Abstract
Ni–P–B coatings are produced directly on surface of carbon steel (AISI 1040) using electroless plating technique. The effects of temperature on the friction and wear behavior of Ni–P–B alloy coatings have been investigated. Tribological tests are conducted at four temperatures (30, 100, 300 and 500 °C) under constant load and sliding speed in a pin-on-disk apparatus. Results show that Ni–P–B coatings sustain the elevated temperatures with minimal effect on friction and wear performances. Ni–P–B coating is found to exhibit the maximum hardness among the binary Ni–P and Ni–B coatings with as-deposited hardness reaching around 700HV. Heat treatment increases the hardness as well as wear resistance by precipitation of boride and phosphide phases of nickel. Room temperature test shows mostly adhesive wear pattern but finally, it leads to a mixture of abrasive–adhesive wear mechanism. Friction and wear of Ni–P–B is overall governed by the formation of oxidative layer, mechanically mixed layer with iron (from ferrous counter face), wear mechanism, phase transformation and changes in microstructure during elevated wear test. Phase transformation and corresponding micro-structural changes occurring during elevated test duration help in providing better wear resistance to the coating.
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References
A. Brenner, G.E. Riddel, Nickel plating on steel by chemical reduction. J. Res. NBS 37, 31–34 (1946)
G.G. Gawrilov, Chemical (Electroless) Nickel Plating (Portcullis Press, Surrey, 1979)
W. Riedel, Electroless Nickel Plating (ASM International, Metals Park, 1991)
R.N. Duncan, T.L. Arney, Operation and use of sodium borohydride reduced electroless nickel. Plat. Surf. Finish. 71, 49–54 (1984)
Z. Guo, K.G. Keong, W. Sha, Crystallisation and phase transformation behaviour of electroless nickel phosphorus platings during continuous heating. J. Alloys Compd. 358, 112–119 (2003)
K.G. Keong, W. Sha, Crystallisation and phase transformation behaviour of electroless nickel-phosphorus deposits and their engineering properties. Surf. Eng. 18, 329–343 (2002)
T.S.N. Sankara Narayanan, S.K. Seshadri, Formation and characterization of borohydride reduced electroless nickel deposits. J. Alloys Compd. 365, 197–205 (2004)
A. Contreras, C. León, O. Jimenez, E. Sosa, R. Pérez, Electrochemical behavior and microstructural characterization of 1026 Ni–B coated steel. Appl. Surf. Sci. 253, 592–599 (2006)
Y.W. Riddle, T.O. Bailerare, Friction and wear reduction via an Ni–B electroless bath coating for metal alloys. JOM 57, 40–45 (2005)
C.T. Dervos, J. Novakovic, P. Vassiliou, Vacuum heat treatment of electroless Ni–B coatings. Mater. Lett. 58, 619–623 (2004)
S.M. Aouadi, B. Luster, P. Kohli, C. Muratore, A.A. Voevodin, Progress in the development of adaptive nitride-based coatings for high temperature tribological applications. Surf. Coat. Technol. 204, 962–968 (2009)
I.M. Allam, Solid lubricants for applications at elevated temperatures. J. Mater. Sci. 26, 3977–3984 (1991)
S. Zhu, J. Cheng, Z. Qiao, J. Yang, High temperature solid-lubricating materials: a review. Tribol. Int. (2019). https://doi.org/10.1016/j.triboint.2018.12.037
Z. Li, J. Wang, J. Lu, J. Meng, Tribological characteristics of electroless Ni–P–MoS2 composite coatings at elevated temperatures. Appl. Surf. Sci. 264, 516–521 (2013)
S. Kundu, S.K. Das, P. Sahoo, Properties of electroless nickel at elevated temperature—a review. Procedia Eng. 97, 1698–1706 (2014)
F. Masoumi, H.R. Ghasemi, A.A. Ziaei, D. Shahriari, Tribological characterization of electroless Ni-10% P coatings at elevated test temperature under dry conditions. Int. J. Adv. Manuf. Technol. 62, 1063–1070 (2012)
S. Kundu, S.K. Das, P. Sahoo, Tribological behavior of electroless Ni–P deposits under elevated temperature. Silicon 10, 329–342 (2018)
J.N. Balaraju, K.S. Rajam, Electroless deposition of Ni–Cu–P, Ni–W–P and Ni–W–Cu–P alloys. Surf. Coat. Technol. 195, 154–161 (2005)
S. Alirezaei, S.M. Monirvaghefi, A. Saatchi, M. Ürgen, A. Motallebzadeh, High temperature friction and wear behaviour of Ni–P–Ag–Al2O3 hybrid nanocomposite coating. Trans. Inst. Met. Finish. 91, 207–213 (2013)
