Abstract
There has been tremendous research progress among scientists in the development of hybrid solar cells (HSC) as green solar energy. The research aims to investigate the influence of several types of transparent conductive electrodes on the performance of fabricated HSC. Single-layer graphene (SG)-based film has been identified as a potential replacement for indium tin oxide (ITO)-based film as anode transparent conductive layer (ATCL) in HSC. In this work, we have fabricated ITO-based HSC (ISc), SG-based HSC (GSc), and heat-treated SG-based HSC (HGSc). It was observed that the power conversion efficiency (PCE) was significantly dependent on the types of ATCL. These significant findings are measured by Raman spectroscopy, a UV–Vis spectrophotometer, and a solar simulator. The HGSc possesses the best PCE of 1.960%, compared to 1.225% in the ISc, with an open-circuit voltage (Voc) of 0.5 V, a short-circuit photocurrent density (Jsc) of 11.2 mAcm−2, and a fill factor (FF) of 0.35. The properties of heat-treated SG-based film were significantly attributed to PCE enhancement in HSC. As a conclusion, the use of graphene-based film has opened up a new research interest in the solar cell fabrication process.
Similar content being viewed by others
Author contributions
All authors contributed to the study conception and design, as stated in the following: conceptualisation and supervision: MFM and MR. Methodology: MSS and MFM. Formal analysis and investigation: MSS and MFM. Resources: MFM, ABS and SMS. Writing-original draft: MSS and MFM. Writing-review and editing: MSS, MFM, ABS, SMS and MR. Project administration: MFM and ABS. Prior to the submission, all authors have read and approved the final manuscript.
Data availability
Data will be made available on request.
References
P.R. Wallace, The band theory of graphite. Phys. Rev. 71, 622–634 (1947)
K. Novoselov, A. Geim, S. Morozov et al., Science 306, 666 (2004)
P. Avouris, Z. Chen, V. Perebeinos, Carbon-based electronics. Nat. Immunol. 2, 605–615 (2007)
P.A. Denis, F. Iribarne, Comparative study of defect reactivity in graphene. J. Phys. Chem. C 117(37), 19048–19055 (2013)
A.A. Balandin, S. Ghosh, W. Bao et al., Superior thermal conductivity of single-layer graphene. Nano Lett. 8(3), 902–907 (2008)
E. Stolyarova, K.T. Rim, S. Ryu et al., High-resolution scanning tunneling microscopyimaging of mesoscopic graphene sheets on an insulating surface. Proc. Natl. Acad. Sci. U.S.A. 104(22), 9209–9212 (2007)
R.R. Nair, P. Blake, A.N. Grigorenko et al., Fine structure constant defines visual transparency of graphene. Science 320(5881), 1308 (2008)
F. Giannazzo, I. Deretzis, A. La Magna et al., Electronic transport at monolayer-bilayer junctions in epitaxial graphene on SiC. Phys. Rev. B 86, 235422 (2012)
I.V. Gornyi, V.Y. Kachorovskii, A.D. Mirlin, Conductivity of suspended graphene at the Dirac point. Phys. Rev. B 86, 165413 (2012)
J.H. Chen, C. Jang, S. Xiao et al., Intrinsic and extrinsic performance limits of graphene devices on SiO2. Nat. Nanotechnol.Nanotechnol. 3, 206–209 (2008)
A. Akturk, N. Goldsman, Electron transport and full-band electron-phonon interactions in graphene. J. Appl. Phys. 103, 053702 (2008)
F. Bonaccorso, L. Colombo, G. Yu, Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage. Science 347, 6217 (2015)
P. Soukiassian, Will graphene be the material of the 21st century? MRS Bull. 37(12), 1321 (2012)
E. Becquerel, Mémoire sur les effets électriques produits sous l’influence des rayons solaires. Compt. Rend. Acad. Sci. 9, 561–567 (1839)
