Abstract
An electrochemical characterization of the atmospheric corrosion products formed on silver exposed to Colombian tropical-mountain sites is reported. Rural and urban environments were selected for exposures up to 6 months. Corrosion products were characterized by X-ray diffraction (XRD), linear sweep voltammetry (LSV), and coulometric reduction (CR). XRD patterns shows that achantite (Ag2S) and silver (I) oxide (Ag2O) were the main corrosion products. Electrochemical results show a relationship between the reduction charge obtained by LSV and the sulfide thickness estimated by CR. To perform a correct assignments of all reduction peaks, cyclic voltammetry (CV) and subsequent anodic polarizations at specific potentials of pure silver surface were made in different solutions, such as 0.1 M NaOH, 0.01 M Na2S, and 0.1 M Na2SO4. This procedure was reliable in terms of the electrochemical formation of Ag2S, Ag2O, and Ag2SO4, respectively. Electrochemical techniques were highly reproducible and sensible to detect and measure silver corrosion rates in this type of environments.
Similar content being viewed by others
References
Mendoza AR, Corvo F, Gómez A, Gómez J (2004) Influence of the corrosion products of copper on its atmospheric corrosion kinetics in tropical climate. Corros Sci 46:1189–1200
Graedel TE (1992) Corrosion mechanisms for silver exposed to the atmosphere. J Electrochem Soc 139:1963–1970
Abbott WH (1974) Effects of industrial air pollutants on electrical contact materials. IEEE Trans Parts Hybrids Packag 10:24–27
Franey JP, Kammlott GW, Graedel TE (1985) The corrosion of silver by atmospheric sulfurous gases. Corros Sci 25:133–143
Volpe L, Peterson PJ (1989) The atmospheric sulfidation of silver in a tubular corrosion reactor. Corros Sci 29:1179–1196
Kleber C, Wiesinger R, Schnöller J, Hilfrich U, Hutter H, Schreiner M (2008) Initial oxidation of silver surfaces by S2− and S4+ species. Corros Sci 50:1112–1121
Wiesinger R, Martina I, Kleber C, Schreiner M (2013) Influence of relative humidity and ozone on atmospheric silver corrosion. Corros Sci 77:69–76
Rice DW, Peterson P, Rigby EB, Phipps PBP, Cappell RJ, Tremoureux R (1981) Atmospheric corrosion of copper and silver. J Electrochem Soc 128:275–284
Graedel TE, Franey JP, Gualtieri GJ, Kammlott GW, Malm DL (1985) On the mechanism of silver and copper sulfidation by atmospheric H2S and OCS. Corros Sci 25:1163–1180
Arroyave C, Morcillo M (1995) The effect of nitrogen oxides in atmospheric corrosion of metals. Corros Sci 37:293–305
Leygraf C, Graedel T (2000) Atmospheric corrosion. Wiley-Interscience, New York
de Mele MFL, Duffó G (2002) Tarnishing and corrosion of silver-based casting alloys in synthetic salivas of different compositions. J Appl Electrochem 32:157–164
Homem P, Fonseca I, Cavalheiro J (2008) The tarnishing of the silver altar of porto’s cathedral: an atmospheric corrosion case. Corros Prot Mater 27:82–86
Ha H, Payer J (2011) The effect of silver chloride formation on the kinetics of silver dissolution in chloride solution. Electrochim Acta 56:2781–2791
Capelo S, Homem PM, Cavalheiro J, Fonseca ITE (2013) Linear sweep voltammetry: a cheap and powerful technique for the identification of the silver tarnish layer constituents. J Solid State Electrochem 17:223–234
Allen JA (1952) Oxide films on electrolytically polished copper surfaces. Trans Faraday Soc 48:273–279
Krumbein S, Newell B, Pascucci V (1989) Monitoring environmental tests by coulometric reduction of metallic control samples. J Test Eval 17:357–367
