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Rheology and microscopy analysis of polymer–surfactant complexes

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Abstract

Polyelectrolytes are a fascinating type of polymeric substance that is increasingly being employed in sophisticated industrial formulations. Combining these polymers with a surfactant results in a solution with unique behaviour and formation due to a mixture of hydrophobic and hydrophilic interactions at both the large (polymer) and tiny (surfactant) molecular scales. In this study, we look at the literature on polyelectrolyte–surfactant complexes on a molecular level, using mostly rheology and TEM to cover all the elements that go into producing them and the interplay that exists between distinct molecular interacting types. This study was assembled from over 300 sources to investigate a wide range of rich polymer\surfactant complex systems with a variety of uses, some of which had a basic purpose of understanding the effects of alteration on the behaviour of these systems. Gene therapy, drug administration, oil recovery, and nanoparticle manufacturing are among the target applications of surfactant polymer systems, according to the literature. Most of the published literature focuses on changing the type of surfactant (e.g., Gemini or single-chain surfactant), changing the system (exchanging polymer or surfactant), functionalizing surfactant\polymer, making the surfactant or polymer less hydrophobic for better binding, and then studying and exploring the formed complexes using a variety of techniques.

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Rich rheological behaviour of polymer\surfactant system

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    Aref Abbasi Moud

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Abbasi Moud, A. Rheology and microscopy analysis of polymer–surfactant complexes. Colloid Polym Sci 300, 733–762 (2022). https://doi.org/10.1007/s00396-022-04982-2

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