M. Franco, W. Sha, G. Aldic, S. Malinov, H. Çimenoğlu, Effect of reinforcement and heat treatment on elevated temperature sliding of electroless Ni–P/SiC composite coatings. Tribol. Int. 97, 265–271 (2016)
S. Du, Z. Li, Z. He, H. Ding, X. Wang, Y. Zhang, Effect of temperature on the friction and wear behavior of electroless Ni–P–MoS2–CaF2 self-lubricating composite coatings. Tribol. Int. 128, 197–203 (2018)
A. Mukhopadhyay, T.K. Barman, P. Sahoo, Effect of operating temperature on tribological behavior of as plated Ni–B coating deposited by electroless method. Tribol. Trans. 61, 41–52 (2018)
A. Mukhopadhyay, T.K. Barman, P. Sahoo, Tribological behavior of electroless Ni–B–W coating at room and elevated temperatures. Proc. Inst. Mech. Eng. J.: J. Eng. Tribol. 232, 1450–1466 (2018)
A. Mukhopadhyay, T.K. Barman, P. Sahoo, Tribological behavior of sodium borohydride reduced electroless nickel alloy coatings at room and elevated temperatures. Surf. Coat. Technol. 321, 464–476 (2017)
T.S.N. Sankara Narayanan, K. Krishnaveni, S.K. Seshadri, Electroless Ni–P/Ni–B duplex coatings: preparation and evaluation of microhardness, wear and corrosion resistance. Mater. Chem. Phys. 82, 771–779 (2003)
W.X. Zhang, Z.H. Jiang, G.Y. Lio, J.S. Lian, Electroless Ni–P/Ni–B duplex coatings for improving the hardness and the corrosion resistance of AZ91D magnesium alloy. Appl. Surf. Sci. 254, 4949–4955 (2008)
V. Vitry, A. Sens, A.F. Kanta, F. Delaunois, Wear and corrosion resistance of heat treated and as-plated Duplex NiP/NiB coatings on 2024 aluminum alloys. Surf. Coat. Technol. 206, 3421–3427 (2012)
P.G. Venkatkrishna, T.S.N. Sankara Narayanan, Electroless Ni–B–P ternary alloy coating: preparation and evaluation of characteristic properties. Eur. J. Sci. Res. 82, 506–514 (2013)
P.G. Venkatkrishna, S.S. Mohamed Nazirudeen, T.S.N. Sankara Narayanan, Structural characterization and mechanical properties of as-plated and heat treated electroless Ni–B–P alloy coatings. Int. J. Eng. Technol. 6, 1059–1064 (2014)
Q.S. Shao, R.C. Bai, Z.Y. Tang, Y.F. Gao, J.L. Sun, M.S. Ren, Durable electroless Ni and Ni–PB plating on aromatic polysulfonamide (PSA) fibers with different performances via chlorine-aided silver activation strategy. Surf. Coat. Technol. 302, 164–171 (2017)
V. Vitry, L. Bonin, Increase of boron content in electroless nickel–boron coating by modification of plating conditions. Surf. Coat. Technol. 311, 185–194 (2016)
R.O. Oloyede, A.M. Bodude, E.D. Esezobor, Deposition and evaluation of electroless nickel based coating for corrosion and high temperature environment. Petro Tech Dev. J. 5(2), 4–12 (2015)
K.L. Lin, P.J. Lai, Interdiffusion of the electroless Ni–P deposit with the steel substrate. J. Electrochem. Soc. 137(5), 1509–1513 (1990)
K. Krishnaveni, T.S.N. Sankara Narayanan, S.K. Seshadri, Electroless Ni–B coatings: preparation and evaluation of hardness and wear resistance. Surf. Coat. Technol. 190, 115–121 (2005)
V. Vitry, A. Sens, A.F. Kanta, F. Delaunois, Experimental study on the formation and growth of electroless nickel–boron coatings from borohydride-reduced bath on mild steel. Appl. Surf. Sci. 263, 640–647 (2012)
S. Kundu, S.K. Das, P. Sahoo, Friction and wear behavior of electroless Ni–P–W coating exposed to elevated temperature. Surf. Interface 14, 192–207 (2019)
F. Gołek, P. Mazur, Z. Ryszka, S. Zuber, AFM image artifacts. Appl. Surf. Sci. 304, 11–19 (2014)
J.N. Balaraju, A. Priyadarshi, V. Kumar, N.T. Manikandanath, P.P. Kumar, B. Ravisankar, Hardness and wear behaviour of electroless Ni–B coatings. Mater. Sci. Technol. 32, 1654–1665 (2016)
V. Niksefat, M. Ghorbani, Mechanical and electrochemical properties of ultrasonic-assisted electroless deposition of Ni–B–TiO2 composite coatings. J. Alloys Compd. 633, 127–136 (2015)
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Kundu, S., Das, S.K. & Sahoo, P. Tribological behavior of autocatalytic Ni–P–B coatings at elevated temperatures. Appl. Phys. A 125, 520 (2019). https://doi.org/10.1007/s00339-019-2816-1
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DOI: https://doi.org/10.1007/s00339-019-2816-1