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A triazine based organic framework with micropores and mesopores for use in headspace solid phase microextraction of phthalate esters

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Abstract

A dual-pore covalent organic framework (COF) that contains micropores and mesopores was prepared from 2,4,6-triphenoxy-1,3,5-triazine (TPT). A building block is used in which double linking sites were introduced at each branch of a C3-symmetric skeleton. The COF is shown to be a viable coating for fibers for solid-phase microextraction of phthalic acid esters (PAEs). Its high specific surface, high hydrophobicity, and wide pore size distribution of a TPT-COF coated fiber result in extraordinarily powerful extraction of PAEs. The enrichment factor is up to 7790 under optimum conditions. The method has detection limits that range between 5 and 95 ng L−1. The inter-batch relative standard deviations are between 3.1 and 10.9%, and those for intra-batch assays are from 0.8 to 4.7%. The TPT-COF coated fibers were applied to the extraction of PAEs from (spiked) juice samples, and satisfactory recoveries were achieved.

TPT-COF coated SPME fiber was prepared for the preconcentration of phthalate esters coupled with GC-FID.

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Acknowledgements

The project was supported by Open Project of State Key Laboratory of Supramolecular Structure and Materials, Jilin University, China (sklssm201815).

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Authors and Affiliations

  1. College of Chemistry, Jilin University, Changchun, 130012, China

    Huihua Guo, Gang Chen, Jiutong Ma & Qiong Jia

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  1. Huihua Guo
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  2. Gang Chen
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Correspondence to Jiutong Ma.

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Guo, H., Chen, G., Ma, J. et al. A triazine based organic framework with micropores and mesopores for use in headspace solid phase microextraction of phthalate esters. Microchim Acta 186, 4 (2019). https://doi.org/10.1007/s00604-018-3060-7

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