Abstract
In the present work, the dependence of photovoltaic parameters of laboratory-scale dye sensitized solar cells (DSSCs) on photoanode active area (A) and also the effect of using current collector on this dependency were investigated. Current collectors were applied, in the form of silver strips, on the edges of electrodes. Electrochemical impedance spectroscopy (EIS) and current-voltage (I-V) curve measurement were employed as characterizing methods. The role of current collector was to decrease the resistance against current collection from the surface of electrodes and thus to decrease series resistance of DSSCs. It was observed that all photovoltaic parameters, i.e., short circuit current density (J sc), open circuit voltage (V oc), fill factor (FF), and power conversion efficiency (η), decrease with increasing A. Applying current collector had no influence on photovoltaic parameters of smallest DSSC, but it improved the performance of larger DSSCs. Also, applying current collector caused the photovoltaic parameters of DSSCs to be less dependent on A. It was shown that A dependence of photovoltaic parameters was due to the effect of A on area-specific series resistance (r s) of DSSC. Also, the effect of current collector on A dependency of photovoltaic parameters was due to its effect on A dependency of r s.
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References
O’Regan B, Grätzel M (1991) A low-cost high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature 353:737–740
Grätzel M (2003) Review: dye-sensitized solar cells. J Photochem Photobiol C: Photochem Rev 4:145–153
Hagfeldt A, Boschloo G, Sun L, Kloo L, Pettersson H (2010) Dye-sensitized solar cells. Chem Rev 110:6595–6663
Vendra VK, Absher J, Ellis SR, Amos DA, Druffel T, Sunkara MK (2012) Photoanode area dependent efficiency and recombination effects in dye-sensitized solar cells. J Electrochem Soc 159:H728–H733
Fakharuddin A, Archana PS, Kalidin Z, Yusoff MM, Jose R (2013) Standardization of photoelectrode area of dye-sensitized solar cells. RSC Adv 3:2683–2689
Hočevar M, Krašovec UO, Berginc M, Dražič G, Hauptman N, Topič M (2008) Development of TiO2 pastes modified with Pechini sol-gel method for high efficiency dye-sensitized solar cell. J Sol-Gel Sci Technol 48:156–162
Mashreghi A, Davoudi F (2014) Effect of TiO2 nanoparticle content sol-gel derived TiO2 paste on the photovoltaic properties of TiO2 photoanode of dye-sensitized solar cells. Mater Sci Semicond Process 26:669–676
Mashreghi A, Ghasemi M (2015) Investigating the effect of molar ratio between TiO2 nanoparticles and titanium alkoxide in Pechini based TiO2 paste on photovoltaic performance of dye-sensitized solar cells. Renew Energy 75:481–488
Mashreghi A, Davoudi F (2015) The effect of ethylene glycol/citric acid molar ratio in the initial precursor of TiO2 nanoparticle paste synthesized by a polymerizable complex method on the photovoltaic properties of dye-sensitized solar cells. Mater Sci Semicond Process 30:618–624
Bahrami Moghadam F, Mashreghi A (2015) Investigating the electrolyte iodine concentration effect on photovoltaic properties of dye-sensitized solar cells by electrochemical impedance spectroscopy. Mater Sci Semicond Process 40:84–89
Shin I, Seo H, Son MK, Kim JK, Prabakar K, Kim HJ (2010) Analysis of TiO2 thickness effect on characteristic of a dye-sensitized solar cell by using electrochemical impedance spectroscopy. Curr Appl Phys 10:S422–S424
Lan JL, Wei TC, Feng SP, Wan CC, Cao G (2012) Effects of iodine content in the electrolyte on the charge transfer and power conversion efficiency of dye-sensitized solar cells under low light intensities. J Phys Chem C 116:25727–25733
Noh SI, Ahn HJ, Riu DH (2012) Photovoltaic property dependence of dye sensitized solar cells on sheet resistance of FTO substrate deposited via spray pyrolysis. Ceram Int 38:3735–3739
Acknowledgments
This research was financially supported by Iran National Science Foundation (INSF) (Grant No. 93011385) and by Shiraz University of Technology. The authors are grateful for these supports.
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Mashreghi, A., Bahrami Moghadam, F. Effect of photoanode active area on photovoltaic parameters of dye sensitized solar cells through its effect on series resistance investigated by electrochemical impedance spectroscopy. J Solid State Electrochem 20, 1361–1368 (2016). https://doi.org/10.1007/s10008-016-3133-7
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DOI: https://doi.org/10.1007/s10008-016-3133-7