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NaBrO3/bmim[HSO4]: a versatile system for the selective oxidation of 1,2-diols, α-hydroxyketones, and alcohols

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Abstract

Sodium bromate with bmim[HSO4] has been found to be an excellent oxidizing agent in aqueous medium. NaBrO3:bmim[HSO4] oxidized 1,2-diols, α-hydroxyketones, and alcohols to the corresponding carbonyl compounds in excellent yields. This method offers advantages such as low cost reagents, aqueous reaction conditions, moderate temperatures and short reaction times and hence environmentally benign reaction. Moreover, the ionic liquid bmim[HSO4] could be recycled for at least three times without loss of significant activity.

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Acknowledgments

AL thanks University of Delhi for the award of University Teaching Assistantship and AC thanks C.S.I.R., New Delhi, India for the grant of Senior Research Fellowship.

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Authors and Affiliations

  1. Department of Chemistry, University of Delhi, Delhi, 110007, India

    Jitender M. Khurana, Anshika Lumb & Ankita Chaudhary

Authors
  1. Jitender M. Khurana
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  2. Anshika Lumb
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  3. Ankita Chaudhary
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Correspondence to Jitender M. Khurana.

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Khurana, J.M., Lumb, A. & Chaudhary, A. NaBrO3/bmim[HSO4]: a versatile system for the selective oxidation of 1,2-diols, α-hydroxyketones, and alcohols. Monatsh Chem 148, 381–386 (2017). https://doi.org/10.1007/s00706-016-1749-z

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