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Synthesis and characterization of supramolecule grafted on modified magnetic nanoparticles: new hybrid organic–inorganic phase transfer catalyst

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Abstract

In this study, for the first time, calix[4]resorcinarene was grafted on the silica-coated magnetic nanoparticles (MNPs-Si) which efficiently catalyze one-pot epoxide ring opening reaction in excellent yields in a very short reaction time. Various advantages associated with this protocol include simple workup procedure, short reaction times, and high product yields. High catalytic activity and ease of recovery, using an external magnetic field, are additional eco-friendly attributes of this catalytic system.

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References

  1. Shenhar R, Rotello VM (2003) Acc Chem Res 36:549

    Article  CAS  Google Scholar 

  2. Thomas KG, Kamat PV (2003) Acc Chem Res 36:888

    Article  CAS  Google Scholar 

  3. Schmid G (2004) Nanoparticles: from theory to application. Wiley-VCH, Weinheim

    Google Scholar 

  4. Rao CNR, Muller A, Cheetham AK (2004) The chemistry of nanomaterials: synthesis, properties and applications. Wiley-VCH, Weinheim

    Book  Google Scholar 

  5. Drechsler U, Erdogan B, Rotello VM (2004) Chem Eur J 10:5570

    Article  CAS  Google Scholar 

  6. Raimondi F, Scherer GG, Kçtz R, Wokaun A (2005) Angew Chem 117:2228

    Article  Google Scholar 

  7. Hood MA, Mari M, Munoz R (2014) Materials 7:4057

    Article  CAS  Google Scholar 

  8. Sanchez C, Julian B, Belleville P, Popall M (2005) J Mater Chem 15:3559

    Article  CAS  Google Scholar 

  9. Verho O, Nagendiran A, Johnston EV, Tai C, Bäckvall JE (2013) Chem Cat Chem 5:612

    CAS  Google Scholar 

  10. Baig RBN, Varma RS (2013) Chem Commun 49:752

    Article  CAS  Google Scholar 

  11. Baig RBN, Varma RS (2013) Green Chem 15:398

    Article  Google Scholar 

  12. Polshettiwar V, Luque R, Fihri A, Zhu H, Bouhrara M, Basset J (2011) Chem Rev 111:3036

    Article  CAS  Google Scholar 

  13. García-Garrido SE, Francos J, Cadierno Basset V, Polshettiwar V (2011) Chem Sus Chem 4:104

    Article  Google Scholar 

  14. Nakayama T, Takhashi T, Takeshi K (1999) J Photopolym Sci Tec 12:347

    Article  CAS  Google Scholar 

  15. Aba OH, Haga K, Ueda M, Morikawa O, Konishi H (1999) Chem Mat 11:427

    Article  Google Scholar 

  16. Bell TW, Hext NM (2004) Chem Soc Rev 33:589

    CAS  Google Scholar 

  17. Jain VK, Pillai SG, Gupte HS (2008) J Iran Chem Soc 5:646

    Article  CAS  Google Scholar 

  18. Mouradzadegun A, Kiasat AR, Kazemian Fard P (2012) Catal Commun 29:1

    Article  CAS  Google Scholar 

  19. Mouradzadegun A, Abadast F, Elahi S (2014) Monatsh Chem 145:1663

    Article  CAS  Google Scholar 

  20. Mouradzadegun A, Abadast F, Elahi S (2014) Catal Lett 144:1636

    Article  CAS  Google Scholar 

  21. Yadollahi B, Danafar H (2007) Catal Lett 113:120

    Article  CAS  Google Scholar 

  22. Can K, Ozmen M, Ersoz M (2009) Colloids Surf B 71:154

    Article  CAS  Google Scholar 

  23. Kamal A, Arifuddin M, Rao M (1999) Tetrahedron Asymmetry 10:4261

    Article  CAS  Google Scholar 

  24. Kiasat AR, Fallah-Mehrjerdi MJ (2009) J Iran Chem Soc 6:542

    Article  CAS  Google Scholar 

  25. Kiasat AR, Mirzajani R, Shalbaf H, Tabatabaei T, Fallah-Mehrjerdi M (2009) J Chin Chem Soc 56:594

    Article  CAS  Google Scholar 

  26. Procopio A, Costanzo P, Dalpozzo R, Maiuolo L, Nardi M, Oliverio M (2010) Tetrahedron Lett 51:5150

    Article  CAS  Google Scholar 

  27. Mombani Godajdar B, Kiasat AR, Mahmoodi Hashemi M (2013) J Mol Liq 183:14

    Article  Google Scholar 

  28. Deng YH, Wang CC, Hu JH, Yang WL, Fu SK (2005) Colloids Surf A Physicochem Eng Asp 262:87

    Article  CAS  Google Scholar 

  29. Stober W, Fink A, Bohn E (1968) J Colloid Interface Sci 26:62

    Article  Google Scholar 

  30. Linda M, Tunstad JA, Dalcanale T, Dalcanale E, Bryant A, Sherman C, Helgeson RC, Knobler CB, Cram DJ (1989) J Org Chem 54:1305

    Article  Google Scholar 

Download references

Acknowledgments

We are grateful to the Research Council of Shahid Chamran University for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Shahid Chamran University of Ahvaz, Ahvaz, 61357-4-3169, Iran

    Arash Mouradzadegun, Sadjad Boroon & Pegah Kazemian Fard

Authors
  1. Arash Mouradzadegun
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  2. Sadjad Boroon
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  3. Pegah Kazemian Fard
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Corresponding author

Correspondence to Arash Mouradzadegun.

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Mouradzadegun, A., Boroon, S. & Fard, P.K. Synthesis and characterization of supramolecule grafted on modified magnetic nanoparticles: new hybrid organic–inorganic phase transfer catalyst. Monatsh Chem 148, 367–374 (2017). https://doi.org/10.1007/s00706-016-1759-x

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  • DOI: https://doi.org/10.1007/s00706-016-1759-x

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