Abstract
In this paper, ZnO nano thin film is prepared on n-type Si substrate with <100> orientation using RF sputtering technique and a surface acoustic wave (SAW) based fluorine (F2) gas sensor integrated on ZnO with Palladium (Pd) on top as sensing layer is fabricated and characterized. The input and output interdigital transducer is fabricated of aluminum (Al) using nanolithography technique. The morphological characterization of ZnO thin film is done using scanning electron microscopy and atomic force microscopy. The XRD confirms the formation of ZnO nanostructured thin film. The voltage handling capability of the fabricated device is evaluated with negative and positive bias voltage. The study confirms that the SAW sensor based on ZnO/Si substrate and Pd sensing layer has good characteristic response of F2 gas with different concentration of gas from 0.5 to 20 ppm. The sensor shows good reproducibility and its sensitivity is approximately 2.4 kHz ppm−1.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00542-014-2277-6/MediaObjects/542_2014_2277_Fig1_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00542-014-2277-6/MediaObjects/542_2014_2277_Fig2_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00542-014-2277-6/MediaObjects/542_2014_2277_Fig3_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00542-014-2277-6/MediaObjects/542_2014_2277_Fig4_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00542-014-2277-6/MediaObjects/542_2014_2277_Fig5_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00542-014-2277-6/MediaObjects/542_2014_2277_Fig6_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00542-014-2277-6/MediaObjects/542_2014_2277_Fig7_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00542-014-2277-6/MediaObjects/542_2014_2277_Fig8_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00542-014-2277-6/MediaObjects/542_2014_2277_Fig9_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00542-014-2277-6/MediaObjects/542_2014_2277_Fig10_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00542-014-2277-6/MediaObjects/542_2014_2277_Fig11_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00542-014-2277-6/MediaObjects/542_2014_2277_Fig12_HTML.gif)
Similar content being viewed by others
References
Anderson RB (1946) Modifications of the Brunauer, Emmett and Teller equation 1. J Am Chem Soc 68:686–691
Brunauer S, Emmett PH, Teller EJ (1938) The adsorption of gases in multimolecular layers. J Am Chem Soc 60:309
Dang WL, Fu YQ, Luo JK, Flewitt AJ, Milne WI (2007) Deposition and characterization of sputtered ZnO films. Superlattice Microstruct 42:89–93
Eisermann S, Sann J, Polity A, Meyer BK (2009) Sputter deposition of ZnO thin films at high substrate temperatures. Thin Solid Films 517:5805–5807
Ekem N, Korkmaz S, Pat S, Balbag MZ, Cetin EN, Ozmumcu M (2009) Int J Hydrogen Energy 34:5218–5222
Gao XD, Li XM, Yu WD (2005) Rapid preparation, characterization, and photoluminescence of ZnO films by a novel chemical method. Mater Res Bull 40:1104–1111
Hashim AJ, Jaafar MS, Ghazai AJ, Ahmed NM (2013) Fabrication and characterization of ZnO thin film using sol–gel method. Optik 124:491–492
Hickernell FS (1985) Zinc oxide films for acoustoelectric device applications. IEEE Trans Sonic Ultrason 32:621–629
Horrillo MC, Fernandez MJ, Fontecha JL, Sayago I, Garcia M, Aleixandre M, Gutierrez J, Gracia I, Cane C (2006) Optimization of SAW sensors with a structure ZnO–SiO 2–Si to detect volatile organic compounds. Sens Actuators B Chem 118:356–361
Jeong SH, Lee JW, Lee SB, Boo JH (2003) Deposition of aluminum-doped zinc oxide films by RF magnetron sputtering and study of their structural, electrical and optical properties. Thin Solid Films 435:78–82
Kato Y, Yoshikawa K, Kitora M (1997) Temperature-dependent dynamic response enables the qualification and quantification of gases by a single sensor. Sens Actuators B 40:33–37
