Abstract
Herein, bismuth–yttrium iron garnet (Bi-YIG) doped with In3+ ions with chemical formula Y2BiInxFe5−xO12 (x = 0.00–0.75 in steps of 0.15) was successfully prepared using solid-state reaction method. Effects of In3+-ion doping on microstructural, magnetic, and dielectric properties of Bi-YIG ferrite are investigated and discussed. Results show that In doping does not change the phase of Bi-YIG ferrite but increases lattice constant. Microstructure analysis indicates that In doping not only results in uniform grain shape but also influences grain size (the maximum average size is 3.46 μm at x = 0.30). Vibrating sample magnetometry results reveal that upon increasing In3+-ion content from x = 0.00 to x = 0.75, saturation magnetization first increases from 14.48 to 24.71 emu/g (at x = 0.45) and then decreases to 15.43 emu/g (at x = 0.75). Ferromagnetic resonance linewidth first decreases from 538.5 to 384.7 Oe (at x = 0.30) and then increases to 416.5 Oe (at x = 0.75). Real part of the permeability increases from 17.1 (x = 0.00) to 21.2 (x = 0.45) and then decreases to 19.5 (x = 0.75) in frequency range from 1 MHz to 1 GHz. Additionally, In doping leads to the dielectric constant reaching a maximum value of ε' = 20.4 at x = 0.15, while maintaining low dielectric loss of ~ 10−4 at the frequency of 10 GHz. Prepared material can be employed in high-frequency circulators, isolators, and microwave devices.
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References
J.D. Adam, L.E. Davis, G.F. Dionne, E.F. Schloemann, S.N. Stitzer, Ferrite devices and materials. IEEE T Microw Theory 50, 721–737 (2002)
J. Li, Y.H. Sun, F. Gao, H.K. Su, X.I. Han, Z. Liang, H.W. Zhang, Q. Li, Enhanced FMR linewidth and magnetic properties of In3+-doped YIG ferrite materials for microwave devices applications. J Magn Magn Mater. 538, 168318 (2021)
W.W. Zhou, J.Y. Ye, S. Zhuo, D.X. Yu, P. Fang, R. Peng, Y. Liu, W.F. Chen, Synthesis and characterization of novel yellow-green Al-doped Y3Fe5O12 nano-pigments with high NIR reflectance. J Alloys Compd. 896, 162883 (2022)
R. Fu, Y.X. Li, R. Peng, Y.C. Lu, Q.Y. Wen, High dielectric constant YIG ferrites with low sintering temperature. J Mater Sci-Mater El 33, 4914–4923 (2022)
X.N. Han, J. Li, H. Wu, K. Sun, Y.X. Chen, L.J. Jia, H.W. Zhang, P.J. Zhang, C.Y. Wu, High dielectric constant and magnetic properties of Bi-In Co-substituted YIG ferrites. J Magn Magn Mater. 570, 170512 (2023)
M.S. Jang, H.J. Ok, I. Oh, G.H. Kang, J.W. Yoo, K.S. Lee, Formation of Y3Fe5O12 matrix including epsilon-phase Fe2O3 with the giant coercive field via optimized sol-gel method. J Magn Magn Mater 552, 169218 (2022)
S.S. Du, Q.H. Yang, X.A. Fan, H.W. Zhang, High selectivity and compact tunable bandpass filter using YIG material. J Appl Phys. (2023). https://doi.org/10.1063/5.0141279
J. Matilla-Arias, Y. Guerra, P.A. Marino-Castellanos, R. Pena-Garcia, Theoretical investigation of cation distribution and their effect on the physical properties of Ni-doped YIG system. Appl Phys a-Mater. (2022). https://doi.org/10.1007/s00339-022-06236-y
Q.Q. Chen, P.P. Lin, X.Y. Du, H. Inoue, K. Kizaki, T.S. Lin, P. He, A new strategy to fabricate YIG ferrite joint with novel magnetic Bi2O3-CoO-Fe2O3-B2O3 glass. Mater Design 215, 110521 (2022)
J.Q. Wang, Y.L. Jin, J.A. Yang, Y.Y. Huang, T. Qiu, Effect of ZrO2 addition on the microstructure and electromagnetic properties of YIG. J. Alloy. Compd. 509, 5853–5857 (2011)
H.W. Zhang, J. Li, H. Su, T.C. Zhou, Y. Long, Z.L. Zheng, Development and application of ferrite materials for low temperature co-fired ceramic technology. Chin Phys B 22, 117504 (2013)
Q.S. Yin, Y.L. Liu, J. Wu, J. Li, J.F. Chen, S.F. Lu, K. Liu, Mechanistic study of the effect of Ca-Sn co-doping on the microwave dielectric properties and magnetic properties of YIG. Ceram. Int. 48, 32827–32836 (2022)
Y. Yang, Z. Yu, Q.G. Guo, K. Sun, R.D. Guo, X.N. Jiang, Y. Liu, H. Liu, G.H. Wu, Z.W. Lan, Thermomagnetization characteristics and ferromagnetic resonance linewidth broadening mechanism for Ca-Sn Co-substituted YIG ferrites. Ceram. Int. 44, 11718–11723 (2018)
