Abstract
Magmatism plays a key role in accommodating and localizing extension during continental breakup. However, how the crustal magmatic systems evolve at the continental-ocean transition is poorly understood. We address these questions by studying the evolution of the magmatic system in the rift of Central Afar (Ethiopia), currently marking the transition from continental rifting to oceanic spreading. We focus on the voluminous and widespread Upper Stratoid Series (2.6–1.1 Ma) and the following Central Afar Gulf Series (1.1–0.6 Ma), the latter corresponding to localization of volcanism in narrow magmatic segments. We carried out the first systematic study of major and trace element mineral chemistry for these two Series and integrated it with geothermobarometry estimates and geochemical modeling, to reconstruct the evolution of the magmatic system architecture during rift localization. The Upper Stratoid magmas evolved by fractional crystallization in a melt-rich, moderately zoned, middle-lower crustal (10–18 km) magmatic system, from where they rose directly to the surface. Polybaric plagioclase convection and dissolution of a plagioclase-rich crystal mush is recorded in the phenocryst texture and chemistry. The Central Afar Gulf magmas evolved at similar depth in a more complex and dynamic storage system, with magma rising and mixing through multiple, relatively small, crystal-rich and interconnected reservoirs. Our study documents the transition during the continental breakup, from an overall stable and melt-rich magmatic system feeding the voluminous and homogeneous Upper Stratoid eruptions to a more dynamic, interconnected and crystal-rich situation feeding small-volume eruption while the rift localizes.
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Introduction
The changes in magmatic system architecture during rifting are linked to the evolution of magma intrusion and volcanism in space and time (Su et al. 2021; Nicotra et al. 2021; Hutchison et al. 2018; Caracciolo et al. 2023). Volcanic activity can change drastically during rifting (Storch et al. 2020; Franceschini et al. 2020; Pouclet et al. 2018; Shillington et al. 2009; Brune et al. 2023) due to variation in mantle source melting, extension rate or volatile release (Muirhead et al. 2016; White and McKenzie 1989; White 1992). Bimodal volcanism has been observed in several Continental Flood Basalt (CFB) eruptions, typically taking place at the beginning of the continental breakup process (Natali et al. 2011; Webb et al. 2019; Ukstins et al. 2002). During subsequent rift evolution, the nature of the magmatism is also variable in erupted volumes and composition, alternating between mafic- and silicic-dominated volcanism (Rooney 2020a; Goswami et al. 2020; Dostal et al. 2017). Taking as an example the Ethiopian rift, continental rifting is initially associated with large-scale silicic volcanic events (Rooney 2020b; Wolfenden et al. 2005; Stab et al. 2016) followed by widespread fissural basaltic volcanism (Stab et al. 2016; Tortelli et al. 2022; Rooney 2020b) then by silicic central volcanism (Lahitte et al. 2003a), and lastly by localized volcanism and intrusion in magmatic segments (Mohr et al. 1978; Ebinger and Casey 2001; Siegburg et al. 2018).
In the last few years, several lines of evidence suggest that vertically stacked mush-magma-host rock magmatic systems exist in different geological settings (Cashman et al. 2017; Sparks et al. 2019; Neave et al. 2013; Caracciolo et al. 2023; Biggs et al. 2021; Chambers et al. 2021). Studies of the magmatic system during rift evolution suggest a progressive shallowing of the magma reservoirs (Fitton et al. 1998; Fowler et al. 2004). The magmatic system architecture of the most recent stage of the rifting process (magmatic segments) are well studied and reasonably well understood. For example, the seismic velocity and anisotropic structure of the rift valley crust suggests the plumbing system beneath the magmatic segments transitions from sill- to dyke-dominated storage mechanism as the rift widens (Chambers et al. 2021). Petrological constraints show this is associated with reservoir shallowing, decrease in magma storage time, and increase in erupted volumes of basaltic lava (Hutchison et al. 2018). However, the magmatic systems architecture of the rift prior, and leading up to, the localized volcanism in the magmatic segments is still poorly understood. In order to address this, in this work we use mineral chemistry data of a range of volcanic rocks from the Afar rift, at the transition from widespread volcanism to localized magmatic segments.
The Afar depression is an excellent place to study the evolution of a magmatic system in relation to the ongoing continental-oceanic transition. Here we focus on the Red Sea rift branch activity in Central Afar, where the voluminous and widespread Upper Stratoid Series (hereafter US) are followed by more localized emplacement of the Central Afar Gulf Series (hereafter CAG), marking the transition from wider to localized rifting along the Tendaho-Manda Hararo segment (Fig. 1; Stab et al. 2016; Tortelli et al. 2022). We used a petrologic and geochemical approach based on mineral chemistry and phenocryst texture to investigate the magmatic system evolution during rift localization in Central Afar.
Geological and volcanological background
The study area is located at the intersection of the northernmost portion of the East African Rift System (i.e., Main Ethiopian Rift, MER) with the Red Sea and Gulf of Aden rifts in the Afar region to form a rift-rift-rift triple junction (Fig. 1A). In Afar, the transition from continental rifting to oceanic spreading is underway and exposed subaerially (Bastow and Keir 2011; Bastow et al. 2018). The onset of the activity is thought to be related to the arrival of a mantle plume around 45 Ma and the emplacement of the Ethiopian flood basalt volcanic successions, continuing at least until 30 Ma (Ebinger et al. 1993; Rooney 2017; Pik et al. 1999; Hofmann et al. 1997). The rifting between the Arabia, Nubia and Somalian plates started around ~ 35 Ma in the Gulf of Aden rift, at ~ 27.5–23.8 Ma in Red Sea rift (Fournier et al. 2010; Bosworth et al. 2005) while seafloor spreading started at ∼20 Ma in the Gulf of Aden (Fournier et al. 2010) and at ~ 4 Ma in the south-central Red Sea (Cochran 1983).
