Abstract
Hot filament chemical vapor deposition technique was used to deposit microcrystalline diamond (MCD) and nanocrystalline diamond (NCD) films on silicon (Si) and tungsten carbide (WC-6Co) substrates. Friction coefficient of larger diamond grains deposited on WC-6Co substrate shows less value approximately 0.2 while this differs marginally on films grown on Si substrate. The study claims that for a less friction coefficient, the grain size is not necessarily smaller. However, the less friction coefficient (less than 0.1 saturated value) in MCD and NCD deposited on Si is explained by the formation of graphitized tribolayer. This layer easily forms when diamond phase is thermodynamically unstable.
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C.A. Brookes, E.J. Brookes, Diamond on perspective a review of mechanical properties of natural diamond. Diam. Relat. Mater. 1, 13–17 (1991)
K. Miyoshi, Structures and mechanical properties of natural and synthetic diamonds. Diam. Films Technol. 8, 153–172 (1995)
A. Erdemir, O.L. Eryilmaz, G. Fenske, Synthesis of diamond like carbon films with superlow friction and wear properties. J. Vac. Sci. Technol. 18, 1987–1992 (2000)
A.V. Sumant, O. Auciello, M. Liao, O.A. Williams, MEMS/NEMS based on mano-, nano-, and ultrananocrystalline diamond films. MRS Bull. 39, 511–516 (2014)
A. Erdimer, C. Donnet, in Modern Tribology Handbook, chap. 24, ed. by B. Bhushan (CRC Press, Boca Raton, 2000)
D.R. Gilbert, D.G. Lee, R.K. Singh, Novel in situ production of smooth diamond films. J. Mater. Res. 13, 1735–1737 (1998)
R. Erz, W. Doetter, K. Jung, H. Ehrhardt, Preparation of smooth and nanocrystalline diamond films. Diam. Relat. Mater. 2, 449–453 (1993)
S. Hogmark, P. Hollman, A. Alahelisten, P. Hedenqvist, Direct current bias applied to hot flame diamond deposition produces smooth low friction coatings. Wear 200, 225–232 (1996)
F.P. Bowden, Tabor D. Friction, Lubrication of Solids. (Part I, Part II, (1964) (Clarendon Press, Oxford, 1950)
Y. Enomoto, D. Tabor, The properties of diamond. Proc. R. Soc. Lond. 373, 405–417 (1981)
F.P. Bowden, A.E. Hanwell, The friction of clean crystal surfaces. Proc. R. Soc. 295, 233–243 (1966)
S. Chandrasekar, B. Bhushan, The role of environment in the friction of diamond for magnetic recording head applications. Wear 153, 79–89 (1992)
M. Kohzaki, S. Noda, Tribological properties of CVD diamond films in various environments. Diam. Films Technol. 3, 135–148 (1994)
F.P. Bowden, J.E. Young, Friction of diamond, graphite, and carbon and influence of surface films. Proc. R. Soc. Lond. 208, 444–455 (1951)
M. Casey, J. Wilks, The friction of diamond sliding on polished cube faces of diamond. J. Phys. D Appl. Phys. 6, 1772–1781 (1973)
B. Samuels, J.J. Wilks, The friction of diamond sliding on diamond. J. Mater. Sci. 23, 2846–2864 (1988)
K. Panda, N. Kumar, B.K. Panigrahi, S.R. Polaki, S. Sundaravel, S. Dash, A.K. Tyagi, I.N. Lin, Tribol. Int. 57(9), 124–136 (2013)
W.C. Oliver, G.M. Pharr, An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments. J. Mater. Res. 7, 1564–1583 (1992)
Costas A. Charitidis, Elias P. Koumoulos, Dimitrios A. Dragatogiannis, Nanotribological behavior of carbon based thin films: friction and lubricity mechanisms at the nanoscale. Lubricants 1, 22–27 (2013)
A. Bogus, I.C. Gebeshuber, A. Pauschitz, M. Roy, R. Haubner, Micro and nanomechanical properties of diamond film with various surface morphologies. Diam. Relat. Mater. 17, 1998–2004 (2008)
A.C. Ferrari, J. Robertson, Resonant Raman spectroscopy of disordered, amorphous, and diamondlike carbon. Phys Rev B 64, 75414–75426 (2001)
N. Kumar, R. Ramadoss, A.T. Kozakov, K.J. Sankaran, S. Dash, A.K. Tyagi, N.H. Tai, I.N. Lin, Humidity-dependent friction mechanism in an ultrananocrystalline diamond film. J. Phys. D Appl. Phys. 46, 275501–275509 (2013)
R. Dumpala, M. Chandran, N. Kumar, S. Dash, B. Ramamoorthy, M.S.R. Rao, Growth and characterization of integrated nano-and microcrystalline dual layer composite diamond coatings on WC-Co substrates. Int. J. Ref. Met. Hard Mater. 37, 127–133 (2013)
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The authors acknowledge Department of Science and Technology (DST) of India for the financial support (Grant No. SR/NM/NAT-02/2005). Dr. Niranjan Kumar, IGCAR is acknowledged for the Tribology measurements.
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Radhika, R., Ramachandra Rao, M.S. Growth and tribological properties of diamond films on silicon and tungsten carbide substrates. Appl. Phys. A 122, 937 (2016). https://doi.org/10.1007/s00339-016-0473-1
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DOI: https://doi.org/10.1007/s00339-016-0473-1