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The study of humidity sensor based on Li-doped ZnO nanorods by hydrothermal method

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Abstract

In this study, we report the one-dimension Li doped ZnO nanorods (NRs) on glass substrates with hydrothermal method, and the fabrication of Li doped ZnO NRs humidity sensors. It was found that the as-grown Li doped ZnO NRs were structurally evenly with a wurtzite structure. The relative humidity (RH) effect factor was found to be dependent on the ultraviolet (UV) illumination of humidity sensors with a nanostructure. During UV illumination, it was also found that photocurrent to dark current contrast ratios were approximately 17.6 and 14.5, when measured with RHs of 30 and 80%, respectively, at 5.0 V applied bias. The competitive surface effects of a great quantity oxygen/water to explain the observed variations in UV photodetector under different relative humidity conditions.

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References

  • Assunção V, Fortunato E, Marques A, Águas H, Ferreira I, Costa MEV (2003) Influence of the deposition pressure on the properties of transparent and conductive ZnO: Ga thin-film produced by r.f. sputtering at room temperature. Thin Solid Films 427:401–405

    Article  Google Scholar 

  • Baruah S, Dutta J (2009) Hydrothermal growth of ZnO nanostructures. Sci Technol Adv Mater 10:013001(19)

    Article  Google Scholar 

  • Calestani D, Culiolo M, Villani M, Delmonte D, Solzi M, Kim TY, Kim SW, Marchini L, Zappettini A (2018) Functionalization of carbon fiber tows with ZnO nanorods for stress sensor integration in smart composite materials. Nanotechnology 29:596–600

    Article  Google Scholar 

  • Chang YC, Hsu CC, Wu SH, Chuang KW, Chen YF (2018) Fabrication of Cu-doped ZnO nanoneedles on different substrate via wet chemical approach: structural characterization and photocatalytic performance. Appl Surf Sci 447:213–221

    Article  Google Scholar 

  • Chen TP, Young SJ, Chang SJ, Hsiao CH, Huang CS (2012) Field-emission and photoelectrical characteristics of ZnO nanorods photodetectors prepared on flexible substrate. J Electrochem Soc 159(5):J153–J157

    Article  Google Scholar 

  • Chen TP, Young SJ, Chang SJ, Hsiao CH, Ji LW, Hsu YJ, Wu SL (2013) Low-frequency noise characteristics of ZnO nanorods schottky barrier photodetectors. IEEE Sens J 13(6):2115–2119

    Article  Google Scholar 

  • Cho Y, Ji H, Kim H, Yoon J, Choi B (2018) New insights into mechanism of surface reactions of ZnO nanorods during electrons beam irradiation. J Nanosci Nanotechnol 18:5996–6000

    Article  Google Scholar 

  • Djurisic AB et al (2006) Optical properties of ZnO nanostructures. Small 2:944–961

    Article  Google Scholar 

  • Fowler RH, Nordheim L (1928) Electron emission in intense electric fields. Series A 119:173–181

    MATH  Google Scholar 

  • Hamid NMA, Celik-Butler Z (2018) Characterization and performance analysis of Li-doped ZnO nanowire as a nano-sensor and nano-energy harvesting element. Nano Energy 50:159–168

    Article  Google Scholar 

  • Hsiao CH, Huang CS, Young SJ, Chang SJ, Guo JJ, Liu CW, Chang SJ (2013) Optical and structural properties of Ga-doped ZnO nanorods. J Nanosci Nanotechnol 13(12):8320–8324

    Article  Google Scholar 

  • Hsu CL, Hsu DX, Hsueh TJ, Chang SP, Chang SJ (2017) Transparent gas senor and photodetector based on Al doped ZnO nanowires synthesized on glass substrate. Ceram Int 43:5434–5440

    Article  Google Scholar 

  • Jeong SH, Boo JH (2008) Study on the doping effect of Li-doped ZnO film. Thin Solid Films 516:5586–5589

    Article  Google Scholar 

  • Jeong SH, Park BN, Lee SB, Boo JH (2005) Structural and optical properties of silver-doped zinc oxide sputtered films. Surf Coat Technol 193:340

