Abstract
The NiCr alloy nanowires were electrodeposited from an acidic sulphate baths into nanoporous anodized aluminume oxide (AAO). This template was fabricated by two-step anodization. The NiCr alloy nanowires were synthesized for Cr content up to 0.32% without any significant improvement in magnetic properties. Above this threshold, Cr clusters were formed and magnetic properties were decreased significantly. For Cr content of higher than 2.1% the wires were formed so short and incomplete which were like the nanoparticles. X-ray diffraction patterns revealed changing in the FCC crystal structure of Ni nanowires to an amorphous phase by increasing the Cr content. This leads to a significant decline in the magnetic properties like coercivity and squareness. The effect of thermal annealing on the magnetic properties of the NiCr alloy nanowires, showed that the squareness and the coercivity were improved by enhancing the amount of the temperature to 300 °C and were decreased by enhancing that to 500 °C.
Similar content being viewed by others
References
A. Blondel, J.P. Meier, B. Doudin, J.P. Ansermet, Giant magnetoresistance of nanowires of multilayers. Appl. Phys. Lett. 65, 3019–3021 (1994)
K. Nielsch, R.B. Wehrspohn, J. Barthel, J. Kirschner, U. Gosele, S.F. Fischer, H. Kronmuller, Hexagonally ordered 100 nm period nickel nanowire arrays. Appl. Phys. Lett. 79, 1360–1362 (2001)
L. Piraux, J.M. George, J.F. Despres, C. Leroy, E. Ferain, R. Legras, K. Ounadjela, A. Fert, Giant magnetoresistance in magnetic multilayered nanowires. Appl. Phys. Lett. 65, 2484–2486 (1994)
M. Tanase, D.M. Silevitch, A. Hultgren, L.A. Bauer, P.C. Searson, G.J. Meyer, D.H. Reich, Magnetic trapping and self-assembly of multicomponent nanowires. J. Appl. Phys. 91, 8549–8551 (2002)
D. Zhang, Z. Liu, S. Han, C. Li, B. Lei, M.P. Stewart, J.M. Tour, C. Zhou, Magnetite (Fe3O4) core−shell nanowires: synthesis and magnetoresistance. Nano Lett. 4, 2151–2155 (2004)
G.S. Cheng, L.D. Zhang, Y. Zhu, G.T. Fei, L. Li, C.M. Mo, Y.Q. Mao, Large-scale synthesis of single crystalline gallium nitride nanowires. Appl. Phys. Lett. 75, 2455–2475 (1999)
H. Xu, D.H. Qin, Z. Yang, H.L. Li, Fabrication and characterization of highly ordered zirconia nanowire arrays by sol–gel template method. Mater. Chem. Phys. 80, 524–528 (2003)
Y. Li, G.W. Meng, L.D. Zhang, F. Philipp, Ordered semiconductor ZnO nanowire arrays and their photoluminescence properties. Appl. Phys. Lett. 76, 2011–2013 (2000)
R.M. Metzger, V.V. Konovalov, M. Sun, T. Xu, G. Zangari, B. Xu, M. Benakli, W.D. Doyle, Magnetic nanowires in hexagonally ordered pores of alumina. Magn. IEEE Trans. 36, 30–35 (2000)
Z. Hao, Y. Shaoguang, N. Gang, Y. Dongliang, D. Youwei, Study on magnetic property of Fe14Ni86 alloy nanowire array. J. Magn. Mater. 234, 454–458 (2001)
H.R. Khan, K. Petrikowski, Anisotropic structural and magnetic properties of arrays of Fe26Ni74 nanowires electrodeposited in the pores of anodic alumina. J. Magn. Mater. 215, 526–528 (2000)
