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Electrospun of functionalized mesoporous UiO-66 as the selective coating of solid phase microextraction Arrow for the determination of nine alkylphenols

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Abstract

A solid-phase microextraction (SPME) Arrow and high-performance liquid chromatography-UV detector (HPLC-UV, detection at 225 nm) based method was developed for the selective determination of nine alkylphenols (APs) in milk. The functionalized mesoporous UiO-66 (4-meso-UiO-66) was utilized as the new coating material, which was synthesized by post-modification of pore-expanded UiO-66-NH2 by an esterification reaction with 4-pentylbenzoic acid. It was fully characterized by X-ray photoelectron spectroscopy (XPS), fourier transformation infrared spectrometry, nitrogen sorption-desorption test, scanning electron microscopy, transmission electron microscopy, and X-ray diffractometer. The characterization results showed the ester groups and benzene rings were introduced into the 4-meso-UiO-66, and the mesoporous structure was predominant in the 4-meso-UiO-66. The extraction mechanism of 4-meso-UiO-66 to APs is the synergistic effect of Zr-O electrostatic interaction and the size exclusion effect resulting from XPS, selectivity test, and nitrogen sorption-desorption test. The electrospinning technique was utilized to fabricate the 4-meso-UiO-66 coated SPME Arrow and polyacrylonitrile (PAN) was used as the adhesive. The mass rate of 4-meso-UiO-66 to PAN and the electrospinning time were evaluated. The extraction and desorption parameters were also studied. The linear range of this method was 0.2–1000 μg L–1 with a coefficient of determination greater than 0.9989 under the optimal conditions. The detection limits were 0.05–1 μg L–1, the inter-day and intra-day precision (RSD) were 2.8–11.5%, and the recovery was 83.6%–112%. The reusability study showed that the extraction performance of this new SPME Arrow could be maintained after 80 adsorption-desorption cycles. This method showed excellent applicability for the selective determination of APs in milk.

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Acknowledgements

This research was funded by the National Natural Science Foundation of China (No. 32102060), the Key R&D Program of Zhejiang (No. 2022C02028), Eyas Program Incubation Project of Zhejiang Provincial Administration for Market Regulation (No. CY2023216) and the Ningbo Public Welfare Science and Technology Project (2021S195).

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  1. State Key Laboratory for Quality and Safety of Agro-Products, Zhejiang-Malaysia Joint Research Laboratory for Agricultural Product Processing and Nutrition and College of Food and Pharmaceutical Sciences, Ningbo University, Ningbo, 315800, China

    Peixun Yang, Xiaoyan Zhu, Hangzhen Lan & Daodong Pan

  2. Zhoushan Institute for Food and Drug Control, Zhoushan, 316012, China

    Yichun Wu

  3. Ningbo Customs Technology Center, Ningbo, 315048, China

    Xiaoyan Zhu

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  1. Peixun Yang
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Yang, P., Zhu, X., Lan, H. et al. Electrospun of functionalized mesoporous UiO-66 as the selective coating of solid phase microextraction Arrow for the determination of nine alkylphenols. Microchim Acta 191, 188 (2024). https://doi.org/10.1007/s00604-024-06248-w

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