Abstract
Nickel-titanium oxide nanotubes (NiTiONTs), nanoparticles, and nanopores were in situ grown on NiTi fiber substrates by controlling anodization parameters. The adsorption performance of different bimetallic oxide nanostructures was evaluated using typical aromatic compounds including chlorophenols, phthalic acid esters, ultraviolet filters (UVFs), and polycyclic aromatic hydrocarbons (PAHs) coupled to HPLC-UV. The results clearly indicate that these NiTiO nanostructures show good extraction capability for UVFs and PAHs. The extraction performance of UVFs and PAHs greatly depends on the surface morphologies and sizes of the grown NiTiO nanostructures along with their elemental compositions. Compared with NiTiO nanoparticle and nanopore coatings, the longer well-aligned NiTiONT coating exhibits better extraction capability and selectivity for PAHs than for UVFs. Therefore, the extraction parameters of the NiTi@NiTiONT fiber for PAHs were investigated and optimized. Under optimized conditions, the proposed method was linear in the range 0.05–200 μg L−1 with correlation coefficients above 0.999. Limits of detection were between 0.008 and 0.124 μg L−1. Relative standard deviations (RSDs) of the intra-day and the inter-day analyses with the single fiber varied from 4.09 to 6.33%. RSDs for fiber-to-fiber reproducibility of the proposed method with five fibers prepared in different batches were between 5.75 and 7.43%. The applicability of the proposed method was investigated by the enrichment and determination of target PAHs in environmental water samples and relative recoveries of 84.5 ± 6.5 – 116 ± 7.8% were achieved. Notably, the prepared fiber was stable up to 250 times.
Similar content being viewed by others
References
Arthur CL, Pawliszyn J (1990) Solid phase microextraction with thermal desorption using fused silica optical fibers. Anal Chem 62(19):2145–2148
Tian Y, Feng JJ, Bu YN, Wang XQ, Luo CN, Sun M (2017) In-situ hydrothermal synthesis of titanium dioxide nanorods on titanium wire for solid-phase microextraction of polycyclic aromatic hydrocarbons. Anal Bioanal Chem 409:4071–4078
Lashgaria M, Yaminia Y (2019) An overview of the most common lab-made coating materials in solid phase microextraction. Talanta 191:283–306
Piri-Moghadam H, Alam MN, Pawliszyn J (2017) Review of geometries and coating materials in solid phase microextraction: opportunities, limitations, and future perspective. Anal Chim Acta 984:42–65
Aziz-Zanjani MO, Mehdinia A (2014) A review on procedures for the preparation of coatings for solid phase microextraction. Microchim Acta 181:1169–1190
Zheng J, Huang JL, Yang Q, Ni CY, Xie XT, Shi YR, Sun JF, Zhu F, Ouyang GF (2018) Fabrications of novel solid phase microextraction fiber coatings based on new materials for high enrichment capability. Trends Anal Chem 108:135–153
Feng JJ, Loussala HM, Han S, Ji XP, Li CY, Sun M (2020) Recent advances of ionic liquids in sample preparation. Trend Anal Chem 125:115833
Mehdinia A, Aziz-Zanjani MO (2013) Recent advances in nanomaterials utilized in fiber coatings for solid-phase microextraction. Trends Anal Chem 42:205–215
Wang XQ, Feng JJ, Tian Y, Luo CN, Sun M (2018) Co-Al bimetallic hydroxide nanocomposites coating for online in-tube solid-phase microextraction. J Chromatogr A 1550:1–7
Aziz-Zanjani MO, Mehdinia A (2013) Electrochemically prepared solid-phase microextraction coatings. Anal Chim Acta 781:1–13
Feng JJ, Qiu HD, Liu X, Jiang SX (2013) The development of SPME fibers with metal wires as supporting substrates. Trends Anal Chem 46:44–58
Shabalovskaya S, Anderegg J, Van Humbeeck J (2008) Critical overview of Nitinol surfaces and their modifications for medical applications. Acta Biomater 4:447–467
Setkova L, Risticevic S, Linton CM, Ouyang GF, Bragg LM, Pawliszyn J (2007) Solid-phase microextraction–gas chromatography–time-of-flight mass spectrometry utilized for the evaluation of the new-generation super elastic fiber assemblies. Anal Chim Acta 581:221–231
Budziak D, Martendal E, Carasek E (2007) Preparation and application of NiTi alloy coated with ZrO2 as a new fiber for solid-phase microextraction. J Chromatogr A 1164:18–24
Budziak D, Martendal E, Carasek E (2008) New poly (ethylene glycol) solid-phase microextraction fiber employing zirconium oxide electrolytically deposited onto a NiTi alloy as substrate for sol-gel reactions. J Chromatogr A 1198–1199:54–58
Azenha M, Ornelas M, Silva AF (2009) Solid-phase microextraction Ni-Ti fibers coated with functionalized silica particles immobilized in a sol-gel matrix. J Chromatogr A 1216:2302–2306
Dias AN, Simão V, Merib J, Carasek E (2013) Cork as a new (green) coating for solid-phase microextraction: determination of polycyclic aromatic hydrocarbons in water samples by gas chromatography–mass spectrometry. Anal Chim Acta 772:33–39
Ho TD, Toledo BR, Hantao LW, Anderson JL (2014) Chemical immobilization of crosslinked polymeric ionic liquids on nitinol wires produces highly robust sorbent coatings for solid-phase microextraction. Anal Chim Acta 843:18–26