    Article  Google Scholar 

  • Joseph M, Tabata H, Kawai T (1999) Ferroelectric behavior of Li-doped ZnO thin films on Si(100) by pulsed laser deposition. Appl Phys Lett 74:2534

    Article  Google Scholar 

  • Kwon J, Hong S, Kim G, Suh YD, Lee H, Choo SY, Lee D, Kong H, Yeo J, Ko SH (2018) Digitally patterned resistive micro heater as a platform for zinc oxide nanowire based micro sensor. Appl Surf Sci 447:1–7

    Article  Google Scholar 

  • Lai LT, Chang SJ, Yang CC, Young SJ (2018) UV-enhanced 2D nanostructured ZnO field emitter with adsorbed Pt nanoparticles. IEEE Electron Device Lett 39(12):1932–1935

    Article  Google Scholar 

  • Lei SJ, Tao CJ, Li JL, Zhao X, Wang WZ (2018) Visible light-induced charge transfer to improve sensitive surface-enhanced Raman scattering of ZnO/Ag nanorod arrays. Appl Surf Sci 452:148–154

    Article  Google Scholar 

  • Liang S, Sheng H, Liu Y, Huo Z, Lu Y, Shen H (2001) ZnO Schottky ultraviolet photodetectors. J Cryst Growth 225:110–113

    Article  Google Scholar 

  • Liu JM, Xia YB, Wang LJ, Su QF, Shi WM (2007) Effect of grain size on the electrical properties of ultraviolet photodetector with ZnO/diamond film structure. J Cryst Growth 300:353–357

    Article  Google Scholar 

  • Liu YH, Young SJ, Ji LW, Chang SJ (2014) enhanced field emission properties of Ga-doped ZnO nanosheets by using an aqueous solution at room temperature. IEEE Trans Electron Devices 61(12):4192–4196

    Article  Google Scholar 

  • Liu YH, Young SJ, Ji LW, Chang SJ (2015) UV enhanced field emission properties of Ga-doped ZnO nanosheets. IEEE Trans Electron Devices 62:2033–2037

    Article  Google Scholar 

  • Liu YH, Chang SJ, Young SJ (2016) enhanced field emitter base on indium-doped ZnO nanostructures by aqueous solution. ECS J Solid State Sci Technol 5(12):R203–R205

    Article  Google Scholar 

  • Rathore N, Sarkar SK (2016) Dopant induced polarity inversion in polar ZnO nanorods. J Mater Sci-Mater Electron 27:12312–12317

    Article  Google Scholar 

  • Spemann D, Kaidashev EM, Lorenz M, Vogt J, Butz T (2004) Ion beam analysis of epitaxial (Mg, Cd)xZn1−xO and ZnO:(Li, Al, Ga, Sb) thin films grown on c-plane sapphire. Nucl Instrum Methods Phys Res B Beam Interact Mater Atoms 891:219–220

    Google Scholar 

  • Tyagi AK, Jayakumar OD, Sudarsan V (2010) Tunable Ferromagnetism accompanied by Morphology Control in Li-doped Zn0.97Ni0.03O. J Phys Chem C 114:17428

    Article  Google Scholar 

  • Vanheusden K et al (1996) Mechanisms behind green photoluminescence in ZnO phosphor powders. J Appl Phys 79:7983–7990

    Article  Google Scholar 

  • Wang XS, Wu ZC, Webb JF, Liu ZG (2003) Ferroelectric and dielectric properties of Li-doped ZnO thin films prepared by pulsed laser deposition. Appl Phys A 77:561

    Article  Google Scholar 

  • Yang CC, Su YK, Hsiao CH, Young SJ, Kao TH, Chung MY, Huang YC, Wang BC, Wu SL (2014) Novel Ga-ZnO nanosheet structures applied in ultraviolet photodetectors. IEEE Photonics Technol Letters 26(13): 1317–1320

  • Yao CB, Zhang KX, Wen X, Li J, Li QH, Yang SB (2017) Morphologies, field-emission and ultrafast nonlinear optical behavior of pure and Ag-doped ZnO nanostructures. J Alloy Compd 698:284–290