Gil H, Leygraf C (2007) Initial atmospheric corrosion of copper induced by carboxylic acids A comparative in situ study. J Electrochem Soc 154:C611–C617
Echavarría A, Echeverría F, Gil H, Arroyave C (2009) Influence of environmental factors in the atmospheric corrosion of copper in the presence of propionic acid. J Chil Chem Soc 54:212–217
Campbell WE, Thomas UB (1939) Tarnish studies the electrolytic reduction method for the analysis of films on metal surfaces. Trans Electrochem Soc 76:303–328
Bernard MC, Dauvergne E, Evesque M, Keddam M, Takenouti H (2005) Reduction of silver tarnishing and protection against subsequent corrosion. Corros Sci 47:663–679
Silva M, Dick LFP (2000) Development of a coulometric method for the determination of gaseous sulfur compounds in urban atmospheres. J Braz Chem Soc 11:159–163
Costa V, Leyssens K, Adriaens A, Richard N, Scholz F (2010) Electrochemistry reveals archaeological materials. J Solid State Electrochem 14:449–451
Amor YB, Sutter E, Takenouti H, Tribollet B, Boinet M, Faure R, Balencie J, Durieu G (2014) Electrochemical study of the tarnish layer of silver deposited on glass. Electrochim Acta 131:89–95
Gil H, Calderón JA, Buitrago CP, Echavarría A, Echeverría F (2010) Indoor atmospheric corrosion of electronic materials in tropical-mountain environments. Corros Sci 52:327–337
Morcillo M, Almeida E, Marrocos M, Rosales B (2001) Atmospheric corrosion of copper in Ibero-America. Corrosion 57:967–980
ETS 300 019-1-0 (1994) Equipment Engineering (EE), environmental conditions and environmental tests for telecommunications equipment Part 1–0: classification of environmental conditions
ISO TC 156/WG 4 — N382 (2000) Measurement of environmental parameters affecting indoor corrosivity ISO/CD 15965 (Draft ISO 11844–3, 5th Revised Version of 2000-25-10)
ISO 9225:1992 corrosion of metals and alloys, corrosivity of atmospheres, measurement of pollution
ASTM B825-13 (2013) Test method for coulometric reduction of surface films on metallic test samples. ASTM International
Shams ElDin AM, Abd ElKader JM, Abd ElWahab FM, Saber TMH, ElAzhari AA, ElWaraky AA (1985) An electrochemical and ESCA study on the tarnishing of silver in solutions of different pS and pH values. Electrochim Acta 30:461–468
Johansson E, Leygraf C (1999) Corrosion measurements of silver and copper in indoor atmospheres using different evaluation techniques. Br Corros J 34:27–33
Fukuda Y, Fukushima T, Sulaiman A, Musalam I, Yap LC, Chotimongkol L, Judabong S, Potjanart A, Keowkangwal O, Yoshihara K, Tosa M (1991) Indoor corrosion of copper and silver exposed in Japan and ASEAN1 countries. J Electrochem Soc 138:1238–1243
Liang D, Allen HC, Frankel GS, Chen ZY, Kelly RG, Wu Y, Wyslouzil BE (2010) Effects of sodium chloride particles, ozone, UV, and relative humidity on atmospheric corrosion of silver. J Electrochem Soc 157:C146–C156
Ramamurthy AC, Rangarajan SK (1981) A gaussian quadrature analysis of linear sweep voltammetry. Electrochim Acta 26:11–115
Waterhouse GIN, Bowmaker GA, Metson JB (2001) The thermal decomposition of silver (I, III) oxide: a combined XRD, FT-IR and raman spectroscopic study. Phys Chem Chem Phys 3:3838–3845
Al-Kuhaili MF (2007) Characterization of thin films produced by the thermal evaporation of silver oxide. J Phys Appl Phys 40:2847
Ramesh MNV, Sundarayya Y, Sunandana CS (2007) Reactively radio frequency sputtered silver oxide thin films: phase evolution and phase stability. Mod Phys Lett B 21:1933–1944
