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Magnetic properties of metastable bcc phase in Fe64Ni36 alloy synthesized through polyol process

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Abstract

The equilibrium FeNi alloy exhibits the bcc phase in a narrow composition less than 5 at.% Ni. Fe64Ni36 was obtained through instant chemical reduction employing polyol process and compared with Fe5Ni95 alloy. X-ray diffraction revealed bcc and fcc phases for the Fe-rich and Ni-rich FeNi compositions, respectively. The metastable bcc FeNi transformed to the fcc phase on annealing at 700 °C, whereas the Ni-rich alloy retained its fcc phase. Electron microscopic examination revealed spherical morphology for Fe64Ni36 alloy with an average size of 72 nm compared with flake-like morphology for the Fe5Ni95. The thermomagnetic analysis revealed a Curie temperature of 567 and 359 °C for the as-synthesized Fe and Ni-rich phases, respectively. An increase in Curie temperature by 30 °C was observed in both the compositions on annealing. Room temperature hysteresis loop measurements showed a saturation magnetization of 117 emu/g for bcc Fe64Ni36 alloy which increased to 165 emu/g for the fcc Fe64Ni36. The reaction kinetics involved in polyol process has enabled us to synthesis and investigate the magnetic properties of metastable bcc phase in the Fe64Ni36 composition.

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Acknowledgements

The authors acknowledge the Department of Science and Technology, Govt. of India, for the facilities sanctioned under FIST and CRG(CRG/2018/000939). RJJ acknowledges Dr. B. Jeyadevan, TUSP, Japan for his contributions.

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Authors and Affiliations

  1. Magnetic Materials Laboratory, Department of Physics, National Institute of Technology, Tiruchirappalli, 620 015, India

    G. Antilen Jacob & R. Justin Joseyphus

  2. Division of Applied Physics, University of Tsukuba, Tsukuba, Ibaraki, 305-8573, Japan

    S. Sellaiyan & A. Uedono

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  1. G. Antilen Jacob
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  2. S. Sellaiyan
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  3. A. Uedono
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  4. R. Justin Joseyphus
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Correspondence to R. Justin Joseyphus.

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Jacob, G.A., Sellaiyan, S., Uedono, A. et al. Magnetic properties of metastable bcc phase in Fe64Ni36 alloy synthesized through polyol process. Appl. Phys. A 126, 120 (2020). https://doi.org/10.1007/s00339-020-3292-3

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