Abstract
A composition-dependent structural, microstructure, ferroelectric, and energy storage performance of novel barium-based (1 − x)Ba(Zr0.1Ti0.9)O3 − x(Ba0.85Ca0.15)TiO3[(1 − x)BZT − xBCT] pseudo-binary systems with x = 0.0, 0.3, 0.5, 0.7 and 1 are investigated systematically. The barium zirconate titanate, BZT (x = 0.0), and barium calcium titanate, BCT (x = 1) ceramics exhibited a single-phase rhombohedral (R) and tetragonal (T) perovskite structure, respectively. The derivative of [(1 − x)BZT − xBCT] compositions with x = 0.3 enters into the orthorhombic phase (O), and the other two compositions with x = 0.5 and 0.7 compositions enter into the tetragonal phase. The surface morphologies reveal dense, uniform grain size varies from 2.59–12.05 μm with the addition of BCT to the BZT matrix. The presence of all the elements is confirmed using EDX analysis, and the existence of both Ti4+ and Ti3+ valence states in the Ti core level found in the sample. The maximum polarization is 15.06 μC/cm2 achieved for the x = 0.3 sample at 15.50 kV/cm applied field. The recoverable energy density (Wrec) and energy efficiency (η) are estimated to be nearly 167 mJ/cm3 and 42%, respectively. These outstanding characteristics of [(1 − x)BZT − xBCT] ceramics are ascribed to polymorphic phase boundaries, demonstrating their superior ferroelectric and optical properties. The present study may pave a new path in designing dielectric ceramics through intermixing MPBs for energy storage and multifunctional electro-optical devices.
Similar content being viewed by others
Data availability
The datasets generated during and/or analyzed during the current study are available from the corresponding author upon reasonable request.
References
Q. Hu, Y. Tian, Q. Zhu, J. Bian, L. Jin, H. Du, D.O. Alikin, V.Y. Shur, Y. Feng, Z. Xu, X. Wei, Nano Energy 67, 104264 (2020)
R. Verma, A. Chauhan, K.M. Batoo, M. Hadi, E.H. Raslan, R. Kumar, M.F. Ijaz, A.K. Assaifan, J. Alloys Compd. 869, 159520 (2021)
Q. Yuan, G. Li, F. Yao, S. Cheng, Y. Wang, R. Ma, Nano Energy 52, 203 (2018)
S. Priya Balmuchu, S.R.N.K. Mangalampalli, P. Dobbidi, Mater. Sci. Eng. B Solid-State Mater. Adv. Technol. 282, 115791 (2022)
S.P. Balmuchu, P. Dobbidi, J. Mater. Sci. Mater. Electron. 32, 9623 (2021)
S. Verma, P. Mahajan, B. Padha, A. Ahmed, S. Arya, Electrochim. Acta. Acta 465, 142933 (2023)
A. Ahmed, S. Verma, P. Mahajan, A.K. Sundramoorthy, S. Arya, Sci. Rep. 13, 12146 (2023)
N. Sharma, S. Verma, A. Singh, M. Gupta, S. Arya, Appl. Phys. A Mater. Sci. Process. 129, 457 (2023)
V. Bijalwan, J. Erhart, Z. Spotz, D. Sobola, V. Prajzler, P. Tofel, K. Maca, J. Am. Ceram. Soc. 104, 1088 (2021)