O. Rosales-Gonzalez, F. Sanchez-De Jesus, F. Pedro-Garcia, C.A. Cortes-Escobedo, M. Ramirez-Cardona, A.M. Bolarin-Miro, Enhanced multiferroic properties of YFeO3 by doping with Bi3+. Materials. 12, 2054 (2019)
L.L. Wang, Z.G. Huang, H.Q. Zhang, R.B. Yu, Phase and magnetic properties evolutions of Y3–x(CaZr)(x)Fe5-xO12 by the sol-gel method. J. Magn. Magn. Mater. 395, 73–80 (2015)
N. Jia, H.W.W. Zhang, V.G. Harris, Iron-depleted Bi-YIG having enhanced gyromagnetic properties suitable for LTCC processing. J. Am. Ceram. Soc. 102, 1180–1191 (2019)
D.D. Andhare, S.R. Patade, M.V. Khedkar, A.A. Nawpute, K.M. Jadhav, Intensive analysis of uncoated and surface modified Co-Zn nanoferrite as a heat generator in magnetic fluid hyperthermia applications. Appl Phys a-Mater. (2022). https://doi.org/10.1007/s00339-022-05648-0
S.T. Zhang, L.K. Wang, B.L. Xu, J. Liu, S.L. Luo, S.Y. Ji, Y. Ding, L. Zhang, J.J. Ma, T. Duan, Rapid synthesis of Nd-doped Y3Fe5O12 garnet waste forms by microwave sintering. Ceram. Int. 47, 21924–21933 (2021)
X.L. Wu, L. Du, Y.L. Zheng, Q. Ren, M.K. Pei, O. Hai, Synthesis and luminescent properties of new green Li2Mg1-xSiO4:xMn(2+) phosphors. Polyhedron 198, 115078 (2021)
W. Anukool, R.A. El-Nabulsi, S. Dabagh, M. Almessiere, M.G.B. Ashiq, S. Guner, A. Baykal, Effects of aluminum substitution on the microstructure and magnetic properties of cobalt ferrites prepared by the co-precipitation precursor. Appl Phys a-Mater. (2022). https://doi.org/10.1007/s00339-022-05831-3
J.W. Tao, S. Zou, D.H. He, X. Zeng, P.S. Qiu, L. Ling, X.Y. He, Fabrication and characteristics of Ce-doped Y3Fe5O12 ceramics by hot-press sintering with oxygen/nitrogen atmosphere. J Am Ceramic Soc. (2022). https://doi.org/10.1111/jace.18738
X.Y. Huo, H. Su, Y. Wang, Y.X. Li, X.L. Tang, Effects of Zn substitution on high-frequency properties of Ba(1.5)Sr(1.5)Co(2-x)ZnxFe(22)O(41) hexaferrites. Ceram Int. 47, 17120–17127 (2021)
J.J. Xu, P.P. Lin, Q.Q. Chen, X. Zhao, P. He, T.S. Lin, C.L. Jiang, Y. Liu, H.Z. Liu, W.M. Long, Evolutionary mechanism of YBO3 whisker and its effect on the properties of YIG ferrite joint brazed by Bi2O3-B2O3-SiO2-ZnO glass. Ceram. Int. 47, 973–983 (2021)
H.R. Wu, F.Z. Huang, R.X. Ti, X.M. Lu, C.Y. Zhang, L. Yuan, Y. Xu, L.W. Zhang, Effect of Ca dopant on magnetic and magnetodielectric properties of Y3Fe5O12. J Alloys Compd. 861, 157996 (2021)
A. Krysztofik, S. Ozoglu, R.D. McMichael, E. Coy, Effect of strain-induced anisotropy on magnetization dynamics in Y3Fe5O12 films recrystallized on a lattice-mismatched substrate. Sci Rep. (2021). https://doi.org/10.1038/s41598-021-93308-3
M.A. Yousuf, M.M. Baig, N.F. Al-Khalli, M.A. Khan, M.F.A. Aboud, I. Shakir, M.F. Warsi, The impact of yttrium cations (Y3+) on structural, spectral and dielectric properties of spinel manganese ferrite nanoparticles. Ceram. Int. 45, 10936–10942 (2019)
E. Varouti, E. Devlin, Y. Sanakis, M. Pissas, C. Christides, G.N. Tomara, P.K. Karahaliou, S.N. Georga, C.A. Krontiras, A systematic Mossbauer spectroscopy study of Y3Fe5O12 samples displaying different magnetic ac-susceptibility and electric permittivity spectra. J Magn Magn Mater. 495, 165881 (2020)
Acknowledgements
This work was supported by the National Key R&D Program of China (No. 2022YFB3504800), by the National Key Research and Development Program of China (No. 2018YFE0115500), by National Natural Science Foundation of China Nos. 52003256, 51902037.
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CW: methodology, writing-orignal draft. BL: formal analysis. YX: results discussion. WL: results discussion. SW: data testing and analysis. YL: writing- review and editing. PZ: results discussion. CW: data testing. JL: funding acquisition, writing- review and editing.
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Wu, C., Lu, B., Xiao, Y. et al. Enhanced magnetic and dielectric properties of In3+-doped Y2BiInxFe5−xO12 ferrites for microwave device applications. Appl. Phys. A 129, 867 (2023). https://doi.org/10.1007/s00339-023-07159-y
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DOI: https://doi.org/10.1007/s00339-023-07159-y