Due to the asynchronous development of multiple rift branches in Afar, the ages of individual Series commonly differ between the rifts (Lahitte et al. 2003b; Le Gall et al. 2015; Rime et al. 2023). However, magmatic, stratigraphic and tectonic studies allow reconstructing the temporal evolution of the Red Sea rift from South Afar (broadly below 11°N) to the formation of the Tendaho-Manda Hararo segment in Central Afar. Volcano-tectonic reconstruction by Wolfenden et al. (2005) suggests that since 16 Ma, the locus of strain in South Afar migrated eastward from the Afar western margin, in agreement with Kalb (1995) indicating a migration of the paleo-depocenter toward Central Afar broadly between 10 and 3 Ma. Starting at ∼4.5 Ma the volcanism in Afar is marked by the eruption of the Stratoid Series (Rooney et al. 2023). According to petrological, geophysical and stratigraphic evidence, after the emplacement of the Lower Stratoid Series in South Afar, the locus of strain migrated in Central Afar (Hammond et al. 2011) around 2.6 Ma (Wynn et al. 2008; Tortelli et al. 2022) with the emplacement of the US (Fig. 1 and 2.87–1.18 Ma; Feyissa et al. 2019; Kidane et al. 2003; Lahitte et al. 2003b). Broadly between 1.5 and 0.5 Ma, several silicic central volcanoes were formed and have been interpreted as the precursors of the development of magmatic segments in Central Afar (Barberi and Santacroce 1980; Lahitte et al. 2003a, b). Around 1.1 Ma, rifting progressively localized (Tortelli et al. 2022; Stab et al. 2016), leading to the formation of the Tendaho-Manda Hararo segment in Central Afar and to the emplacement of the CAG (Fig. 1.11–0.49 Ma; Feyissa et al. 2019; Kidane et al. 2003; Lahitte et al. 2003b). The most recent magmatic segment activity in Central Afar, known as Axial Series (< 0.65 Ma; Ferguson et al. 2013; Field et al. 2013; Lahitte et al. 2003b; Medynski et al. 2015; Feyissa et al. 2019), can be mainly observed along the Manda Hararo segment (Fig. 1).
The crust in Central Afar ranges between 22 and 30 km thick (Ahmed et al. 2022; Hammond et al. 2011). Crustal scale seismic anisotropy is consistent with the presence of stacked sills and vertical dikes (Hammond 2014; Chambers et al. 2021). A deep, sill-like region at the Moho level has been suggested using InSAR modeling and magnetotelluric investigation in Afar (Desissa et al. 2013; La Rosa et al. 2024). At the same time, shallow reservoirs have been identified at 5–15 km deep at the Tendaho graben and Manda-Hararo magmatic segment (Grandin et al. 2010; Didana et al. 2014). Volatile contents analysis in melt inclusions and modeling of InSAR deformation have been used by Field et al. (2012a) to identify a system of stacked sills from 1 to 5 km below the currently active Dabbahu volcano. In the brittle upper crust, the magma can episodically propagate laterally from one or more magma chambers, feeding dike intrusion or fissural eruptions, such as the 2005–2010 Manda Hararo-Dabbahu rifting event (Wright et al. 2012).
The US are dominated by basaltic lava flow successions, however, primary basalts (MgO > 10 wt%) are absent and primitive lavas are rarely documented in Central Afar. The erupted magmas are chemically homogeneous and moderately differentiated (Tortelli et al. 2022). The lava flows are on the order of 10 m thick and generally aphyric, partially preventing the investigation of the magma evolution by mineral chemistry studies. The CAG are instead less voluminous, dominated by meter-thick (up to 2 m) basaltic lava flows slightly more mafic and porphyritic with respect to the Stratoid. The recent study of Tortelli et al. (2022) suggested an evolution through fractional crystallization for both the two Series with considerable differences in the crustal storage and ascent pathways, with the CAG ponding at ~ 9–16 km and the US directly rising to the surface with no evidence of stationing in the crust.
Materials and methods
In this work we studied samples of the US and CAG lava flows outcropping in the area of the Tendaho graben in Central Afar (Fig. 1). The samples are from the field campaign conducted in February 2020 and from the collection of the Afar Repository of the University of Pisa (https://repositories.dst.unipi.it/index.php/home-afar). For the present work, six lavas from the February 2020 field campaign and three lavas from the Afar Repository have been selected. The petrography and the whole rock geochemistry of major and trace elements of these products have been previously described in Tortelli et al. (2022) except for two samples that are presented here for the first time (Z16 and Z131; Tab. S1). These two samples have been collected along the Gamarri escarpment in the Tendaho which is mapped as Upper Stratoid in literature and have an age within the Upper Stratoid age range. The abundance of the phenocrysts has been quantitatively evaluated by comparison with volume % estimation diagrams. Major and trace elements analyses (Tab. S1) were carried out at Activation Laboratories Ltd. (Ontario, Canada) by means of Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) and Inductively Coupled Plasma Mass Spectrometry (ICP-MS).
Polished thin sections were prepared for five US and three CAG mafic lava samples and one US silicic lava samples. These samples were studied by means of Scanning Electron Microscopy-Backscattered Electron Imaging (SEM-BSEI) and energy dispersive X-ray spectroscopy (EDS) microanalysis with the field emission scanning electron microscope FEI Quanta 450 ESEM-FEG provided with a Bruker QUANTAX XFlash Detector 6/10 (Centro per la Integrazione della Strumentazione dell’Università di Pisa, CISUP). Based on the SEM observations, mineral chemistry was then analyzed using a JEOL JXA-8230 superprobe device (joint laboratory of the Dipartimento di Scienze della Terra di Firenze and CNR-IGG). The analytical conditions were 15 kV of accelerating voltage with 20 nA of beam current and 3 μm beam size for olivine, pyroxene, and oxide and 10 nA beam current and 5 μm beam size for plagioclase. The counting time was 15 s on peak and 7 s in the background for major elements (Si, Ti, Al, Fe, Mg, Ca, K) with the exception of Na that is counted for 10 s on peak and 5 s in the background. For minor elements (Mn, Sr, Ba), the counting time was 30–40 s on peak and 15–20 s in the background. The standards used for the calibration are Albite Astimex for Si and Na, Plagioclase Astimex for the Al, Olivine Astimex for the Mg, Diopside Astimex for the Ca, Sanidine Astimex for K, Ilmenite Smithsonian for Ti and Fe, Baryte Astimex for the Ba, Celestite Astimex for the Sr.
