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Large-scale facile green synthesis of porous silver nanocubes on monolithic activated carbon for room-temperature catalytic oxidation of formaldehyde

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Abstract

Porous silver nanocubes supported on monolithic activated carbon (porous Ag/MAC) have been prepared by a novel two-step, chemical reductant-free, facile and selective  process. The Ag nanocubes have been characterized using the SEM, XRD and the inner structures are revealed by the FIB-SEM technique. The growth mechanism of porous silver nanocubes on MAC is proposed based on the galvanic cell mechanism and confirmed by the characteristics of the carbon and the products at different growth stages. The porous Ag/MAC exhibits a better catalytic oxidation performance for formaldehyde removal at low temperature than bare MAC, achieving 83% formaldehyde removal with the initial concentration of 1.5 mg m−3 at 22 °C for 3 h. This better performance is attributed to the synergistic effect of adsorption, higher surface area and catalytic properties of porous silver nanocubes.

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Acknowledgements

This work is supported by the National Key Research and Development Program of China (No. 2021YFB2800700, No. 2021YFB2800703), the Chinese Academy of Sciences, the Science and Technology Commission of Shanghai Municipality (STCSM) (Grant 17230732700) and the Innovate UK (Grant 104013).

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Authors and Affiliations

  1. State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China

    Hong Dong, Yuesheng Ning & Binyuan Zhao

  2. Shanghai Key Laboratory of Hydrogen Science & Center of Hydrogen Science, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China

    Haiyan Yang

  3. State Key Laboratory of High Field Laser Physics, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai, 201800, China

    Fenghua Liu & Weiping Wu

  4. Key Laboratory of Materials for High Power Laser, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai, 201800, China

    Fenghua Liu & Weiping Wu

  5. Laboratory of Thin Film Optics, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai, 201800, China

    Fenghua Liu & Weiping Wu

  6. Department of Materials, University of Oxford, Oxford, 16 Parks Road, OX1 3PH, UK

    Robert Bradley

  7. MatSurf Technology Ltd., The Old Stables Marion Lodge, Little Salkeld, Penrith, Cumbria, CA10 1NW, UK

    Robert Bradley

  8. School of Energy Resources, University of Wyoming, Laramie, WY, 82071, USA

    Robert Bradley

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  1. Hong Dong
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Dong, H., Yang, H., Ning, Y. et al. Large-scale facile green synthesis of porous silver nanocubes on monolithic activated carbon for room-temperature catalytic oxidation of formaldehyde. Appl. Phys. A 128, 976 (2022). https://doi.org/10.1007/s00339-022-06049-z

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