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Primary electroviscous effect in a dilute suspension of charged spherical colloidal particles with a slip surface

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Abstract

The theory of Watterson and White (J Chem Soc Faraday Trans II, 77: 1115, 1981) on the primary electroviscous effect in a dilute suspension of charged spherical colloidal particles in an electrolyte solution is extended to cover the case where liquid slip occurs on the particle surface on the basis of the Navier boundary condition suitable for a hydrophobic surface. The general expressions for the effective viscosity and the primary electroviscous coefficient of the suspension as well as their low-zeta potential approximate expressions are derived.

Primary electroviscous coefficient

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Acknowledgments

I thank Dr. Partha P. Gopmandal of the National Institute of Technology Durgapur and Prof. Somnath Bhattacharyya of Indian Institute of Technology Kharagpur for introducing me to the field of electrokinetics of colloidal particles with a slip surface.

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  1. Faculty of Pharmaceutical Sciences, Tokyo University of Science, 2641 Yamazaki Noda, Chiba, 278-8510, Japan

    Hiroyuki Ohshima

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  1. Hiroyuki Ohshima
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Ohshima, H. Primary electroviscous effect in a dilute suspension of charged spherical colloidal particles with a slip surface. Colloid Polym Sci 298, 1551–1557 (2020). https://doi.org/10.1007/s00396-020-04741-1

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  • DOI: https://doi.org/10.1007/s00396-020-04741-1

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