In-situ trace element analysis has been performed by LA-ICP-MS on plagioclase phenocrysts of three US and two CAG mafic lava samples previously analyzed by EPMA. The laser ablation-ICP-MS analyses were performed using a PerkinElmer NexION 2000 ICP-MS coupled with a NWR-193 AR-F 193 nm excimer laser, in the Earth Science Department of Pisa, at the CISUP laboratories. The ablation was performed with a spot size of 50–60 μm, fluency of 5 J cm− 2, 10 Hz repetition rate, warm up time of 20 s, ablation time of 25 s and wash out time of 25 s. Ultrapure He was used as carrier gas. The NIST612 glass reference material was used as external calibration standard, the data reduction was carried out with Iolite v.2.5 (Paton et al. 2011) in quantitative mode and Ca concentrations (analyzed by EPMA) were used as internal standard. The accuracy and precision of the analyses were performed analyzing the NIST610 international standard together with an in-house standard (glass of basalt BE-N). For each session, both the calibrant and the secondary standards were analyzed at the beginning, at the end and every six analyses of the unknown sample to correct for the instrumental drift and improve the quality of the data. Typical precision and accuracy of the NIST610 reference material trace elements are < 15% which improves to < 5–10% for the elements presented in this work (i.e., Sr, Ba and LREE; Table S1).
Results
Rock classification and petrography
The US and CAG Series lavas are mainly basalts and basaltic andesites, with minor evolved products (Fig. 2). Both the Series are subalkaline, with transitional to tholeiitic affinity. The lavas of the US Series are mainly aphyric with rare micro-porphyritic or moderately porphyritic types. Plagioclase is the most abundant phenocryst, while olivine and clinopyroxene are common only in the more primitive lavas. The CAG are micro-porphyritic or porphyritic, rarely aphyric; plagioclase is the most abundant phenocryst phase, but olivine and clinopyroxene phenocrysts are also common (Tortelli et al. 2022; Fig. S1; Tab. S1).
For the microanalytical study we selected five US and three CAG mafic samples from the Tendaho graben, based on the presence of phenocrysts and geochemical characteristics representative of the Series. In particular, for both Series we have selected samples with MgO in the range 4–6 wt% (hereafter low-MgO samples and representing the majority of the erupted lavas; Tortelli et al. 2022) and 6-8.3 MgO wt% (hereafter high-MgO samples). Furthermore, the only US silicic lava flow, collected within the US lava successions in the Tendaho graben area, has been analyzed (rhyolite sample AF20-14c; Figs. 1 and 2).
The US high-MgO samples are presented here for the first time and represent the most primitive lavas (up to 8.3 MgO wt%) erupted during the US phase (Fig. 2). The high-MgO samples are moderately porphyritic (10–15% vol.) with olivine and clinopyroxene phenocrysts more abundant than plagioclase (Fig. S1A; Tab S1). The US low-MgO range from nearly aphyric to plagioclase-dominated porphyritic samples (up to 35% vol.) with rare clinopyroxene and olivine (Fig. S1A; Tab. S1). The US rhyolitic sample is moderately porphyritic (15% vol.) and phenocrysts are mainly feldspar and clinopyroxene (Fig. S1B; Tab. S1). The CAG high-MgO sample has an ophitic texture dominated by clinopyroxene and olivine with minor plagioclase (10% vol.). The CAG low-MgO are porphyritic (up to 20% vol.), plagioclase-dominated but showing an increase in size and abundance of clinopyroxene and olivine with respect to the US low-MgO samples (Fig. S1C; Tab. S1). Two different Fe-Ti oxides (Ti-magnetite and ilmenite) have been observed in all the samples, while apatite has been observed only in the US rhyolitic sample. For both Series, the groundmass is composed of plagioclase, clinopyroxene, Fe-Ti oxides and, occasionally, olivine. Furthermore, both the CAG low-MgO samples show textural heterogeneity consisting in different crystal abundance and groundmass grain size (Fig. S1C).
Mineral chemistry
In this section we present the mineral chemistry results of plagioclase and clinopyroxene, for high- and low-MgO samples of the two Series (Figs. 3 and 4; Fig. S2; Tab. S1) and the plagioclase analysis of the US rhyolitic sample (Fig. 3; Tab. S1). The mineral chemistry results of olivine and Fe-Ti oxides are described in the Supplementary Text file.
Plagioclase
The plagioclase covers an overall similar compositional range in the two Series, with phenocryst composition from bytownite to andesine (An24 − 88 for the US and An27 − 85 for the CAG) (Fig. 3A, B), and a bimodal distribution of the core composition (modes An67 and An83 for the US and modes An71 and An78 for the CAG, Fig. 3C, D). The bimodality in the plagioclase core composition corresponds to the low-MgO and high-MgO rock groups for both Series (Fig. 3E, F, G, H).
Regarding the US high-MgO samples, plagioclase phenocrysts are mainly normally zoned or unzoned, with core composition corresponding to the lower An group of the US core analyses (Fig. 3C; range An53 − 80 and mode An67) and similar or lower An for the rim (range An24 − 76 and mode An60) (Fig. 3E). However, a few plagioclase show an intermediate portion (i.e., mantle) between core and rim, showing a more complex, oscillatory or reverse, zoning (An75 − 80 in Fig. 3E) followed by a lower An rim. In the US low-MgO samples the plagioclase crystals are normally zoned, with core composition corresponding to the higher An group of the US core analyses (Fig. 3C; range An54 − 88 and mode An83) and a compositional gap with the lower An rim (range An24 − 84 and mode An59). This gap between core and rim is partially covered by the composition of the mantle (range An53 − 87 and mode An71) (Fig. 3G). The plagioclase phenocrysts of the US rhyolitic sample range from oligoclase to andesine (An28 − 47) and are all normally zoned (Fig. 3I, L).
Regarding the CAG, the high-MgO samples have normally zoned or unzoned plagioclase, with core composition corresponding to the lower An group of the CAG core analyses (Fig. 3D; range An63 − 74 and mode An72) and similar or lower An for the rim (range An27 − 73) (Fig. 3F). In the CAG low-MgO samples plagioclase phenocrysts with normal and reverse zoning coexist, with the more represented core composition corresponding to the higher An group of the CAG core analyses (Fig. 3D; An78). In these samples the plagioclase core, mantle and rim compositions broadly overlap, with the cores having a major mode at An78 and two minor modes at An54 and An68 while mantle and rim composition range at An60 − 83 and An54 − 80 respectively (Fig. 3H).
