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Solid phases in the systems glycine–ZnX2–H2O (X = Cl−, Br−, I−) at 25 °C

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Abstract

The crystallization in the systems glycine–ZnX2 –H2O (X = Cl−, Br−, I−) was summarised. Occurrence of both equilibrium and non-equilibrium crystallization was found for these systems. The systems include complex compounds, from which three anhydrous and four hydrate formula types were obtained. The main building units of their crystal structures were mixed electroneutral tetrahedra, isolated in the case of xGly·ZnX2·yH2O (x = 1, 2, 3; y = 0, 1, 2) compounds, or connected in more complex polymer chains in the cases of Gly·ZnX2 and 2Gly·3ZnI2·4H2O. These crystallization processes were explained on the basis of Pearson’s softness–hardness concept and the chemical species existing in the solutions. The study of the system glycine–ZnBr2–H2O at 25 °C showed the occurrence of equilibrium and non-equilibrium crystallization in it. Three hitherto unknown compounds were obtained, Gly·ZnBr2 (monoclinic crystal system, space group P21), 3Gly·ZnBr2 (orthorhombic crystal system, space group Pna21) and 2Gly·ZnBr2·2H2O (monoclinic crystal system, space group C2/c), and characterised by XRD, IR, Raman, and DTA methods.

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Authors and Affiliations

  1. Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev Str., Bl. 11, 1113, Sofia, Bulgaria

    Stefka Tepavitcharova, Diana Rabadjieva, Christo Balarew & Rumjana Gergulova

  2. Department of Inorganic Chemistry, Faculty of Science, Charles University, Hlavova 2030, 128 40, Prague 2, Czech Republic

    David Havlíček, Irena Matulková, Ivan Němec & Ivana Císařová

  3. Institute of Inorganic Chemistry of the ASCR, v. v. i., Husinec-Řež 1001, 250 68, Řež, Czech Republic

    Jiří Plocek

Authors
  1. Stefka Tepavitcharova
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  2. David Havlíček
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  3. Irena Matulková
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  4. Diana Rabadjieva
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  5. Christo Balarew
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  6. Rumjana Gergulova
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  7. Ivan Němec
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  8. Ivana Císařová
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  9. Jiří Plocek
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Corresponding author

Correspondence to Stefka Tepavitcharova.

Additional information

In memory of Prof. H. Gamsjäger.

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Tepavitcharova, S., Havlíček, D., Matulková, I. et al. Solid phases in the systems glycine–ZnX2–H2O (X = Cl−, Br−, I−) at 25 °C. Monatsh Chem 149, 299–311 (2018). https://doi.org/10.1007/s00706-017-2120-8

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  • DOI: https://doi.org/10.1007/s00706-017-2120-8

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