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Investigating fossil hydrothermal systems by means of fluid inclusions and stable isotopes in banded travertine: an example from Castelnuovo dell’Abate (southern Tuscany, Italy)

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Abstract

Southern Tuscany (Italy) hosts geothermal anomalies with associated widespread CO2 gas-rich manifestations and active travertine-deposing thermal springs. Geothermal anomalies have been active since the Late Miocene and have led to the formation of widespread Late Miocene–Pleistocene travertine deposits and meso- and epithermal mineralizations. This study investigates the travertine deposit exposed in the Castelnuovo dell’Abate area of southern Tuscany. Here, a fissure-ridge type travertine deposit and its feeding conduits, currently filled with banded calcite veins (i.e. banded travertine), represent a spectacular example of fossil hydrothermal circulation in the peripheral area of the exploited Monte Amiata geothermal field. The Castelnuovo dell’Abate travertine deposit and associated calcite veins were analysed to establish the characteristics of the parent hydrothermal fluids, and the age of this circulation. The focus of the study was on fluid inclusions, rarely considered in travertine studies, but able to provide direct information on the physico-chemical characteristics of the original fluid. Uranium–thorium geochronological data provided further constraints on the: (1) age of tectonic activity; (2) age of the hydrothermal circulation; and (3) evolution of the Monte Amiata geothermal anomaly. Results indicate that brittle deformation (NW- and SE-trending normal to oblique-slip faults) was active during at least the Middle Pleistocene and controlled a hydrothermal circulation mainly characterized by fluids of meteoric origin, and as old as 300–350 ka. This is the oldest circulation documented to date in the Monte Amiata area. The fluid chemical composition is comparable to that of fluids currently exploited in the shallow reservoir of the Monte Amiata geothermal field, therefore suggesting that fluid composition has not changed substantially over time. These fluids, however, have cooled by about 70 °C in the last 300–350 ka, corresponding to a cooling rate of the Monte Amiata geothermal area of about 20 °C 100 ka−1.

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Acknowledgments

This study was financially supported by MIUR PRIN 2010–2011 to P. Costagliola and P. Lattanzi. This research was accomplished thanks to the scientific instruments provided by the Ente Cassa di Risparmio di Firenze to the Dipartimento di Scienze della Terra (Università di Firenze). Radiometric age data were obtained using funds provided by the Australian National Centre for Groundwater Research and Training (Program 3). Elena Pecchioni and Mario Paolieri (Università di Firenze) are also gratefully thanked for their assistance during XRD and SEM–EDS analysis. Two anonymous reviewers are also thanked for their help to improve the manuscript.

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Authors and Affiliations

  1. CNR - Istituto di Geoscienze e Georisorse, Via G. La Pira 4, 50121, Florence, Italy

    Valentina Rimondi & Giovanni Ruggieri

  2. Dipartimento di Scienze della Terra, Università di Firenze, Via G. La Pira 4, 50121, Florence, Italy

    Pilario Costagliola & Marco Benvenuti

  3. CNR - Istituto di Geoscienze e Georisorse, Via Moruzzi 1, 56124, Pisa, Italy

    Chiara Boschi

  4. Dipartimento di Scienze della Terra e Geoambientali, Università di Bari, Via Orabona 4, 70125, Bari, Italy

    Andrea Brogi & Domenico Liotta

  5. Dipartimento di Fisica e Geologia, Università di Perugia, Via Pascoli, 06123, Perugia, Italy

    Enrico Capezzuoli

  6. School of Earth Sciences, The University of Queensland, St Lucia, QLD, 4072, Australia

    Guia Morelli & Massimo Gasparon

  7. Australian National Centre for Groundwater Research and Training, The University of Queensland, St Lucia, QLD, 4072, Australia

    Massimo Gasparon

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  1. Valentina Rimondi
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  2. Pilario Costagliola
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Correspondence to Valentina Rimondi.

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Rimondi, V., Costagliola, P., Ruggieri, G. et al. Investigating fossil hydrothermal systems by means of fluid inclusions and stable isotopes in banded travertine: an example from Castelnuovo dell’Abate (southern Tuscany, Italy). Int J Earth Sci (Geol Rundsch) 105, 659–679 (2016). https://doi.org/10.1007/s00531-015-1186-y

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  • DOI: https://doi.org/10.1007/s00531-015-1186-y

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