J.P.B. Silva, E.C. Queirós, P.B. Tavares, K.C. Sekhar, K. Kamakshi, J.A. Moreira, A. Almeida, M. Pereira, M.J.M. Gomes, J. Electroceram.Electroceram. 35, 135 (2015)
V. Madhu Babu, J. Paul Praveen, D. Das, Chem. Phys. Lett. Phys. Lett. 772, 138560 (2021)
R.L. Nayak, Y. Zhang, S.S. Dash, M.P.K. Sahoo, Ceram. Int. 48, 10803 (2022)
N. Buatip, M. Dhanunjaya, P. Amonpattaratkit, P. Pomyai, T. Sonklin, K. Reichmann, P. Janphaung, S. Pojprapai, Radiat. Phys. Chem.. Phys. Chem. 172, 108770 (2020)
A. Zhang, R. Jing, M. Zhuang, H. Hou, L. Zhang, J. Zhang, X. Lu, Y. Yan, H. Du, L. Jin, Ceram. Int. 47, 32747 (2021)
Z. Hanani, S. Merselmiz, M. Amjoud, D. Mezzane, M. Lahcini, J. Ghanbaja, M. Spreitzer, D. Vengust, M. El Marssi, I.A. Luk’yanchuk, Z. Kutnjak, B. Rožič, M. Gouné, J. Mater. Mater. 8, 873 (2022)
W. Liu, X. Ren, Phys. Rev. Lett. 103, 1 (2009)
J. Shi, X. Lu, J. Shao, B. Fang, S. Zhang, Q. Du, J. Ding, X. Zhao, H. Luo, Ferroelectrics 507, 186 (2017)
K. Xu, L. Li, P. Yang, W. Peng, Ceram. Int. 47, 25901 (2021)
R. Verma, A. Chauhan, K.M. Batoo, R. Kumar, M. Hadi, E.H. Raslan, Ceram. Int. 47, 15442 (2021)
P. Parjansri, U. Intatha, S. Eitssayeam, Mater. Res. Bull. 65, 61 (2015)
H. Amorín, M. Venet, E. Chinarro, P. Ramos, M. Algueró, A. Castro, J. Eur. Ceram. Soc. 42, 4907 (2022)
X. Ji, C. Wang, T. Harumoto, S. Zhang, R. Tu, Q. Shen, J. Shi, Sci. Rep. 10, 1 (2020)
Y. Liu, H. Zhang, W. Shi, Q. Wang, G. Jiang, B. Yang, W. Cao, J. Tan, J. Mater. Sci. Technol. Mater. Sci. Technol. 117, 207 (2022)
S. Kumari, A. Kumar, A. Kumar, V. Kumar, V.N. Thakur, Ceram. Int. 48, 13780 (2022)
H. Mezzourh, S. Belkhadir, D. Mezzane, M. Amjoud, E. Choukri, A. Lahmar, Y. Gagou, Z. Kutnjak, M. El Marssi, Phys. B Condens. Matter 603, 412760 (2021)
D.S. Keeble, F. Benabdallah, P.A. Thomas, M. Maglione, J. Kreisel, Appl. Phys. Lett. Phys. Lett. 102, 0 (2013)
V. Pal, D. Kumar, A.K. Singh, Mater. Sci. Eng. B Solid-State Mater. Adv. Technol. 288, 116194 (2023)
B. Mohanty, N.C. Nayak, B.N. Parida, R.K. Parida, Inorg. Chem. Commun.Commun. 151, 110588 (2023)
I. Coondoo, A. Krylov, D.K. Sharma, S. Krylova, D. Alikin, J.S. Kumar, A. Mirzorakhimov, N. Melnikova, M.J. Soares, A.L. Kholkin, Mater. Chem. Phys. 277, 125526 (2022)
J. Pokorńy, U.M. Pasha, L. Ben, O.P. Thakur, D.C. Sinclair, I.M. Reaney, J. Appl. Phys. 109, 114110 (2021)
A. Dahri, Y. Gagou, N. Abdelmoula, H. Khemakhem, M. El Marssi, Ceram. Int. 48, 3157 (2022)
R.M. German, Jom 68, 878 (2016)
S. Shi, H. Hashimoto, T. Sekino, Ceram. Int. 47, 3272 (2021)
P. Jaiban, M. Tongtham, P. Wannasut, N. Pisitpipathsin, O. Namsar, N. Chanlek, S. Pojprapai, R. Yimnirun, R. Guo, A.S. Bhalla, A. Watcharapasorn, Ceram. Int. 45, 17502 (2019)
M.S. Alkathy, A. Rahaman, V.R. Mastelaro, F.P. Milton, F.L. Zabotto, M.H. Lente, A. Strabello, J.A. Eiras, Mater. Chem. Phys. 294, 127032 (2023)