Raju NRC, Kumar KJ, Subrahmanyam A (2009) Physical properties of silver oxide thin films by pulsed laser deposition: effect of oxygen pressure during growth. J Phys Appl Phys 42:135411
Djurle S, Sørensen P, Stenhagen E, Hartiala K, Veige S, Diczfalusy E (1958) An X-ray study on the system Ag-Cu-S. Acta Chem Scand 12:1427–1436
Lu X, Li L, Zhang W, Wang C (2005) Preparation and characterization of Ag2S nanoparticles embedded in polymer fibre matrices by electrospinning. Nanotechnology 16:2233
Suzuki RO, Ogawa T, Ono K (1999) Use of ozone to prepare silver oxides. J Am Ceram Soc 82:2033–2038
Kim H (2003) Corrosion process of silver in environments containing 0.1 ppm H2S and 1.2 ppm NO2. Mater Corros 54:243–250
Pourbaix M (1974) Atlas of electrochemical equilibria in aqueous solutions. NACE International
Jovic BM, Jovic VD, Stafford GR (1999) Cyclic voltammetry on Ag(111) and Ag(100) faces in sodium hydroxide solutions. Electrochem Commun 1:247–251
Jović BM, Jović VD, Stafford GR (2000) Electrochemical formation and characterization of silver (I) oxide. Mater Sci Forum 352:57–64
Takehara Z, Namba Y, Yoshizawa S (1968) Anodic oxidation of silver in alkaline solution. Electrochim Acta 13:1395–1403
Assaf FH, Zaky AM, Abd El-Rehim SS (2002) Cyclic voltammetric studies of the electrochemical behaviour of copper–silver alloys in NaOH solution. Appl Surf Sci 187:18–27
Jovic B, Jovic V (2004) Electrochemical formation and characterization of Ag2O. J Serb Chem Soc 69:153–166
Sato N, Shimizu Y (1973) Anodic oxide on silver in alkaline solution. Electrochim Acta 18:567–570
Ambrose J, Barradas RG (1974) The electrochemical formation of Ag2O in KOH electrolyte. Electrochim Acta 19:781–786
Arul Raj I, Vasu KI (1993) Electrochemical and oxygen reduction behaviour of solid silver-bismuth/antimony electrodes in KOH solutions. J Appl Electrochem 23:728–734
Droog JMM, Alderliesten PT, Bootsma GA (1979) Initial stages of anodic oxidation of silver in sodium hydroxide solution studied by potential sweep voltammetry and ellipsometry. J Electroanal Chem Interfacial Electrochem 99:173–186
Teijelo ML, Vilche JR, Arvía AJ (1984) The electroformation and electroreduction of anodic films formed on silver in 0.1 M sodium hydroxide in the potential range of the Ag/Ag2O couple. J Electroanal Chem Interfacial Electrochem 162:207–224
Gomez Becerra J, Salvarezza RC, Arvia AJ (1988) The role of a slow phase formation process in the growth of anodic silver oxide layers in alkaline solutions—I. Electroformation of Ag(I) oxide layer. Electrochim Acta 33:1431–1437
Price DW, Warren GW, Drouven B (1986) The electrochemical behaviour of silver sulphide in sulphuric acid solutions. J Appl Electrochem 16:719–731
Schweizer M, Kolb DM (2003) First observation of an ordered sulfate adlayer on Ag single crystal electrodes. Surf Sci 544:93–102
Acknowledgments
The authors are grateful to TROPICORR project and Universidad de Antioquia for financial assistance (Estrategia de Sostenibilidad 2013–2014 de la Universidad de Antioquia).
Author information
Authors and Affiliations
Corresponding author
Additional information
H. Gil holds a PhD, Politécnico Colombiano Jaime Isaza Cadavid PCJIC.
Rights and permissions
About this article
Cite this article
Gil, H., Buitrago, C.P. & Echavarría, A. Characterization of atmospheric corrosion products formed on silver in tropical-mountain environments. J Solid State Electrochem 19, 1817–1825 (2015). https://doi.org/10.1007/s10008-015-2821-z
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10008-015-2821-z