Y. Sun, W. Zhang, H.J. Chi et al., Recent development of graphene materials applied in polymer solar cell. Renew. Sustain. Energy Rev. 43, 973–980 (2015)
Z. Zhang, L. Wei, X. Qin et al., Carbon nanomaterials for photovoltaic process. Nano Energy 15, 490–522 (2015)
S.H. Kim, Y.J. Noh, S.N. Kwon et al., Efficient modification of transparent graphene electrodes by electron beam irradiation for organic solar cells. J. Ind. Eng. Chem. 26, 210–213 (2015)
G.S. Selopal, R. Milan, L. Ortolani et al., Graphene as transparent front contact for dye sensitized solar cells. Sol. Energy Mater. Sol. Cells 135, 99–105 (2015)
X. Wang, L. Zhi, K. Mullen, Transparent, conductive graphene electrodes for dye-sensitized solar cells. Nano Lett. 8(1), 323–327 (2008)
V.C. Tung, L.M. Chen, M.J. Allen et al., Low-temperature solution processing of graphene-carbon nanotube hybrid materials for high-performance transparent conductors. Nano Lett. 9(5), 1949–1955 (2009)
G. Eda, Y.Y. Lin, S. Miller et al., Transparent and conducting electrodes for organic electronics from reduced graphene oxide. Appl. Phys. Lett. 92, 233305 (2008)
J. Wu, H.A. Becerril, Z. Bao et al., Organic solar cells with solution-processed graphene transparent electrodes. Appl. Phys. Lett. 92, 263302 (2008)
X. Wang, L. Zhi, N. Tsao et al., Transparent carbon films as electrodes in organic solar cells. Angew. Chem. Int. Ed.. Chem. Int. Ed. 47(16), 2990–2992 (2008)
B. Szyszka, P. Loebmannb, A. Georg et al., Development of new transparent conductors and device applications utilizing a multidisciplinary approach. Thin Solid Film 518(11), 3109–3114 (2010)
C.G. Granqvist, Transparent conductors as solar energy materials: a panoramic review. Sol. Energy Mater. Sol. Cells 91(17), 1529–1598 (2007)
M.F. Malek, M.Z. Sahdan, M.H. Mamat et al., A novel fabrication of MEH-PPV/Al:ZnO nanorod arrays based ordered bulk heterojunction hybrid solar cells. Appl. Surf. Sci. 275, 75–83 (2013)
M.Z. Sahdan, M.F. Malek, M.S. Alias et al., Fabrication of inverted bulk heterojunction organic solar cells based on conjugated P3HT:PCBM using various thicknesses of ZnO buffer layer. Optik 126(6), 645–648 (2015)
L.W. Schwartz, R.V. Roy, Theoretical and numerical results for spin coating of viscous liquids. Phys. Fluids 16(3), 569–584 (2004)
Solar cell woes. Nat. Photon. 8, 665 (2014). https://doi.org/10.1038/nphoton.2014.212
R.C. Willson, New radiometric techniques and solar constant measurements. Sol. Energ. 14(2), 203–211 (1973)
Z.J. Lapin, R. Beams, L.G. Cançado et al., Near-field Raman spectroscopy of nanocarbon materials. Faraday Discuss. (2015). https://doi.org/10.1039/C5FD0050E
T.L. Vasconcelos, B.S. Archanjo, B. Fragneaud et al., Tuning localized surface plasmon resonance in scanning near-field optical microscopy probes. ACS Nano (2015). https://doi.org/10.1021/acsnano.5b01794
F.D. Heinz, W. Warta, M.C. Schubert, Optimizing micro Raman and PL Spectroscopy for solar cell technological assessment. Ener. Proc. 27, 208–211 (2012)
A. Jorio, L.G. Cançado, Perspectives on Raman spectroscopy of graphene-based systems: from perfect two-dimensional surface to charcoal. Phys. Chem. Chem. Phys. 14(44), 15246–15256 (2012)
M.S. Dresselhaus, A. Jario, L.G. Cançado et al., “Raman spectroscopy: characterization of edges, defects, and the fermi energy of graphene and sp2 carbons, in Graphene nanoelectronics. (Springer, Berlin Heidelberg, 2012), pp.15–55