Q. Yu, D. Liu, R. Wang, Z. Feng, Z. Zuo, S. Qin, H. Liu, X. Xu, Mater. Sci. Eng. B Solid-State Mater. Adv. Technol. 177, 639 (2012)
T.S. Jeon, J.M. White, D.L. Kwong, Appl. Phys. Lett. 78, 368 (2001)
W. Zheng, J. Lin, X. Liu, W. Yang, Y. Li, RSC Adv. 11, 2616 (2021)
Q. Zhang, W. Cai, Q. Li, R. Gao, G. Chen, X. Deng, Z. Wang, X. Cao, C. Fu, J. Alloys Compd. 794, 542 (2019)
F. Wei, L. Zhang, R. Jing, Q. Hu, D.O. Alikin, Y.Y. Shur, J. Zhang, X. Lu, Y. Yan, H. Du, X. Wei, L. Jin, Ceram. Int. 47, 34676 (2021)
X.W. Wang, X.N. Shi, R.Y. Zhang, Y.C. Shi, Y.F. Liang, B.H. Zhang, H.N. Li, S.Y. Hu, K.X. Yu, Y.C. Hu, J. Shang, S.Q. Yin, J. Mater. Sci. Mater. Electron. 33, 20399 (2022)
W. Ji, B. Fang, X. Lu, S. Zhang, N. Yuan, J. Ding, Phys. B Condens. Matter 567, 65 (2019)
X. Lu, B. Fang, S. Zhang, N. Yuan, J. Ding, X. Zhao, F. Wang, Y. Tang, W. Shi, H. Xu, H. Luo, Funct. Mater. Lett.. Mater. Lett. 10, 1750046 (2017)
S. Merselmiz, Z. Hanani, D. Mezzane, A.G. Razumnaya, M. Amjoud, L. Hajji, S. Terenchuk, B. Rožič, I.A. Luk’yanchuk, Z. Kutnjak, RSC Adv. Adv. 11, 9459 (2021)
A.R. Jayakrishnan, K.V. Alex, A. Thomas, J.P.B. Silva, K. Kamakshi, N. Dabra, K.C. Sekhar, J. Agostinho Moreira, M.J.M. Gomes, Ceram. Int.. Int. 45, 5808 (2019)
R. Muhammad, M.A. Khalil, M.S. Castro, Ceram. Int. 46, 1059 (2020)
Y. Zhao, Q. Xu, X. Zhou, M. Yan, H. Gong, X. Yuan, Ceram. Int.. Int. 49, 8259 (2023)
Acknowledgements
The authors acknowledge the Department of Physics, Center of Nanotechnology, and Central Instrumental Facility, IIT Guwahati for the instrumental facilities. The authors are thankful to ISRO (STC#0364) and TIDF (Ref. No: TIH/2022/R-83) for the financial support. The author gratefully acknowledges the ongoing INUP-i2i and SWASTHA projects for experimental facilities. SPB is grateful for the financial assistance provided by MHRD.
Funding
No funding was received to assist with the preparation of this manuscript.
Author information
Authors and Affiliations
Contributions
SPB: conceptualization, data curation, investigation, formal analysis, writing-original draft, writing—review and editing. RP: characterization, analysis, and write-up. PD: supervision, resources, writing—review and editing.
Corresponding author
Ethics declarations
Conflict of interest
The authors have no competing interests to declare that are relevant to the content of this article.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Balmuchu, S.P., Pathak, R. & Dobbidi, P. Composition-driven (barium titanate based ceramics) pseudo-binary system for energy storage applications through ferroelectric studies. Appl. Phys. A 129, 767 (2023). https://doi.org/10.1007/s00339-023-07067-1
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00339-023-07067-1