Skip to main content
SpringerLink
Log in

New advances in triboelectrochemistry: from steady state to impedance of abraded stainless steel in acidic medium

  • Original Paper
  • Published:
Journal of Solid State Electrochemistry Aims and scope Submit manuscript

Abstract

The present paper reports on the application of electrochemical impedance spectroscopy (EIS) in triboelectrochemistry. Electrochemical measurements were performed at the constant dc current attained during a permanent regime of friction achieved by a rotating pin-on-disc (P-o-D) tribometer. A model is then proposed which embodies a classical kinetic description of an active–passive transition into the accepted description of the triboelectrochemical response of a passive material. From the derivation of the equation at steady state, a set of parameters were determined allowing to describe correctly both the dc and ac behaviours of the interface and to estimate the different components of the triboelectrochemical signals.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  1. Landolt D, Mischler S, Stemp M (2001) Electrochemical methods in tribocorrosion: a critical appraisal. Electrochim Acta 46:3913–3929

    Article  CAS  Google Scholar 

  2. Takadoum J (1996) The influence of potential on the tribocorrosion of nickel and iron in sulfuric acid solution. Corros Sci 38:643–654

    Article  CAS  Google Scholar 

  3. Favero M, Stadelmann P, Mischler S (2006) Effect of the applied potential of the near surface microstructure of a 316L steel submitted to tribocorrosion in sulfuric acid. J Phys D Appl Phys 39:3175–3183

    Article  CAS  Google Scholar 

  4. Keddam M, Wenger F (2011) Electrochemical methods in tribocorrosion. In: Tribocorrosion of Passive Metals and Coatings. pp 187–221

  5. Ponthiaux P, Wenger F, Drees D, Celis JP (2004) Electrochemical techniques for studying tribocorrosion processes. Wear 256:459–468

    Article  CAS  Google Scholar 

  6. Guadalupe Maldonado S, Mischler S, Cantoni M, Chitty WJ, Falcand C, Hertz D (2013) Mechanical and chemical mechanisms in the tribocorrosion of a Stellite type alloy. Wear 308:213–221

    Article  CAS  Google Scholar 

  7. Déforge D, Huet F, Nogueira RP, Ponthiaux P, Wenger F (2006) Electrochemical noise analysis of tribocorrosion processes under steady-state friction regime. Corrosion 62:514–521

    Article  Google Scholar 

  8. Keddam M, Ponthiaux P, Vivier V (2014) Tribo-electrochemical impedance: a new technique for mechanistic study in tribocorrosion. Electrochim Acta 124:3–8

    Article  CAS  Google Scholar 

  9. Azzi M, Klemberg-Sapieha JE (2011) Tribocorrosion test protocols for sliding contacts. In: Tribocorrosion of Passive Metals and Coatings. pp 222–238

  10. García I, Drees D, Celis JP (2001) Corrosion-wear of passivating materials in sliding contacts based on a concept of active wear track area. Wear 249:452–460

    Article  Google Scholar 

  11. Isaacs HS, Ryan MP, Oblonsky LJ (1997) Mapping currents at the corroding surface/solution interface. ProcCorros/97 ResTopSymp 65–79

  12. Tallman DE, He J, Gelling VJ, Bierwagen GP, Wallace GG (2003) Scanning vibrating electrode studies of electroactive conducting polymers on active metals. ACS SympSer 843 (Electroactive Polymers for Corrosion Control) 228–253

  13. Bayet E, Huet F, Keddam M, Ogle K, Takenouti H (1999) Local electrochemical impedance measurement: scanning vibrating electrode technique in ac mode. Electrochim Acta 44(24):4117–4127

    Article  CAS  Google Scholar 

  14. Annergren I, Thierry D, Zou F (1997) Localized electrochemical impedance spectroscopy for studying pitting corrosion on stainless steels. J Electrochem Soc 144:1208–1215

    Article  CAS  Google Scholar 

  15. Huang VM-W, Wu S-L, Orazem ME, Pebere N, Tribollet B, Vivier V (2011) Local electrochemical impedance spectroscopy: a review and some recent developments. Electrochim Acta 56:8048–8057

    CAS  Google Scholar 

  16. Keddam M (2006) 2006 W.R. Whitney Award Lecture: application of advanced electrochemical techniques and concepts to corrosion phenomena. Corrosion 62:1056–1066

    Article  CAS  Google Scholar 

  17. Keddam M, Mattos OR, Takenouti H (1981) Reaction model for iron dissolution studied by electrode impedance. II. Determination of the reaction model. J Electrochem Soc 128:266–274

    Article  CAS  Google Scholar 

  18. Keddam M, Mattos OR, Takenouti H (1986) Mechanism of anodic dissolution of iron-chromium alloys investigated by electrode impedances—II. Elaboration of the reaction model. Electrochim Acta 31:1159–1165

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. UPMC Univ Paris 06, UMR 8235, Laboratoire Interfaces et Systèmes Electrochimiques, Sorbonne Universités, F-75005, Paris, France

    Michel Keddam & Vincent Vivier

  2. Laboratoire LGPM, Ecole Centrale, Rue des Vignes, 92290, Châtenay-Malabry, France

    Feng Liao & Pierre Ponthiaux

Authors
  1. Michel Keddam
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Feng Liao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Pierre Ponthiaux
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Vincent Vivier
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Michel Keddam, Pierre Ponthiaux or Vincent Vivier.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Keddam, M., Liao, F., Ponthiaux, P. et al. New advances in triboelectrochemistry: from steady state to impedance of abraded stainless steel in acidic medium. J Solid State Electrochem 19, 2591–2599 (2015). https://doi.org/10.1007/s10008-015-2914-8

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10008-015-2914-8

Keywords

Search

Navigation