Clinopyroxene
All the clinopyroxenes of both series have broadly similar augitic composition in the pyroxene quadrilateral Di-Hd-En-Fs, close to the diopside field (Fig. 4A, B). In detail, the CAG high-MgO sample shows a small but significant sub-trend shifted toward the hedenbergite field (Fig. 4B). The two series have indeed a similar compositional range (range Mg#52−82 and Mg#54−81 for the US and CAG respectively; Mg# = (Mg/[Mg + Fe] x 100)) but depict a unimodal distribution for the US core composition (mode Mg#81) and a bimodal distribution for the CAG core composition (mode Mg#69 and Mg#76) (Fig. 4C, D). Similarly to the plagioclase, the bimodality of the CAG core composition corresponds to the low-MgO and high-MgO rock groups (Fig. 4E, F, G, H).
Regarding the US, the high-MgO samples have normally zoned clinopyroxene with high Mg# values in the core (range Mg#71−82 and mode Mg#81) and lower Mg# for the rim (range Mg#52−81) (Fig. 4E). The US low-MgO samples have few and unzoned clinopyroxene with variable Mg# for the core (range Mg#65−80) and similar or lower Mg# for the rim (range Mg#59−75) (Fig. 4G).
Regarding the CAG, the high-MgO samples have normally zoned or unzoned clinopyroxene with core composition corresponding to the lower Mg# mode (range Mg#64−72 and mode Mg#69) and overlapping or slightly lower Mg# for the rim (range Mg#54−73) (Fig. 4F). The CAG low-MgO samples have normally and, in some cases, reversely zoned clinopyroxene with core composition corresponding to the higher Mg# mode (range Mg#69−81 and mode Mg#76). Slightly higher Mg# values (up to 82) are recorded in many mantle zones and some rims (Fig. 4H).
Phenocrysts textures and chemical zoning
In this section, we describe the texture and chemical zoning of US plagioclase and CAG plagioclase and clinopyroxene. In particular we focus on An-TiO2 and Mg#-Cr2O3 variations respectively for plagioclase and clinopyroxene phenocrysts (Figs. 5 and 6; Fig. S3). Regarding the trace element we focus on the Sr-Ba variations for plagioclase phenocrysts (Fig. 7A; Fig. S4).
Upper Stratoid
We identify one main plagioclase typology for the US high-MgO samples and two for the US low-MgO samples (Fig. 8; Fig. S3A, B).
The prevalent plagioclase type in US high-MgO samples (Type I in Fig. 5A and Fig. S3A) is normally zoned, with a homogeneous core with average An67 and no or very thin rims averaging at An43. Accordingly, high TiO2 content, slightly increasing from core (mean 0.12 wt%) to rim (mean 0.15 wt%), has been observed. Regarding trace elements, Sr has a constant trend from core (mean 553 ppm) to rim (mean 531 ppm) while Ba shows a slight increase from core (mean 33 ppm) to rim (mean 39 ppm) (Fig. 7). Few plagioclase (crystal 1 and 10.1 in Fig. S3A) have portions (i.e., mantle and core) enriched in An and depleted in TiO2.
Two main types have been observed for the US low-MgO samples: Type II) homogeneous and resorbed cores, sometimes sieved, with high An (mean An82) and low TiO2 (mean 0.07 wt%). The rims are thin and marked by an abrupt decrease in An (mean An53) and increase in TiO2 (mean 0.15 wt%) (Fig. 5B; Type II in Fig. S3B); Type III) homogeneous resorbed cores, sometimes sieved, with high An (mean An82) and low TiO2 (mean 0.07 wt%) mostly show an abrupt normal zonation to an oscillatory or homogeneous mantle, averaging An72 and showing an increase in TiO2 (mean 0.10 wt%) (Fig. 5C; Type III in Fig. S3B). At times a core to rim gradual variation, from light- to dark-gray shade, is observed in BSE images, confirmed by the An and TiO2 contents (Type III in Fig. S3B). The crystals show homogenous rims, with a decrease in An (mean An57) and increase in TiO2 (mean 0.13 wt%) with respect to the mantle. Both the US low-MgO samples have an increase in Sr and Ba from core (mean Sr 602 ppm and Ba 27 ppm) to mantle (mean Sr 870 ppm and Ba 47 ppm) to rim (mean Sr 1336 ppm and Ba 183 ppm) (Fig. 7).
Central Afar Gulf
We identify one main plagioclase typology for the CAG high-MgO samples while four have been identified for the CAG low-MgO samples (Fig. 9; Fig. S3C, D).
The plagioclase phenocrysts of high-MgO CAG samples, similarly to those in the high-MgO samples of US, have homogeneous cores with constant and relatively low An, averaging An70, and high TiO2 (0.11 wt%); they have no or very thin rims, showing a decrease in An (mean An47) and increase in TiO2 (0.15 wt%) with respect to the core (Fig. 5D; Type I in Fig. S3C).
The low-MgO CAG plagioclase, on the contrary, show more overall complexity compared to the US, and four different types of plagioclase have been recognised (Fig. 5E, F; Fig. S3D): Type II) mainly sieved and resorbed cores with variable An (range An55 − 82) and low TiO2 (mean 0.10 wt%), with complex mantles showing oscillatory and/or reverse zoning with An averaging An75 and overall similar or lower TiO2 (mean 0.09 wt%). The rims show a decrease in An (mean An65) and increase in TiO2 (mean 0.15 wt%) (Fig. 5E; Type II in Fig. S3D). Type III) Homogeneous or slightly oscillatory cores with high An (mean An74) and low TiO2 (mean 0.09 wt%). The mantles show an abrupt decrease in An (mean An66) and a small increase in TiO2 (mean 0.11 wt%), sometimes having a small reverse zoned portion toward the rims with an increase in An and decrease in TiO2. No, or thin normally zoned rims (mean An60 and TiO2 0.21 wt%) have been observed (Type III in Fig. S3D). Type IV) Homogeneous or lightly oscillating resorbed cores (one sieved) with constant or gradual and small (one with a more marked step) increase in An (range An68 − 85) and slightly increasing or constant TiO2 (mean 0.07 wt%) (Fig. 5F; Type IV in Fig. S3D). No rims or normally zoned rims (mean An72 and TiO2 0.09 wt%) have been observed. Type V) Homogeneous or slightly oscillatory, resorbed cores with a gradual and small decrease in An (range An65 − 83) and slightly increasing or constant TiO2 (mean 0.07 wt%) (Type V in Fig. S3D). No rims or normally zoned rims (mean An66 and TiO2 0.10 wt%) have been observed. Regarding trace elements for all the low-MgO CAG typologies, Sr have a constant trend (mean core 507 ppm, mantle 507 ppm and rim 505 ppm) while Ba show a slight increase from core and mantle (mean 28 ppm) to rim (37 ppm) (Fig. 7).