    Article  Google Scholar 

  • Yogamalar NR, Chandra Bose A (2011) Burstein-Moss shift and room temperature near-band-edge luminescence in lithium-doped zinc oxide. Appl Phys A 33–42

  • Yoon IT, Cho HD, Lee S, Roshchupkin DV (2018) Enhanced structural and luminescent properties of carbon-assisted ZnO nanorod arrays on (100) Si substrate. J Electron Mater 47:4404–4411

    Article  Google Scholar 

  • Young SJ, Lai LT (2015) Field emission properties of ZnO nanosheets grown on a Si substrate. Microelectron Eng 148:40–43

    Article  Google Scholar 

  • Young SJ, Liu YH (2016) Ultraviolet photodetectors with 2-D indium-doped ZnO nanostructures. IEEE Trans Electron Devices 63(8):3160–3164

    Google Scholar 

  • Young SJ, Lai LT (2018) Electron field emission enhancement based on Pt-adsorbed ZnO nanorods with UV irradiation. IEEE Trans Nanotechnol 17(5):1063–1068

    Article  Google Scholar 

  • Young SJ, Wang TH (2018) ZnO nanorods adsorbed with photochemical Ag nanoparticles for IOT and field electron emission application. J Electrochem Soc 165(8): B3043–B3045

  • Young SJ, Tang WL (2019) Wireless zinc oxide based pH sensor system. J Electrochem Soc 169(9): B3047–B3050

  • Young SJ, Yuan KW (2019a) ZnO nanorod humidity sensor and dye-sensitized solar cells as a self-powered device. IEEE Trans Electron Devices 66(9):3978–3981

    Article  Google Scholar 

  • Young SJ, Yuan KW (2019b) Self-Powered ZnO Nanorod Ultraviolet Photodector Integrated with Dye-Sensitized Solar Cell. J Electrochem Soc 166(12):B1034–B1037

    Article  Google Scholar 

  • Young SJ, Yang CC, Lai LT (2017) Review—growth of Al-, Ga-, and In-doped ZnO nanostructures via a low-temperature process and their application to field emission devices and ultraviolet photosensors. J Electrochem Soc 164(5):B3013–B3028

    Article  Google Scholar 

  • Young SJ, Liu YH, Chien JT (2018) Improving field electron emission properties of ZnO nanosheets with Ag nanoparticles adsorbed by photochemical method. ACS Omega 3(7): 8135–8140

  • Young SJ, Lai LT, Tang WL (2019) Improving the performance of pH sensors with one-dimensional ZnO nanostructures. IEEE Sensors J 19(23): 10972–10976

  • Yu M, Ma YX, Liu JH, Li XJ, Li SM, Liu SY (2016) Sub-coherent growth of ZnO nanorod arrays on three-dimensional graphene framework as one-bulk high-performance photocatalyst. Appl Surf Sci 390:266–272

    Article  Google Scholar 

  • Zhang C, Huang XH, Liu HF, Chua SJ, Ross CA (2016) Large-area zinc oxide nanorod arrays templated by nanoimprint lithography: control of morphologies and optical properties. Nanotechnology 27:73–80

    Google Scholar 

  • Zhou Y, Li X, Yu HY, Hu GL, Yao JM (2016) Facile fabrication of controllable zinc oxide nanorod clusters on polyacrylonitrile nanofibers via repeatedly alternating immersion method. J Nanopart Res 18:359–364

    Article  Google Scholar 

  • Zhu Q, Cai FD, Zhang J, Zhao K, Deng AP, Li JG (2016) Highly sensitive electrochemiluminescent immunosensor based on gold nanoparticles-functionalized zinc oxide nanorod and poly (amidoamine)-graphene for detecting brombuterol. Biosens Bioelectron 86:899–906

    Article  Google Scholar 

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Correspondence to Chun-Chi Chou.

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Chou, CC., Shih, LH. & Chang, SJ. The study of humidity sensor based on Li-doped ZnO nanorods by hydrothermal method. Microsyst Technol 28, 423–427 (2022). https://doi.org/10.1007/s00542-020-04957-9

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