Skip to main content
SpringerLink
Log in

Perezone as corrosion inhibitor for AISI 1018 steel immersed in NaCl saturated with CO2

  • Original Paper
  • Published:
Journal of Solid State Electrochemistry Aims and scope Submit manuscript

Abstract

An electrochemical study of natural compound perezone as a corrosion inhibitor of 1018 steel immersed in 3% NaCl solution saturated with CO2 was conducted through electrochemical impedance spectroscopy under static and turbulent flow conditions and inhibitor concentration in the 0–50-ppm range. It was determined that perezone provides good corrosion protection at 10-ppm concentration with efficiency of ƞ = 87% in static conditions, whereas in hydrodynamic conditions at both rotation rates of 100 and 500 rpm, the efficiency reached ƞ = 96 and 95%, respectively, at a concentration of 5 ppm. A thermodynamic analysis by means of the Langmuir adsorption model indicated that inhibitor molecules are physisorbed to the steel surface.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13

Similar content being viewed by others

References

  1. Espinoza A, Rodríguez FJ (2016) Caffeine and nicotine in 3% NaCl solution with CO2 as corrosion inhibitors for low carbon steel. RSC Adv 6:70226–70236

    Article  Google Scholar 

  2. Singh A, Lin Y, Ebenso EE, Liu W, Pan J, Huang B (2015) Gingko biloba fruit extract as an eco-friendly corrosion inhibitor for J55 steel in CO2 saturated 3.5% NaCl solution. J of Ind and Eng Chem 24:219–228

    Article  CAS  Google Scholar 

  3. Zhang H, Pang X, Zhou M, Liu C, Wei L, Gao K (2015) The behavior of pre-corrosion effect on the performance of imidazoline-based inhibitor in 3 wt.% NaCl solution saturated with CO2. Appl Surf Sci 356:63–72

    Article  CAS  Google Scholar 

  4. Espinoza A, García S, Rodríguez FJ (2015) Nicotine as corrosion inhibitor for 1018 steel in 1M HCl under turbulent conditions. J Anal Bional Tech 6(6):273. doi:10.4172/2155-9872.1000273

    Google Scholar 

  5. Bhawsar J, Jain PK, Jain P (2015) Experimental and computational studies of Nicotiana tabacum leaves extract as green corrosion inhibitor for mild steel in acidic medium. Alex Eng J 54:769–775

    Article  Google Scholar 

  6. Ashassi H, Asghari E (2008) Effect of hydrodynamic conditions on the inhibition performance of L-methionine as a green inhibitor. Electrochim Act 54:162–167

    Article  Google Scholar 

  7. Kamal C, Sethuraman MG (2012) Spirulina plantesis, a novel green inhibitor for acid corrosion of mild steel. Arab J of Chem 5:155–161

    Article  CAS  Google Scholar 

  8. Ismail M (2006) Eco friendly corrosion inhibitors: inhibitive action of quinine for corrosion of low carbon steel in 1M HCl. J of Appl Electrochem 36:1163–1168

    Article  Google Scholar 

  9. Khadraoui A, Khelifa A, Hamitouche H (2014) Inhibitive effect by extract of Mentha rotundifolia leaves on the corrosion of steel in 1M HCl solution. Res Chem Intermed 40:961–972

    Article  CAS  Google Scholar 

  10. Ocheje P, Okon N (2014) Commiphora pedunculata gum as a green inhibitor for the corrosion of aluminium alloy in 0.1 M HCl. Res Chem Intermed 40:2641–2649

    Article  Google Scholar 

  11. El Ouariachi E, Bouyanzer A, Salghi R, Hammouti B, Desjobert JM, Costa J, Paolini J, Majidi L (2015) Inhibition of corrosion of mild steel in 1 M HCl by the essential oil or solvent extracts of Ptychotis verticillata. Res Chem Intermed 41:935–946

    Article  CAS  Google Scholar 

  12. Bothi P, Kaleem A, Rahim AA, Awang K, Mukhtar MR, Osman H (2013) Indole alkaloids of Alstonia angustifolia var. latifolia as green inhibitor for mild steel corrosion in 1 M HCl media. J of Mat Eng and Perf 22:1072–1078

    Article  Google Scholar 

  13. Gopiraman M, Sakunthala P, Kesavan D, Alexramani V, Kim IS, Sulochana N (2012) An investigation of mild carbon steel corrosion inhibition in hydrochloric acid medium by environment friendly green inhibitors. J Coat Tech Res 9(1):15–26

    Article  CAS  Google Scholar 

  14. Bouknana D, Hammouti B, Messali M, Aouniti A, Sbaa M (2014) Olive pomace extract (OPE) as corrosion inhibitor for steel in HCl medium. Asian Pac J Trop Dis 4(Suppl 2):S963–S974

    Article  Google Scholar 

  15. Muthukumar N, Ilangovan A, Maruthamuthu S, Palaniswamy N (2007) Surface analysis of inhibitor films formed by 1-aminoanthraquinones on API 5L X60 steel in diedel-water mixtures. Electrochim Act 52:7183–7192

    Article  CAS  Google Scholar 

  16. Jeyaprabha C, Sathiyanarayanan S, Phani KLN, Venkatachari G (2005) Influence of poly(aminoquinone) on corrosion inhibition of iron in acid media. Appl Surf Sci 252:966–975

