Abstract
Here, we report the synthesis of Pt/Ag bimetallic alloy catalyst through combining the ion implantation and electrodeposition method. Ag nanoparticles are employed as the seeds for the growth of Pt nanoparticles. Pt/Ag alloy catalyst demonstrates much higher catalytic activity than pure Pt catalyst, which is about three times more active on the basis of equivalent Pt electrochemically active surface area than that of the pure Pt catalyst. The ion implantation of Ag efficiently enhances the catalytic activity of Pt catalyst for formic acid oxidation.
Similar content being viewed by others
References
C. Rice, R.I. Ha, R.I. Masel, P. Waszczuk, A. Wieckowski, T. Barnard, J. Power Sour. 111, 83–89 (2002)
V. Mazumder, Y. Lee, S.H. Sun, Adv. Funct. Mater. 20, 1224–1231 (2010)
Y.J. Kang, L. Qi, M. Li, C.B. Murray, ACS Nano 6, 2818–2825 (2012)
G. Samjeske, A. Miki, S. Ye, A. Yamakata, Y. Mukouyama, H. Okamoto, M. Osawa, J. Phys. Chem. B 109, 23509–23516 (2005)
M. Neurock, M. Janik, A. Wieckowski, Faraday Discuss. 140, 363–378 (2008)
B.C.H. Steele, A. Heinzel, Nature 414, 345–352 (2001)
W. Vielstich, A. Lamm, H.A. Gasteiger, Hand book of Fuel Cells: Fundamentals, Technology, and Applications, 1st edn. (Wiley, West Sussex, 2003)
W. Vogel, L. Lundquist, P. Ross, P. Stonehart, Electrochim. Acta 20, 79–93 (1975)
H.A. Gasteiger, S.S. Kocha, B. Sompalli, F.T. Wagner, Appl. Catal. B 56, 9–35 (2005)
P.J. Ferreira, G.J. La’O, Y. Shao-Horn, D. Morgan, R. Makharia, S. Kocha, H.A. Gasteiger, J. Electrochem. Soc. 152, A2256–A2271 (2005)
I. Smova-Sloufova, F. Lednicky, A. Gemperle, J. Gemperlova, Langmuir 16, 9928–9935 (2000)
M. Kambayashi, J. Zhang, M. Oyama, Cryst. Growth Des. 5, 81–84 (2005)
T. Xu, S. Yang, J. Lu, Q. Xue, J. Li, W. Guo, Y. Sun, Diam. Relat. Mater. 10, 1441–1447 (2001)
R.S. Jayashree, J.S. Spendelow, J. Yeom, C. Rastogi, M.A. Shannon, P.J.A. Kenis, Electrochim. Acta 50, 4674–4682 (2005)
E. Casado-Rivera, D.J. Volpe, L. Alden, C. Lind, C. Downie, T. Vazquez-Alvarez, A.C.D. Angelo, F.J. Disalvo, H.D. Abruna, J. Am. Chem. Soc. 126, 4043–4049 (2004)
F. Papa, A. Miyazaki, M. Scurtu, A.C. Ianculescu, I. Balint, J. Nanopart. Res. 16, 2249 (2014)
S. Charnvanichborikarn, J. Wong-Leung, J.S. Williams, J. Appl. Phys. 106, 1035261–1035268 (2009)
W.Q. Zhang, J.Z. Yang, X.M. Lu, ACS Nano 6, 7397–7405 (2012)
D. Zhao, B. Yan, B.Q. Xu, Electrochem. Commun. 10, 884–887 (2008)
J. Yang, J.Y. Lee, L.X. Chen, H.P. Too, J. Phys. Chem. B 109, 5468–5472 (2005)
L. Tammeveski, H. Erikson, A. Sarapuu, J. Kozlova, P. Ritslaid, V. Sammelselg, K. Tammeveski, Electrochem. Commun. 20, 15–18 (2012)
A.S. Rad, A. Mirabi, E. Binaian, H. Tayebi, Int. J. Electrochem. Sci. 6, 3671–3683 (2011)
S. Rosset, M. Niklaus, P. Dubois, H.R. Shea, Sens. Actuators A 144, 185–193 (2008)
K. Okamura, T. Ishiji, M. Iwaki, Y. Suzuki, K. Takahashi, Surf. Coat. Technol. 201, 8116–8119 (2007)
H. Quan, S.U. Park, J. Park, Electrochim. Acta 55, 2232–2237 (2010)
Y.J. Kang, L. Qi, M. Li, R.E. Diaz, C.B. Murray, ACS Nano 6, 2818–2825 (2012)
T. Matsushita, Y. Shiraishi, S. Horiuchi, N. Toshima, Bull. J. Chem. Soc. 80, 1217–1225 (2007)
N. Toshima, R. Ito, T. Matsushita, Y. Shiraishi, Catal. Today 122, 239–244 (2007)
Acknowledgments
The authors owe special thanks to the support and sponsor of the National Natural Science Foundation of China (No.20873012) and the Key Lab of Radiation Beam Technology and Material Modification of National Ministry of Education, China.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Guo, C., Hu, J. Bimetallic alloy Pt/Ag nanoparticles with enhanced catalytic activity for formic acid oxidation. Appl. Phys. A 117, 809–813 (2014). https://doi.org/10.1007/s00339-014-8441-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-014-8441-0