V. Carozo, C.M. Almeida, E.H.M. Ferreira et al., Raman signature of graphene superlattices. Nano Lett. 11(11), 4527–4534 (2011)
L.G. Cançado, A. Jorio, M.A. Pimenta, Measuring the absolute Raman cross section of nanographites as a function of laser energy and crystallite size. Phys. Rev. B 76, 064304 (2007). https://doi.org/10.1103/PhysRevB.76.064304
K. Sato, R. Saito, Y. Oyama, D-band Raman intensity of graphitic materials as a function of laser energy and crystallite size. Chem. Phys. Lett. 427(1–3), 117–121 (2006)
A. Grüneis, R. Saito, J. Jiang et al., Electron-phonon interaction and Raman intensities in graphite. AIP Conf. Proc. 732, 372 (2004). https://doi.org/10.1063/1.1812110
M.A. Pimenta, A. Jorio, M.S.S. Dantas et al., Resonance Raman scattering in carbon nanotubes and nanographites. AIP Conf. Proc. 685, 219 (2003). https://doi.org/10.1063/1.1628022
L.G. Cançado, M.A. Pimenta, R. Saito et al., Stokes and anti-Stokes double resonance Raman scattering in two-dimensional graphite. Phys. Rev. B 66, 035415 (2012). https://doi.org/10.1103/PhysRevB.66.035415
A. Grüneis, R. Saito, T. Kimura et al., Determination of two-dimensional phonon dispersion relation of graphite by Raman spectroscopy. Phys. Rev. B 65, 155405 (2002). https://doi.org/10.1103/PhysRevB.65.155405
A.C. Ferrari, D.M. Basko, Raman spectroscopy as a versatile tool for studying the properties of graphene. Nat. Nanotechnol.Nanotechnol. 8, 235–246 (2013)
S.J.A. Moniz, R.Q. Cabrera, C.S. Blackman et al., A simple, low-cost CVD route to thin films of BiFeO3 for efficient water photo-oxidation. J. Mat. Chem A 2, 2922–2927 (2014)
Y.T. Shih, C.Y. Chiu, C.W. Chang et al., Stimulated emission in highly (0001)-oriented ZnO films grown by atomic layer deposition on the amorphous glass substrates. J. Electrochem. Soc.Electrochem. Soc. 157(9), H879–H883 (2010)
U. Eppelt, S Russ C. Hartmann et al., “Diagnostic and simulation of ps-laser glass cutting,” 31st International Congress on Applications of Lasers & Electro-Optics (ICALEO 2012), 10 (2012)
L.G. Cançado, A. Reina, J. Kong et al., Geometrical approach for the study of G′ band in the Raman spectrum of monolayer graphene, bilayer graphene, and bulk graphite. Phys. Rev. B 77, 245408 (2008). https://doi.org/10.1103/PhysRevB.77.245408
L.G. Cançado, K. Takai, T. Enoki et al., Measuring the degree of stacking order in graphite by Raman spectroscopy. Carbon 46(2), 272–275 (2008)
L.G. Cançado, A. Jorio, E.H.M. Ferreira et al., Quantifying defects in graphene via Raman spectroscopy at different excitation energies. Nano Lett. 11(8), 3190–3196 (2011)
R. Beams, L.G. Cançado, L. Novotny, Low temperature Raman study of the electron coherence length near graphene edges. Nano Lett. 11(3), 1177–1181 (2011)
R. Beams, L. G. Cançado, L. Novotny, “Optical measurement of the phase-breaking length in graphene,” Proceedings Frontiers in Optics 2010/Laser Science XXVI. doi:https://doi.org/10.1364/LS.2010.LMB4
A. Jario, L.G. Cançado, E.H.M. Ferreira et al., Raman spectroscopy to study disorder and perturbations in sp2 nano-carbons. AIP Conf. Proc. 1267, 192 (2010). https://doi.org/10.1063/1.3482461
M.A. Pimenta, G. Dresselhaus, M.S. Dresselhaus et al., Studying disorder in graphite-based systems by Raman spectroscopy. Phys. Chem. Chem. Phys. 9, 1276–1291 (2007)
L.G. Cançado, K. Takai, T. Enoki et al., General equation for the determination of the crystallite size La of nanographite by Raman spectroscopy. Appl. Phys. Lett. 88, 163106 (2006)