Although this study is mainly focused on the plagioclase as it is the most abundant phenocryst phase (particularly for the US), for the CAG we also carried out profile analysis for the clinopyroxene, which is a relatively common phenocryst in low-MgO CAG, also. The two low-MgO CAG clinopyroxene analyzed shows oscillatory and reverse zoning with rim and mantle reaching higher Mg# and Cr2O3 (respectively up to 81 and 0.57 wt%) with respect to the cores (up to Mg# 77 and Cr2O3 0.32 wt%; Fig. 6).
Mineral-melt equilibrium and geothermobarometry
Geothermobarometry estimations have been obtained using the phenocryst compositions of plagioclase and clinopyroxene in both US and CAG Series. We used the plagioclase geothermobarometer of Putirka (2008) to calculate the pressure and temperature of crystallization. The clinopyroxene pressure and temperature of crystallization has been calculated using the methods of Neave and Putirka (2017) and Putirka (2008) respectively (Tab. S1). We used the whole rock analysis as the melt composition. The equilibrium was checked based on the plagioclase- clinopyroxene-liquid distribution coefficient of Putirka (2008) (see Supplementary Text) and the water concentration input set at 0.5 wt% according to literature evidence (Field et al. 2012b, 2013; Tortelli et al. 2022). We estimated the storage conditions of the magma based on phenocryst core and mantle analyses in equilibrium with the host rock. The corresponding depths have been derived assuming a 270 bar/km geobaric gradient (Best 2013).
Regarding the US high- and low-MgO samples, both clinopyroxene and plagioclase indicate pressure of mainly 2–5 kbar and temperature ranging from 1125 to 1200 °C (Fig. 10). Only a few plagioclase crystals belonging to one low-MgO sample with low An (An69 − 76) core crystallized at very shallow depth (equilibrium at < 1 km of depth, Fig. 10). For the US rhyolitic sample, the plagioclase in equilibrium with the host rock indicates broadly 2–4 kbar and temperature ranging between 960 °C and 980 °C (Fig. 10). Similarly to the US, the CAG high- and low-MgO samples clinopyroxene and plagioclase indicate mainly 2–5 kbar and temperature ranging from 1145 to 1175 °C (Fig. 10; Supplementary Text for a detailed description).
Given the large error associated with these geothermobarometers, and in particular with those derived from plagioclase (Fig. 10; Putirka 2008; Neave and Putirka 2017; Wieser et al. 2023), in the discussion we use only the clinopyroxene barometer to estimate the depth of the magmatic system. Most of the estimates for both Series focus at or below the upper-lower crust transition, broadly at ~ 10–18 km (± 4 km), reasonably excluding a very shallow (upper crust) magmatic system.
Discussion
US magmatic evolution: insight from whole rock geochemistry
To constrain magmatic differentiation, we calculated the fractional crystallization liquid line of descent (LLD) and the resulting mineral phase compositions using Rhyolite-MELTS (Gualda et. 2012) by AlphaMELTS software (Smith and Asimow 2005). According to AlphaMELTS best fit conditions we then used Magma Chamber Simulator software (MCS; Bohrson et al. 2020; Heinonenet al. 2020) to model Sr and Ba trace elements. We performed the modeling only for the US lavas due to the large number of data available for constraining the model.
We used as the starting composition the most primitive lava analyzed in this work (Z16, MgO wt% 8.3) and modeled liquid evolution for given values of P, T, fO2 and H2O wt%, by free-energy minimization at each ΔT step. Each run starts at the liquidus temperature (calculated by MELTS) and, based on the clinopyroxene barometric estimates, we used 4 kbar as the starting depth. According to literature estimation of Afar magmas, we used the water concentration of 0.5 and 1 wt% (Field et al. 2012b, 2013; Tortelli et al. 2022) and fO2 of QFM -0.5 and QFM -1 (Bizouard et al. 1980; de Moor et al. 2013; Tortelli et al. 2022). For each initial P-T-H2O-fO2 combination, we let the magma undergo fractional crystallization at the pressure of 4 kbar, or start decompressing at different degrees of evolution and at different ΔP to evaluate the modeled behaviour at shallower depth (Fig. S5). Our modeling best fits the drop in Al2O3 due to plagioclase-in at MgO 5.8–6.7 wt% and in FeOt and TiO2 due to spinel-in at MgO 4.5–5 wt% given QFM -0.5, H2O 0.5 wt%, ΔP 30 bar/C° and P 4 kbar as starting conditions (Fig. 11; Fig. S5). Furthermore, the plagioclase-in composition obtained by the MELTS best fit models (An71 − 74) is in excellent agreement with the core compositions of the analyzed plagioclase in equilibrium with Z16 whole rock (An69 − 73). The scatter in Al2O3 observed at 5–6 wt% MgO is well fitted by varying the depth of crystallization (i.e., the initial MgO wt% content of the ascending magma; Fig. 11), while the variation in FeOtot, TiO2 and CaO requires slight variation in H2O and fO2 (Fig. S5). The variation of ΔP has an effect similar to varying the initial MgO wt% content of the ascending magma. Indeed a slow rise (i.e., low ΔP) will let the magma fractionate deeper for a longer time with respect to a rapid rise.
Starting from the most mafic samples (Z16), the MCS modeling has been performed using AlphaMELTS best fit conditions of QFM -0.5, H2O 0.5 wt% and, in order to account for the variation in depth of crystallization, P of 2, 3 and 4 kbar. The Kd of Sr and Ba has been calculated using Dohmen and Blundy (2014) according to the most mafic and silicic plagioclase composition calculated by AlphaMELTS (respectively Sr 1.78, Ba 0.21 and Sr 6.15, Ba 0.43). During the modeling the Kd varied between the mafic and silicic end-member according to MCS calculated temperature. In agreement with the major elements modeling, Sr and Ba analysis are very well fitted by a fractional crystallization trend, up to the most evolved composition (Fig. 12). Only two samples have a remarkably high concentration of respectively Sr and Ba compared to the modeled trend.
