesis of core-shell structured MnCO3 @C as anode material for lithium-ion batteries with superior electrochemical performance. Electrochim Acta 220:391–397
Wu XL, Cao MH, Lu HY (2006) microemulsion-mediated solvothermal synthesis and morphological evolution of MnCO3 nanocrystals. J Nanosci Nanotechnol 6(7):2123–2128
Mirhashemihaghighi S, León B, Vicente CP (2012) Lithium storage mechanisms and effect of partial cobalt substitution in manganese carbonate electrodes. Inorg Chem 51:5554–5560
Xia H, Lai MO, Lu L (2010) Nanoflaky MnO2/carbon nanotube nanocomposites as anode materials for lithium-ion batteries. J Mater Chem 20(33):6896–6902
Peigney A, Laurent C, Flahaut E (2001) Specific surface area of carbon nanotubes and bundles of carbon nanotubes. Carbon 39(4):507–514
Sakamoto JS, Dunn B (2002) Vanadium oxide-carbon nanotube composite electrodes for use in secondary lithium batteries. J Electrochem Soc 149(1):A26–A30
Wang LB, Tang WJ, Jing Y (2014) Do transition metal carbonates have greater lithium storage capability than oxides? a case study of monodisperse CoCO3 and CoO microspindles. Appl Mater Interfaces 6(15):12346–12352
Su LW, Zhou Z, Qin X (2013) CoCO3 submicrocube/graphene composites with high lithium storage capability. Nano Energy 2(2):276–282
Zhong YR, Su LW, Yang M (2013) Rambutan-like FeCO3 hollow microspheres: facile preparation and superior lithium storage performances. ACS Appl Mater Interfaces 5(21):11212–11217
Ding ZJ, Yao B, Feng JK (2013) Enhanced rate performance and cycling stability of a CoCO3 –polypyrrole composite for lithium ion battery anodes. J Mater Chem A 1(37):11200–11209
Su LW, Hei JP, Wu XB (2017) Ultrathin layered hydroxide cobalt acetate nanoplates face-to-face anchored to graphene nanosheets for high-efficiency lithium storage. Adv Funct Mater 27(10):1605544
Cao ZX, Ding YM, Zhang J (2015) Submicron peanut-Like MnCO3 as an anode material for lithium ion batteries. RSC Adv 69:56299–56303
Zhang F, Zhang R, Feng JK (2014) CdCO3/carbon nanotube nanocomposites as anode materials for advanced lithium-ion batteries. Mater Lett 111:165–168
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This work was supported by the Scientific Research Program of Hebei Province (No. 16273706D), the Basic Innovation Team of Tangshan (2017).
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Su, D., Wang, J., Yang, Z. et al. Stability electrochemical performance of self-assembled hierarchical MnCO3/MWCNT nanocomposite as anode material for lithium-ion batteries. J Solid State Electrochem 22, 3485–3491 (2018). https://doi.org/10.1007/s10008-018-4020-1
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DOI: https://doi.org/10.1007/s10008-018-4020-1