Khan S, Arya S, Lehana P (2013) Modeling and design of AlN based SAW device and effect of reflected bulk acoustic wave generated in the device. J Nano Electron Phys 5:02010
Lantto V, Romppainen P (1988) Response of some SnO2 gas sensors to H2S after quick cooling. J Electrochem Soc 135:2550–2556
Lee JB, Lee MH, Park CK, Park JS (2004) Effects of lattice mismatches in ZnO/substrate structures on the orientations of ZnO films and characteristics of SAW devices. Thin Solid Films 447:296–301
Lim C, Wang W, Yang S, Lee K (2011) Development of SAW-based multi-gas sensor for simultaneous detection of CO2 and NO2. Sens Actuators B Chem 154:9–16
Liu J, Lu Y (2014) Response mechanism for surface acoustic wave gas sensors based on surface-adsorption. Sensors 14:6844–6853
Liu J, Wang W, Li S, Liu M, He S (2011) Advances in SAW gas sensors based on the condensate-adsorption effect. Sensors 11:11871–11884
Meulendyk BJ, Wheeler MC, da Cunha MP (2011) Hydrogen fluoride gas detection mechanism on quartz using SAW sensors. IEEE Sens J 11:1768–1775
Min YS, An CJ, Kim SK, Song J, Hwang CS (2010) Growth and characterization of conducting ZnO thin films by atomic layer deposition. Bull Korean Chem Soc 31:2503
Nakata S, Nakamura H, Yoshikawa K (1992) New strategy for development of a gas sensor based on the dynamic characteristics: principle and preliminary experiment. Sens Actuators B 8:187–189
Nakata S, Nakasuji M, Ojima N, Kitora M (1998) Characteristic nonlinear responses for gas species on the surface of different semiconductor gas sensors. Appl Surf Sci 135:285–292
Penza M, Vasanelli L (1997) SAW NO x gas sensor using WO3 thin-film sensitive coating. Sens Actuators B Chem 41:31–36
Penza M, Aversa P, Cassano G, Wlodarski W, Zadeh KK (2007) Layered SAW gas sensor with single-walled carbon nanotube-based nanocomposite coating. Sens Actuators B Chem 127:168–178
Rao YL, Zhang G (2006) 3-D finite element modeling of nanostructure enhanced SAW sensor. Excerpt from the Proceedings of COMSOL User Conference, Boston
Romppainen P, Lantto V, Leppavuori S (1990) Effect of water vapour on the CO response behaviour of tin dioxide sensors in constant temperature and temperature-pulsed modes of operation. Sens Actuators B 1:73–78
Rosa AM, Silva EPD, Amorim E, Chaves M, Catto AC, Filho PNL, Bortoleto JRR (2012) Growth evolution of ZnO thin films deposited by RF magnetron sputtering. J Phys Conf Ser 370:012020
Roy S, Basu S (2002) Improved zinc oxide film for gas sensor applications. Bull Mater Sci 25:513–515
Tasaltin C, Ebeoglu MA, Ozturk ZZ (2012) Acoustoelectric effect on the responses of SAW sensors coated with electrospun ZnO nanostructured thin film. Sensors 12:12006–12015
Wen C, Zhu C, Ju Y, Xu H, Qiu Y (2010) A novel NO2 gas sensor using dual track SAW device. Sens Actuators A Phys 159:168–173
Wohltjen H (1984) Mechanism of operation and design considerations for surface acoustic wave device vapour sensors. Sens Actuators 5:307–325
Zhang Y, Du G, Yang X, Zhao B, Ma Y, Yang T, Ong HC, Liu D, Yang S (2004) Effect of annealing on ZnO thin films grown on (001) silicon substrate by low-pressure metal organic chemical vapour deposition. Semicond Sci Technol 19:755
Acknowledgments
This work was done using the facilities of Centre of Excellence in Nanoelectronics (CEN) under INUP Program at Indian Institute of Technology, Bombay (IITB).
Conflict of interest
This work is related to the PhD work carried by the first author and the authors declare that there is no conflict of interest.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Khan, S., Arya, S., Kumar, S. et al. Fabrication and characterization of highly sensitive ZnO/Si SAW device with Pd selective layer for F2 gas sensing. Microsyst Technol 21, 2011–2017 (2015). https://doi.org/10.1007/s00542-014-2277-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00542-014-2277-6