    Article  CAS  Google Scholar 

  17. Muthukumar N, Ilangovan A, Maruthamuthu S, Palaniswamy N, Kimura A (2007) 1-aminoanthraquinone derivatives as a novel corrosion inhibitor for carbon steel API 5l X60 in white petrol-water mixtures. Mat Chem and Phys 115:444–452

    Article  Google Scholar 

  18. Walls F, Salmón M, Padilla J, Nathan J, Romo P (1965) La estructura de la perezona. J Bol Inst Quím Univ Nac Auton Mex 17:3–5

  19. Odewunmi NA, Umoren SA, Gasem ZM (2015) Water melon waste products as green corrosion inhibitors for mild steel in HCl solution. J of Environ Chem Eng 3:286–296

    Article  CAS  Google Scholar 

  20. Mohan P, Paruthimal G (2013) 1,4-Bis (2-nitrobenzylidene) thiosemicarbazide as effective corrosion inhibitor for mild steel. J Mater Sci Techno 29(11):1096–1100

    Article  CAS  Google Scholar 

  21. Ghareba S, Omanovic S (2011) The effect of electrolyte flow on the performance of 12-aminododecanoic acid as carbon steel corrosion inhibitor in CO2-saturated hydrochloric acid. Corros Sci 52:3805–3812

    Article  Google Scholar 

  22. Kosari A, Moayed MH, Davoodi A, Parvizi R, Momeni M, Eshghi H, Moradi H (2014) Electrochemical and quantum chemical assessment of two organic compounds from pyridine derivatives as corrosion inhibitors for mild steel in HCl solution under stagnant condition and hydrodynamic flow. Corros Sci 78:138–150

    Article  CAS  Google Scholar 

  23. Chidierebere MA, Oguzi EE, Lie L, Li Y, Wang F (2015) Ascorbic acid as corrosion inhibitor for Q235 mild steel in acidic environments. J of Ind and Eng Chem 26:182–192

    Article  Google Scholar 

  24. Okafor PC, Apebende EA (2014) Corrosion inhibition characteristics of Thymus vulgaris, Xylopia aethiopica and Zingiber officinale extracts on mild steel in H2SO4 solutions. Pigment & Resin Techno 43(6):357–364

    Article  CAS  Google Scholar 

  25. Albella JM, Cintas AM, Miranda T, Serratosa JM (1993) Introducción a la ciencia de los Materiales, Textos universitarios, Madrid

  26. Zarrouk A, Hammouti B, Lakhlifi T, Traisnel M, Venin H, Bentiss F (2015) New 1H-pyrrole -2,5-dione derivatives as efficient organic inhibitors of carbon steel corrosion in hydrochloric acid medium: electrochemical, XPS and DFT studies. Corros Sci 90:572–584

    Article  CAS  Google Scholar 

  27. Espinoza A, Negrón GE, González R, Ángeles D, Romero M, Palomar M (2016) Effect of hydrodynamic conditions, temperature and immersion times on the corrosion inhibition efficiency of API 5L X52 steel in 1M HCl containing 1H-1,2,4 or 1H-1,2,3-triazoles. Arab J for Sci and Eng 1–12

  28. Gayed W, El-Sayed NH (2014) Synthesis and corrosion inhibition evaluation of novel aminic nitrogen-bearing 1,2,4-triazole Schiff base compounds. Europ J of Chem 5(4):563–569

    Article  Google Scholar 

  29. Yıldız R (2015) An electrochemical and theoretical evaluation of 4,6-diamino-2-pyrimidinethiol as a corrosion inhibitor for mild steel in HCl solution. Corros Sci 90:544–553

    Article  Google Scholar 

Download references

Acknowledgments

AEV is grateful to DGAPA for the postdoctoral scholarship. FJRG thanks to PAIP (Facultad de Química) support.

The authors would like to thank the Facultad de Química, Departamento de Ingeniería Metalurgica, and the SNI for the designation.

Author information

Authors and Affiliations

  1. Facultad de Química, Departamento de Ingeniería Metalúrgica, Universidad Nacional Autónoma de México, 04510, C.U., Ciudad de México, Mexico

    A. Espinoza-Vázquez & F. J. Rodríguez-Gómez

  2. Facultad de Química, Departamento de Farmacia, Universidad Nacional Autónoma de México, 04510, C.U., Ciudad de México, Mexico

    R. Mata & A. Madariaga-Mazón

  3. Departamento de Ciencias Básicas, Universidad Autónoma Metropolitana—Azcapotzalco, San Pablo Av. No. 180, 02200, Ciudad de México, Mexico

    D. Ángeles-Beltrán

Authors
  1. A. Espinoza-Vázquez
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. F. J. Rodríguez-Gómez
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. Mata
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. Madariaga-Mazón
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. D. Ángeles-Beltrán
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. Espinoza-Vázquez.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Espinoza-Vázquez, A., Rodríguez-Gómez, F.J., Mata, R. et al. Perezone as corrosion inhibitor for AISI 1018 steel immersed in NaCl saturated with CO2 . J Solid State Electrochem 21, 1687–1697 (2017). https://doi.org/10.1007/s10008-017-3528-0

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10008-017-3528-0

Keywords

Search

Navigation