H.R. Khan, K. Petrikowski, Magnetic and structural properties of the electrochemically deposited arrays of Co and CoFe nanowires. J. Magn. Magn. Mater. 249, 458 (2002)
D.J. Sellmyer, M. Zheng, R. Skomski, Magnetism of Fe, Co and Ni nanowires in self-assembled arrays. J. Phys. Condens. Matter 13, R433 (2001)
T.M. Whitney, P.C. Searson, J.S. Jiang, C.L. Chien, Fabrication and magnetic properties of arrays of metallic nanowires. Science 261, 1316 (1993)
X.Y. Zhang, G.H. Wen, Y.F. Chan, R.K. Zheng, X.X. Zhang, N. Wang, Fabrication and magnetic properties of ultrathin Fe nanowire arrays. Appl. Phys. Lett. 83, 3341 (2003)
M. Kroll, W.J. Blau, D. Grandjean, R.E. Benfield, F. Luis, P.M. Paulus, L.J. de Jongh, Magnetic properties of ferromagnetic nanowires embedded in nanoporous alumina membranes. J. Magn. Mater. 249, 241–245 (2002)
J.P. O’Sullivan, G.C. Wood, The morphology and mechanism of formation of porous anodic films on aluminum. Proc. R. Soc. Lond. A 317, 511 (1970)
K. Maleki, S. Sanjabi, Z. Alemipour, DC electrodeposition of NiGa alloy nanowires in AAO template. J. Magn. Magn. Mater. 395, 289–293 (2015)
K. Maleki, S. Sanjabi, Z. Alemipour, AC electrodeposition of NiMn alloy nanowires in AAO template. Int. J. Mod. Phys. B 29, 1550224 (2015)
D.H. Qin, L. Cao, Q.Y. Sun, Y. Huang, H.L. Li, Fine magnetic properties obtained in FeCo alloy nanowire arrays. Chem. Phys. Lett. 358, 484–488 (2002)
R.L. Wang, S.L. Tang, B. Nie, X.L. Fei, Y.G. Shi, Y.W. Du, Fabrication and magnetic properties of ordered Fe 60 Pb 40 nanowire arrays electrodeposited in AAO templates. Solid State Commun. 142, 639–642 (2007)
A. Stephen, T. Nagarajan, M.V. Ananth, Magnetization behaviour of electrodeposited Ni–Mn alloys. Mater. Sci. Eng. B 55, 184–186 (1998)
A. Saedi, M. Ghorbani, Electrodeposition of Ni–Fe–Co alloy nanowire in modified AAO template. Mater. Chem. Phys. 91, 417–423 (2005)
M. Almasi Kashi, A. Ramazani, Z. Fallah, Magnetic properties improvement through off time between pulses and annealing in pulse electrodeposited CoZn nanowires. J. Alloy. Compd. 509, 8845–8849 (2011)
A. Blondel, J.P. Meier, B. Doudin, JPh Ansermet, Giant magnetoresistance of nanowires of multilayers. Phys. Lett. 65, 3019 (1994)
K. Nielsch, F. Müller, A.P. Li, U. Gösele, Uniform nickel deposition into ordered alumina pores by pulsed electrodeposition. Adv. Mater. 12, 582 (2000)
M. Srivastava, V. Ezhil Selvi, V.K. William Grips, K.S. Rajam, Corrosion resistance and microstructure of electrodeposited nickel–cobalt alloy coatings. Surf. Coat. Technol. 201, 3051 (2006)
G.A. Alers, J.R. Neighbours, H. Sato, Temperature dependent magnetic contributions to the high field elastic constants of nickel and an Fe-Ni alloy. J. Phys. Chem. Solids 13, 40 (1960)
E.O. Ezugwu, Z.M. Wang, A.R. Machado, The machinability of nickel-based alloys: a review. J. Mater. Process. Technol. 86, 1 (1999)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Maleki, K., Alemipour, Z. Electrodeposition and characterization of NiCr alloy nanowires. Appl. Phys. A 123, 397 (2017). https://doi.org/10.1007/s00339-017-1009-z
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00339-017-1009-z