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Construction of a novel Cu(II)-selective electrode with long life span based on 8-aminoquinoline functionalized bentonite

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Abstract

A novel 8-aminoquinoline-functionalized bentonite was utilized as an electroactive sensing element in the construction of a potentiometric carboxylated-PVC-based polymeric membrane electrode. The electrode exhibited a linear response for copper(II) ions in the concentration range of 1.0 × 10–5−1.0 × 10–2 mol/dm3 with a slope of 28.24 mV/decade. While the response time of the electrode determined as about 20 s, its detection limit and long life time was determined as 5.0 × 10–6 mol/dm3 and 5 months, respectively. The proposed electrode was applied for the potentiometric detection of Cu(II) contents of some spiked water samples and satisfied results were attained.

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Acknowledgements

The authors gratefully acknowledge funding support from Erzincan Binali Yildirim University, The Scientific Research Projects Coordination Unit (FBA-2020-687).

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Authors and Affiliations

  1. Department of Chemistry, Institute of Science and Technology, Erzincan Binali Yildirim University, 24030, Erzincan, Turkey

    Bilge Dogan

  2. Department of Chemistry, Faculty of Arts and Sciences, Erzincan Binali Yildirim University, 24100, Erzincan, Turkey

    Fatih Coldur, Bulent Caglar & Kemal Volkan Ozdokur

  3. Department of Design, Vocational School, Erzincan Binali Yildirim University, 24100, Erzincan, Turkey

    Agah Oktay Ozdemir

  4. Department of Property Protection and Security, Uzumlu Vocational School, Erzincan Binali Yildirim University, 24150, Erzincan, Turkey

    Eda Keles Guner

Authors
  1. Bilge Dogan
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  2. Fatih Coldur
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  3. Bulent Caglar
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  4. Agah Oktay Ozdemir
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  5. Eda Keles Guner
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  6. Kemal Volkan Ozdokur
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Correspondence to Fatih Coldur or Bulent Caglar.

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Dogan, B., Coldur, F., Caglar, B. et al. Construction of a novel Cu(II)-selective electrode with long life span based on 8-aminoquinoline functionalized bentonite. Monatsh Chem 154, 53–64 (2023). https://doi.org/10.1007/s00706-022-03008-5

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  • DOI: https://doi.org/10.1007/s00706-022-03008-5

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