Pacheco-Fernández I, Najafi A, Pino V, Anderson JL, Ayala JH, Afonso AM (2016) Utilization of highly robust and selective crosslinked polymeric ionic liquid-based sorbent coatings in direct-immersion solid-phase microextraction and high-performance liquid chromatography for determining polar organic pollutants in waters. Talanta 158:125–133
Zhang M, Zhen Q, Wang HJ, Guo M, Zhou SS, Wang XM, Du XZ (2016) Innovative fabrication of the flower-like nanocomposite coating on a nitinol fiber through Fenton’s oxidation for selective and sensitive solid-phase microextraction. Talanta 158:214–221
Wang HJ, Song WL, Zhang M, Zhen Q, Guo M, Zhang YD, Du XZ (2016) Hydrothermally grown and self-assembled modified titanium and nickel oxide composite nanosheets on Nitinol-based fibers for efficient solid phase microextraction. J Chromatogr A 1468:33–41
Zhou SS, Wang HJ, Jin PX, Wang ZY, Wang XM, Du XZ (2018) An effective strategy for controlled fabrication and self-assembled modification of template-supported silica nanosheets on a superelastic nickel-titanium alloy fiber for highly efficient solid-phase microextraction. J Chromatogr A 1569:17–25
Du JJ, Wang HJ, Zhang R, Wang XM, Du XZ, Lu XQ (2018) Oriented ZnO nanoflakes on nickel-titanium alloy fibers for solid-phase microextraction of polychlorinated biphenyls and polycyclic aromatic hydrocarbons. Microchim Acta 185:1–9
Hu QK, Liu SQ, Chen X, Xu JQ, Zhu F, Ouyang GF (2019) Enhancing enrichment ability of a nanoporous carbon based solid-phase microextraction device by a morphological modulation strategy. Anal Chim Acta 1047:1–8
Hang RQ, Liu YL, Zhao LZ, Gao A, Bai L, Huang XB, Zhang XY, Tang B, Chu PK (2014) Fabrication of Ni-Ti-O nanotube arrays by anodization of NiTi alloy and their potential applications. Sci Rep 4(7547):1–9
Chen X, Mao SS (2007) Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications. Chem Rev 107(7):2891–2959
Xu J, Wu P, Ye EC, Yuan BF, Feng YQ (2016) Metal oxides in sample pretreatment. Trends Anal Chem 80:41–56
Liu HM, Wang DA, Ji L, Li JB, Liu SJ, Liu X, Jiang SX (2010) A novel TiO2 nanotube array/Ti wire incorporated solid-phase microextraction fiber with high strength, efficiency and selectivity. J Chromatogr A 1217:1898–1903
Li Y, Zhang M, Yang YX, Wang XM, Du XZ (2014) Electrochemical in situ fabrication of titanium dioxide-nanosheets on a titanium wire as a novel coating for selective solid-phase microextraction. J Chromatogr A 1358:60–67
Es-haghi A, Hosseininasab V, Bagheri H (2014) Preparation, characterization, and applications of a novel solid-phase microextraction fiber by sol-gel technology on the surface of stainless steel wire for determination of polycyclic aromatic hydrocarbons in aquatic environmental samples. Anal Chim Acta 813:48–55
Li QL, Wang XF, Yuan DX (2009) Preparation of solid-phase microextraction fiber coated with single-walled carbon nanotubes by electrophoretic deposition and its application in extracting phenols from aqueous samples. J Chromatogr A 1216:1305–1311
Song XL, Chen Y, Yuan JP, Qin YJ, Zhao RS, Wang X (2016) Carbon nanotube composite microspheres as a highly efficient solid-phase microextraction coating for sensitive determination of phthalate acid esters in water samples. J Chromatogr A 1468:17–22
Doong RA, Chang SM, Sun YC (2000) Solid-phase microextraction for determining the distribution of sixteen US environmental protection agency polycyclic aromatic hydrocarbons in water samples. J Chromatogr A 879:177–188
Zhang YD, Yao YX, Li Y, Zhang M, Wang XM, Du XZ (2015) Growth of cedar-like Au nanoparticles coating on an etched stainless steel wire and its application for selective solid-phase microextraction. Anal Chim Acta 876:55–62
Tian Y, Feng JJ, Wang XQ, Sun M, Luo CN (2018) Silicon carbide nanomaterial as a coating for solid-phase microextraction. J Sep Sci 41:1995–2002
Jiang H, Hu XR, Li Y, Qi JW, Sun XY, Wang LJ, Li JS (2019) Large-pore ordered mesoporous carbon as solid-phase microextraction coating for analysis of polycyclic aromatic hydrocarbons from aqueous media. Talanta 195:647–654
Wang FX, Zheng J, Qiu JL, Liu SQ, Chen GS, Tong Y, Zhu F, Ouyang GF (2017) In situ hydrothermally grown TiO2@C core-shell nanowire coating for highly sensitive solid phase microextraction of polycyclic aromatic hydrocarbons. ACS Appl Mater & Inter 9:1840–1846
Sposito G (1998) On points of zero charge. Environ Sci Technol 32:2815–2819
Funding
This study was funded by the National Natural Science Foundation of China (Grant No. 21765020).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Competing interests
The authors declare that they have no competing interests.
Conflict of interest
The authors declare that they have no competing of interests.
Additional information
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Electronic supplementary material
ESM 1
(PDF 1155 kb)
Rights and permissions
About this article
Cite this article
Liu, Y., An, C., Zhang, R. et al. Modulating the selectivity of solid-phase microextraction fibers based on morphological, compositional, and size-depended control of bimetallic oxide nanostructures grown on nickel-titanium alloy substrates. Microchim Acta 187, 501 (2020). https://doi.org/10.1007/s00604-020-04481-7
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00604-020-04481-7