L.C. Chen, T.Y. Wang, J.R. Yang et al., Growth, characterization, optical and X-ray absorption studies of nano-crystalline diamond films. Diam. Relat. Mater.Relat. Mater. (2000). https://doi.org/10.1016/S0925-9635(99)00355-6
D.L. Duong, G.H. Han, S.M. Lee et al., Probing graphene grain boundaries with optical microscopy. Nature 490, 235–239 (2012)
W. Wu, Q. Yu, P. Peng et al., Control of thickness uniformity and grain size in graphene films for transparent conductive electrodes. Nanotechnology 23(3), 035603 (2012)
P.H. Joshi, D.P. Korfiatis, S.F. Potamianou et al., Oxide thickness and roughness factor as paramters for TiO2-dye sensitized solar cells performance. Russ. J. Electrochem.Electrochem. 47(5), 517–521 (2011)
D.N. Kouvatnos, A.T. Voutsas, M.K. Hatalis, High-performance thin film transistors in large grain size polysilicon deposited by thermal decomposition of disilane. IEEE Trans. Electron Devices 43(9), 1399–1406 (1996)
A.B. Suriani, M.D. Nurhafizah, A. Mohamed et al., A facile one-step method for graphene oxide/natural rubber latex nanocomposite production for supercapacitor applications. Mater. Lett. 161, 665–668 (2015)
J. Rafiee, M.A. Rafiee, Z.Z. Yu et al., Superhydrophobic to superhydrophilic wetting control in graphene films. Adv. Mater. 22, 2151–2154 (2010)
N.A. Patankar, On the modeling of hydrophobic contact angles on rough surfaces. Langmuir 19(4), 1249–1253 (2007)
Z. Wang, N. Koratkar, L. Ci et al., Combined micro-/nanoscale surface roughness for enhanced hydrophobic stability in carbon nanotube arrays. Appl. Phys. Lett. 90, 143117 (2007)
L. Zhu, Y. Xiu, J. Xu et al., Superhydrophobicity on two-tier rough surfaces fabricated by controlled growth of aligned carbon nanotube arrays coated with fluorocarbon. Langmuir 21(24), 11208–11212 (2005)
C.J. Shih, Q.H. Wang, S. Lin et al., Breakdown in the wetting transparency of graphene. Phys. Rev. Lett. 109, 176101 (2012)
F. Taherian, V. Marcon, N.F.A. van der Vegt et al., What is the contact angle of water on graphene. Langmuir 29(5), 1457–1465 (2013)
J. Rafiee, X. Mi, H. Gullapalli et al., Wetting transparency of graphene. Nat. Mater. 11, 217–222 (2012)
Z. Li, Y. Wang, A. Kozbial et al., Effect of airborne contaminants on the wettability of supported graphene and graphite. Nat. Mater. 12, 925–931 (2013)
M. Munz, C.E. Giusca, R.L. Myers-Ward et al., Thickness-dependent hydrophobicity of epitaxial graphene. ACS Nano 9(8), 8401–8411 (2015)
W. Nie, H. Tsai, R. Asadpour et al., High-efficiency solution-processed perovskite solar cells with millimeter-scale grains. Science 347, 522–525 (2015)
X. Zhu, W.C.H. Choy, F. Xie et al., A study of optical properties enhancement in low-bandgap polymer solar cells with embedded PEDOT:PSS gratings. Sol. Energ Mat. C. 99, 327–332 (2012)
S. Ulum, N. Holmes, D. Darwis et al., Determining the structural motif of P3HT: PCBM nanoparticulate organic photovoltaic devices. Sol. Energ Mat. Sol. C. 110, 43–48 (2013)
A. Welte, C. Waldauf, C. Brabec et al., Application of optical absorbance for the investigation of electronic and structural properties of sol–gel processed TiO2 films. Thin Solid Films 516(20), 7256–7259 (2008)
H. Hoppe, N.S. Sariciftci, Organic solar cells: an overview. J. Mat. Res. 19(7), 1924–1945 (2004)
J. Rostalskia, D. Meissner, Photocurrent spectroscopy for the investigation of charge carrier generation and transport mechanisms in organic p/n-junction solar cells. Sol. Energ. Mat. Sol. C. 63(1), 34–47 (2000)