US and CAG magmatic evolution: insights from mineral chemical zoning
In this section we use major and trace elements measured in US and CAG plagioclase (i.e., An, TiO2, Sr, Ba) and in CAG clinopyroxene (i.e., Mg#, Cr2O3) to reconstruct magma evolution in relation to intensive (e.g. pressure, temperature, water content) or extensive (e.g. magma mixing, assimilation) parameters. To this purpose, we discussed and ruled out the effect of chemical diffusion and crystallization kinetics on element redistribution (see Supplementary Text). MgO variations in plagioclase have not been used for the interpretation due the complex effect of the An content on Mg crystal-melt partitioning coefficient (Mutch et al. 2022; Supplementary Text).
Fractional crystallization, plagioclase entrainment and crystal mush resorption recorded in the US crystals
The plagioclase phenocrysts in the US high-MgO samples mostly show no variation in An, TiO2 and FeOt, and no resorption features, suggesting that they grew in a stable and unperturbed magma reservoir (Fig. 5A; Type I in Fig. S3A). Few examples of increasing An with decreasing TiO2 (Fig. S3A) record the occurrence of mafic refilling.
The plagioclase of the US low-MgO samples have cores with overall constant composition of An, TiO2 and FeOt, indicating that the cores grew in a stable and unperturbed magma reservoir. However, resorbed cores which are sometimes sieve-textured have been observed (Fig. S3B), and at the core-rim transition an abrupt decrease in An is accompanied by an increase in FeOt and TiO2 (Fig. 5B; Type II in Fig. S3B). Such decrease in the An content and increase in FeOt and TiO2 can be explained by the high An plagioclase being entrained in the low MgO magma and crystallized the low An rim after a period of plagioclase dissolution, causing the observed compositional gap (Figs. 3G and 5B; Type II in Fig. S3B). Furthermore, more complex zoning is observed in some plagioclase phenocrysts, such as decreasing in An coupled with the increasing TiO2 and FeO from core to mantle or oscillations of An and, sometimes, also of TiO2 (Fig. 5C; Type III in Fig. S3B). The core-mantle variations again suggest the crystal entering a more evolved magma while the oscillatory mantle could be explained by polybaric convection (e.g. Ustunisik et al. 2014) in a slightly zoned magmatic system (when An is coupled with TiO2) before being erupted.
Crystal entering and crystalizing in a more evolved magma can explain the increase of incompatible elements (Ba, LREE) in the plagioclase mantles and rims but not the observed increase of the Sr, up to 1740 ppm (Fig. 7A; Fig. S4). We therefore used the output of the MCS model (Fig. 12) to obtain the concentration of Sr and Ba in the plagioclase during fractional crystallization and plotted them in Fig. 13 together with the composition of natural US plagioclase. According to the model, fractional crystallization can only partially explain the increase in Sr in the plagioclase, without however explaining the highest concentrations (i.e., > 1000 ppm; Fig. 13). We therefore model Recharge, Assimilation, and Fractional Crystallization (RAFC) with MCS using the high An plagioclase composition as an assimilant to evaluate if the assimilation of a plagioclase-rich wall rock can explain the high Sr concentrations. Despite the initial increase in Sr (up to ~ 850 ppm), the high solidus temperature of the plagioclase caused the magma and assimilant temperature to soon equalize, preventing MCS from continuing the modeling. However, magma mixing experiments of basaltic Icelandic lavas indicate that mixing-induced chemical disequilibrium can lead to plagioclase resorption (Neave et al. 2021; Nakamura and Shimakita 1998). Considering the strong chemical disequilibrium between the plagioclase core and the carrying magma, together with the textural evidence of resorption, it is reasonable to think that high An core dissolves in the low-MgO due to chemical disequilibrium. We therefore suggest that the plagioclase dissolution led to the enrichment of Sr in the melt that eventually crystallized the high Sr rim and mantle, similar to what is observed during the thermally remobilization of crystal mush in silicic magmatic systems (Forni et al. 2015; Wolff et al. 2015; Bachmann et al. 2014). At the same time, the absence of plagioclase crystallization would lead to an increase of Sr in the melt if associated with fractionation of other Sr-poor minerals. However, the enrichment in Sr is observed only in the plagioclase and not in the whole rock analysis (Fig. 12), suggesting the melt enrichment is volumetrically restricted. According to Neave et al. (2021), which indicate that even modest amounts of resorption could trigger mush disaggregation, we suggest the dissolution took place within the interstices, along grain boundaries, of mush-like portions that were later infiltrated and disaggregated by rising magma that, enriched in Sr due to plagioclase dissolution, crystallized the high-Sr rim just before or during eruption. In conclusion, based on our observations, the petrogenesis of the US magmas involves an initial period of fractional crystallization in a stable and unperturbed magma reservoir. Subsequently the evolution proceeds within a melt-rich moderately zoned magmatic system due to fractional crystallization and polybaric convection. Eventually, the mineral-melt disequilibrium led to plagioclase dissolution and generation of Sr-rich melt in crystal mushes portions of the magmatic system.
Fractional crystallization, magma mixing and recharging events recorded in the CAG crystals
The plagioclase phenocrysts of the CAG high-MgO lavas are unzoned in An, TiO2 and FeOt, suggesting they grow in an overall stable and unperturbed reservoir, similarly to US (Fig. 5D; Type I in Fig. S3C). On the contrary, petrographic evidence of variations in the crystal abundance and groundmass size suggest possible mixing events for the two analyzed CAG low-MgO samples (Fig. S1). Evidence of reverse zoning has been observed in plagioclase with sieved cores and increasing An and decreasing TiO2 in the mantle with respect to the cores (Fig. 5E; Type II in Fig. S3D). The sieved core may indicate disequilibrium induced by magma mixing, possibly due to the arrival of a Ca-rich and TiO2-poor mafic magma in a more evolved reservoir, with consequent crystallization of the high-An mantle. More complex zoning is instead observed in some plagioclase with a core to mantle direct zoning (i.e., decrease in An and increase in TiO2) sometimes followed by a reversely zoned portion before the rims (i.e., increase in An and decrease in TiO; Type III in Fig. S3D). This suggests that magma mixes with a more evolved melt and the low An plagioclase mantle crystallizes around the high An plagioclase core. At a later time, the same reservoir is affected by the arrival of a new mafic input. Small increase or decrease of An corresponding to inverse or no TiO2 variations could also suggest mixing between two slightly different magmas (Fig. 5F; Type IV and V in Fig. S3D).
