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Improvement of CIGS thin-film solar cell performance by optimization of Zn(O,S) buffer layer parameters

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Abstract

The effects of Zn(O,S) buffer layer parameters on CuInGaSe (CIGS) cell performance are investigated using a physically based solar cell model. The key issue for CIGS solar cells is to remove destructive effects like pinholes due to thinning buffer layer. Choosing Zn(O,S) instead of CdS as the buffer layer provides the benefit of more transmission. The current difference between cells with CdS and Zn(O,S) buffer layers is more obvious in thicker films. Three main properties were investigated: buffer layer thickness, doping density, and oxygen content. The cell performance is investigated as multiple parameters are varied simultaneously. The effects of all physical parameters of Zn(O,S) are dependent on each other, so that by increasing Zn(O,S) carrier concentration from 1018 to 1020 cm−3, the optimum oxygen content range to have maximum efficiency will be expanded from 50–75 to 30–90 %.

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References

  1. A. Okamoto, T. Minemoto, H. Takakura, Jpn. J. Appl. Phys. 50, 04DP10 (2011)

    Article  Google Scholar 

  2. M. A. Contreras, T. Nakada, M. Hongo, A.O. Pudov, and J. R. Sites, in Proc. 3rd World Conf. on Photovoltaic Energy Conversion, 2003, p. 570

  3. T. Nakada, M. Mizutani, Y. Hagiwara, A. Kunioka, Sol. Energy Mater. Sol. Cells 67, 255–260 (2001)

    Article  Google Scholar 

  4. Solar Frontier Sets New Efficiency World Record. 2012; http://www.solar-frontier.com/eng/news/2012/C002980.html

  5. A. Hultqvist, Ph.D. thesis, Uppsala University, Uppsala, 2010

  6. A.O. Pudov, M.A. Contreras, T. Nakada, H.-W. Schock, J.R. Sites, Thin Solid Films 480–481, 273 (2005)

    Article  Google Scholar 

  7. M. Gloeckler, J.R. Sites, Thin Solid Films 480–481, 241 (2005)

    Article  Google Scholar 

  8. A. Pudov, Ph.D thesis, Impact of secondary barriers on CuIn 1x Ga x Se 2 solar cell operation, Department of Physics, Colorado State University, 2005

  9. A. Kanevce et al. Conduction-band-offset rule governing JV distortion in CdS/CI(G)S solar cells. in MRS Proceedings, Cambridge Univ Press, 2005

  10. M.A. Contreras, K. Ramanathan, J. AbuShama, Prog. Photovolt. Res. Appl. 13, 209 (2005)

    Article  Google Scholar 

  11. K. Ramanathan, J. Mann, S. Glynn, S. Christensen, J. Pankow, J. Li, J. Scharf, L. Mansfield, M. Contreras, and R. Noufi, Presented at the 2012 IEEE Photovoltaic Specialists Conference, Austin, Texas, 2012

  12. J. R. Sites, U.S. patent application 2002EA007, E-04(April 2002–March 2005)

  13. U. Zimmermann, M. Ruth and M. Edoff, in 21st European Photovoltaic Solar Energy Conference (2006) (Uppsala University, Uppsala, Sweden, 2006)

  14. M. A. Tashkandi, Ph.D. thesis, Colorado State University, Fort Collins, 2012

  15. M. A. Tashkandi, W.S. Sampath, in Photovoltaic Specialists Conference (PVSC) 37th IEEE, Seattle WA (2011), p. 001700

  16. T. Song, J.T. McGoffin, J.R. Sites, IEEE J. Photovolt. (2014). doi:10.1109/JPHOTOV.2014.2301894

    Google Scholar 

  17. A. Grimm, D. Kieven, R. Klenk, I. Lauermann, A. Neisser, T. Niesen, J. Palm, Thin Solid Films 520(4), 1330 (2011)

    Article  ADS  Google Scholar 

  18. C. Platzer-Björkman, T. Törndahl, D. Abou-Ras, J. Malmström, J. Kessler, L. Stolt, J. Appl. Phys. 100, 044506 (2006). doi:10.1063/1.2222067

    Article  ADS  Google Scholar 

  19. S. Wei, A. Zunger, Appl. Phys. Lett. 72, 2011 (1998)

    Article  ADS  Google Scholar 

  20. T. Minemoto, A. Okamoto, H. Takakura, Thin Solid Films 519, 7568 (2011)

    Article  ADS  Google Scholar 

  21. B.K. Meyer, A. Polity, B. Farangis, Y. He, D. Hasselkamp, T. Kramer, C. Wang, Appl. Phys. Lett. 85, 4929 (2004)

    Article  ADS  Google Scholar 

  22. C. Persson, C. Platzer-Björkman, J. Malmström, T. Törndahl, M. Edoff, Phys. Rev. Lett. 97(14), 146403 (2006)

    Article  ADS  Google Scholar 

  23. S. Sharbati, J.R. Sites, IEEE J. Photovolt. (2014). doi:10.1109/JPHOTOV.2014.2298093

    Google Scholar 

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Acknowledgements

The work presented here was supported in part by the National Renewable Energy Laboratory through the F-PACE project funded by the US Department of Energy’s SunShot program. The authors would also like to thank Dr. James Sites of Colorado State University for his input in this work.

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Correspondence to Samaneh Sharbati.

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Sharbati, S., Keshmiri, S.H., McGoffin, J.T. et al. Improvement of CIGS thin-film solar cell performance by optimization of Zn(O,S) buffer layer parameters. Appl. Phys. A 118, 1259–1265 (2015). https://doi.org/10.1007/s00339-014-8825-1

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  • DOI: https://doi.org/10.1007/s00339-014-8825-1

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