M.H. Abdullah, L.N. Ismail, M.H. Mamat et al., Novel encapsulated ITO/arc-ZnO:TiO2 antireflactive passivating layer for TCO conducting substrate prepared by simultaneous radio frequency-magnetron sputtering. Microelectron. Eng. 108, 138–104 (2013)
M.H. Abdullah, M. Rusop, Improved performance of dye-sesitized solar cell with a speacially tailored TiO2 compact layer prepared by RF magnetron sputtering. J. Alloy. Compd. 600, 60–66 (2014)
M.H. Abdullah, M. Rusop, Novel ITO/arc-TiO2 antireflective conductive substrate for transmittance enhanced properties in dye-sensitized solar cells. Microelectron. Eng. 108, 99–105 (2013)
M.H. Abdullah, M. Rusop, RF sputtered tri-functional antireflective TiO2 (arc-TiO2) compact layer for performance enhancement in dye-sensitised solar cell. Ceram. Int. 40, 967–974 (2014)
H. Kim, K. Lee, Role of interpenetrating networks in the device performance of polymer-fullerene photovoltaic cells. J. Korean Phys. Soc. 42(1), 183–186 (2003)
G.X.R. Smith, R. Crook, J.D. Wadhawan, Measuring the work function of TiO2 nanotubes using illuminated electrostatic force microscopy. J. Phys. Conf. Ser. (2013). https://doi.org/10.1088/1742-6596/471/1/012045
J.S. Kim, B. Lägel, E. Moons et al., Kelvin probe and ultraviolet photoemission measurements of indium tin oxide work function: a comparison. Synthetic Metal. 111–112, 311–314 (2000)
V. Panchal, T. L. Burnett, R. Pearce et al, “Surface potential variations in epitaxial graphene devices investigated by electrostatic force spectroscopy,” 12th IEEE Conference on Nanotechnology (IEEE-NANO), pp 1–5, 2012.
O. Kazakova, V. Panchal, T.L. Burnett, Epitaxial graphene and graphene–based devices studied by electrical scanning probe microscopy. Crystals 3(1), 191–233 (2013)
N. Koch, A. Elschner, J. Schwartz et al., Organic molecular films on gold versus conducting polymer: Influence of injection barrier height and morphology on current–voltage characteristics. Appl. Phys. Lett. (2003). https://doi.org/10.1063/1.1565506
H.H. Malitson, The solar electromagnetic radiation environment. Sol. Energ. 12(2), 197–203 (1968)
C.A. Gueymard, The sun’s total and spectral irradiance for solar energy applications and solar radiation models. Sol. Energ. 76(4), 423–453 (2004)
Acknowledgements
This work was supported in part by grant nos. 600-RMC/YTR/5/3 (005/2021) and 600-RMC/GIP 5/3 (020/2023). The authors would like to thank the Research Management Centre of the University of Southampton Malaysia, Research Management Centre of the Universiti Teknologi MARA (UiTM) and Ministry of Higher Education (MoHE), Malaysia for financial support. The IT support service from the iSolutions of the University of Southampton is greatly acknowledged. The authors also thank Mr. Salifairus Mohammad Jafar (UiTM Senior Science Officer), Mr. Mohd Azlan Jaafar (UiTM assistant engineer), Mr. Suhaimi Ahmad (UiTM assistant engineer) and Mr. Muhamad Faizal Abd Halim (Assistant Research Officer) for their kind support on this research.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no known competing financial interests or personal relationship that could have appeared to influence the work reported in this paper.
Ethical approval and consent to participate
Not applicable.
Consent for publication
Not applicable.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Shamsudin, M.S., Malek, M.F., Suriani, A.B. et al. Utilisation of heat-treated single-layer graphene as an electrode for hybrid solar cell applications. Appl. Phys. A 129, 829 (2023). https://doi.org/10.1007/s00339-023-07106-x
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00339-023-07106-x