Recharging events are also suggested by some clinopyroxene profiles showing increase in Mg# and Cr2O3 in the mantle and rim with respect to the core, indicating the arrival of more mafic magmas (Fig. 6). These observations indicate that, beside fractional crystallization, CAG reservoirs are affected by several recharging events and mixing between magmas with different degrees of evolution. The CAG clinopyroxene are chemically more variable and overall more enriched in TiO2, Al2O3 and Na2O for the same Mg# content with respect to the US, suggesting higher chemical variability within the CAG with respect to the US (Fig. 7B; Fig. S2D, E,F). Furthermore, different trends between the two Series have been observed for Ni in olivine (Fig. S2G). These variations could be related to both mantle source and/or fractional crystallization processes. Investigating the nature of these differences is beyond the scope of this study and clinopyroxene trace elements analyses are needed for a comprehensive study. However, these observations emphasize the differences between the two series and also the variability of the CAG Series with respect to the more homogeneous US.
Magmatic system architecture and dynamics
The deep and stable magmatic system of the US volcanic phase
Most of the US lavas do not show evidence of shallow crystallization as, when the mineral-melt equilibrium is achieved, it is mostly at middle-lower crust levels (10–18 km), just below the upper-lower crust transition (Hammond et al. 2011). The geobarometry results do not show a clear distinction of high-MgO, low-MgO and silicic magmas in discrete reservoirs at different depths (Fig. 10). Based on density constraints, we therefore suggest that the US high-MgO magmas, with high Mg# pyroxene, Fo-rich olivine and plagioclase, the latter bearing evidence of mafic recharging events, reside in the deeper reservoir(s) of this middle-lower crustal magmatic system (Fig. 14A). Above these, in the shallower reservoir(s), we instead identify the low-MgO nearly aphyric magmas with sporadic high An plagioclase and low Mg# clinopyroxene and olivine that are mostly in disequilibrium with the host rock. Finally, we suggest that the silicic magmas, with low An plagioclase, form at the very top of this magmatic system (Fig. 14A).
It is reasonable that the high An plagioclase, found as cores (up to An88) in disequilibrium with the host low-MgO magma, crystallized from a high-MgO-like or more mafic magma in a deep-crustal magmatic system, possibly near the Moho and never directly tapped by eruptions (Fig. 14A). The possibility of these high-An plagioclase floating in the deep magmatic system can be evaluated by density calculations. According to results from MELTS, the calculated liquid remains denser (2.76–2.71 g/cm3) with respect to the crystallized plagioclase (An71 − 64; 2.67–2.66 g/cm3) and also with respect to a bytownite composition (2.71 g/cm3), until the magma reaches ~ 3.8 MgO wt%. Furthermore, in the same MgO range, MELTS calculation indicates an overall low melt viscosity (7.4–31 Pa*s). Using a mean of the liquid density (2.73 g/cm3) and viscosity (20 Pa*s) and 1 mm size plagioclase of bytownite composition (2.71 g/cm3), the Stokes law suggest that plagioclase may remain buoyant in the deep mafic magma (-1.4*10− 6 m/s). The mafic minerals crystallized in the deep mafic magma (clinopyroxene and olivine, respectively 3.23 g/cm3 and 3.24 g/cm3) are instead denser than the melt and therefore prone to sink.
The high An plagioclase can therefore be separated from the denser mafic minerals and carried up by magma ascending from the top of the deep-crustal magmatic system, while clinopyroxene and olivine mostly settle down. The ascent of differentiated magma, polybaric convection (Fig. 5B, C) and plagioclase buoyancy can therefore explain the presence of high An plagioclase in the shallower reservoir(s) of the middle-lower crustal magmatic system. At the same time, the rising plagioclase could be stored in a plagioclase-dominated crystal mush, at the top (but possibly also on the sides) of this middle-lower crustal magmatic system (Fig. 14A), as already proposed for several magmatic systems (e.g., Neave et al. 2014; Sheth 2016; Valer et al. 2017; Óskarsson et al. 2017; Marzoli et al. 2022). Still, we cannot exclude the possibility of in situ crystallization during earlier phases of the magmatic system. Nevertheless, we suggest that the mush forming at the top of the middle-lower crustal magmatic system could be responsible for the differentiation of the crystal-poor US low-MgO and silicic lavas, as already observed for several silicic magma reservoirs (Jackson et al. 2018; Forni et al. 2016; Dufek and Bachmann 2010). At the same time the chemical disequilibrium between the mush and the low-MgO magma percolating within the mush interstices drive the plagioclase resorption, leading to the formation of discrete melt portions enriched in Sr (Fig. 14A; Forni et al. 2015; Wolff et al. 2015; Bachmann et al. 2014) and favoring mush disaggregation (Neave et al. 2021). Eventually, when the shallower reservoir(s) get destabilized and the low-MgO magma eruption begins, the mush starts to disaggregate and the high-Sr melt located within the mush interstices starts to crystallize the Sr-rich rims of the ripped high An plagioclase. The paucity of clinopyroxene and olivine in the US suggest that they settled down to form a cumulated crystal mush at the base of the middle-lower crustal magmatic system, and only occasionally erupted with the high-MgO lava (Fig. 14A).
The polybaric and interconnected magmatic system for the CAG volcanic phase
The CAG show a marked decrease of erupted volumes with respect to the US, indicating a decrease of the eruptable melt stored in the crust. Relatively small magmatic reservoirs can therefore be envisaged for the CAG activity (Fig. 14B). The increase in porphyricity suggests instead that the CAG magmas are more crystal-rich with respect to the US while the more variable mineral assemblage indicates that crystals, in particular olivine and clinopyroxene, are not fractionated so efficiently as for the US (Fig. S1C). Evidence in both plagioclase and clinopyroxene of recharging events and magma mixing (Figs. 5E and 6; Type II in Fig. S3D) indicate that the small reservoirs of the CAG are interconnected (Fig. 14B). Furthermore, evidence of multiple recharging events suggested by phenocrysts with complex zoning (Type III in Fig. S3D) indicates that the system is highly dynamic with the possibility of multiple events of mixing before eruption. Lastly, the variability of CAG clinopyroxene and olivine mineral chemistry (Fig. 7B; Fig. S2) argue for a more heterogeneous magmatic system with respect to the US.
Red Sea rift localization: magmatic system and crustal evolution
The US range from 2.6 to 1.1 Ma without evidence of long breaks and are characterized by voluminous eruptions of similar mostly moderately evolved, aphyric or nearly aphyric magmas indicating a homogenous and melt-rich magmatic system. We suggest that most of the US magma rose directly to the surface from the shallower reservoir(s) of a middle-lower crustal magmatic system. The eruptions, possibly induced by volatiles exsolution as a consequence of differentiation and/or decompression (Black and Manga 2017), mainly tap the aphyric or low plagioclase-phyric low-MgO magma, tearing few plagioclase from the crystal mush. Only occasionally the eruptions tapped the high-MgO magma of the deeper reservoir(s) and the silicic magma of the shallower reservoir(s) (Fig. 14A). This reconstruction is in agreement with evidence of magma differentiation taking place in the lower and middle crust (Sparks et al. 2019; Annen et al. 2006), and in general agreement with models of large eruption magmatic systems (Black and Manga 2017; Ernst et al. 2019; Karlstrom and Richards 2011).
At ~ 1 Ma, the CAG magmatic system developed at middle-lower crustal depths, similarly to the US. The highly dynamic CAG magmatic system with magma rising through multiple, relatively small, crystal-rich and interconnected reservoirs (Fig. 14) differ from the US and is instead similar to the one observed for the magmatic segments in Afar (Pagli et al. 2012; Desissa et al. 2013; Didana et al. 2014; Field et al. 2012a; Chambers et al. 2021; Biggs et al. 2021) and to the source-to-surface vertically stacked magmatic systems described in Cashman et al. (2017). Considering the decrease of erupted volume from the US to the CAG and the increase in the degree of partial melting (Tortelli et al. 2022), an important volume of intruded material at the US-CAG transition is required. This is in agreement with large volumes of intruded material and cumulates observed along the magmatic segments (Hutchison et al. 2018; Lewi et al. 2016). Moreover, Bridges et al. (2012) identified a 10 km wide zone of diking intruding the Tendaho graben in the last 0.8 Myrs of extension, corresponding in time and space with the CAG eruptive phase. We therefore suggest a transition from a melt-dominated magmatic system (i.e., US volcanic phase), to a stacked, crystal-rich magmatic system which started forming since the rift began to localize (i.e., CAG volcanic phase) and whose magmatic architecture is comparable with the present-day magmatic segments activity in Afar.
The link between rift processes and related volcanism have been studied elsewhere, such as the North Atlantic Igneous Province associated with the opening of the North Atlantic ocean and extending between Greenland, Iceland, the Faroe Islands and the northwest British Isles (e.g., Saunders et al. 1997). The US shows similarities with the Neogene flood basalts of eastern Iceland, which precede the ongoing rifting activity of the Iceland oceanic ridge and are dominated by aphyric magma (50–70%) and, to a lesser extent, by plagioclase- or olivine-phyric magmas (Walker 1958). In particular, our reconstruction of the US magmatic system architecture and mush disaggregation process occurring in the middle-lower crust is very similar to the one proposed for the Neogene flood basalt -Grænavatn formation- (Óskarsson et al. 2017). Following the widespread volcanic eruption, the stacked and interconnected CAG magmatic system is instead comparable with the one observed for the magmatic segments in Iceland (Neave et al. 2013; Caracciolo et al. 2023).
Conclusions
The transition from the Upper Stratoid to the Central Afar Gulf volcanic activity represents a crucial stage of rift evolution, marking the transition from broad to localized rift in Central Afar. By means of whole rock analysis, major and trace element mineral chemistry, geothermobarometry estimates and geochemical modeling for both whole rock and mineral chemistry, we identify contrasting magmatic system architectures for the Upper Stratoid and the Central Afar Gulf, which helps to interpret magmatic system evolution during the continental breakup.
The Upper Stratoid evolved due to fractional crystallization in a melt-dominated, slightly zoned, middle-lower crust (10–18 km) magmatic system. Polybaric plagioclase convection and dissolution of a plagioclase-rich crystal mush is recorded in the phenocryst texture and chemistry. Magma mostly rose from the shallower portions of this magmatic system directly to the surface. The Central Afar Gulf magmatic system was instead crystal-rich, spanning approximately the same depth interval as that for the Upper Stratoid but dominated by multiple, relatively small and interconnected magmatic reservoirs. Unlike the Upper Stratoid, multiple mixing events between magmas with different degrees of evolution were frequent.
Our study documents the transition during the continental breakup from an overall stable and melt-rich magmatic system feeding the voluminous and homogeneous Upper Stratoid eruptions to a more dynamic, interconnected and crystal-rich situation feeding small-volume eruption while the rift localizes.
Data availability
The authors confirm that the data supporting this study is available within the online supplementary materials.
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Acknowledgements
The research is part of the PhD of G. Tortelli and is funded by 2017 PRIN project-protocol MIUR: 2017P9AT72 PE10. G. Tortelli acknowledges support by the Tuscany Regional PhD Course in Earth Sciences. The authors are grateful to Gordon Moore, Editor of Contribution to Mineralogy and Petrology for handling the manuscript and to Thomas R. Hudgins and an anonymous reviewer for their valuable comments. We thank R. Ishak and M. Gemelli (SEM lab., CISUP, University of Pisa), A. Orlando (EPMA lab., CNR-IGG of Firenze) and M. Masotta (LA-ICP-MS lab., CISUP, University of Pisa) for their support during analytical acquisition. We thank R. Santacroce (University of Pisa) for discussions and support. We thank the colleagues of the Addis Ababa University and the Ethiopian and Afar Regional Governments, the drivers of the rental agency Ethioder, and the local policeman and guides of the different woredas for their support and logistic help in organizing and conducting the February 2020 campaign. Open access funding provided by Università di Firenze within the CRUI-CARE Agreement.
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Tortelli, G., Gioncada, A., Pagli, C. et al. From melt- to crystal-rich magmatic systems during rift localization: Insights from mineral chemistry in Central Afar (Ethiopia). Contrib Mineral Petrol 179, 87 (2024). https://doi.org/10.1007/s00410-024-02164-7
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DOI: https://doi.org/10.1007/s00410-024-02164-7