Abstract
The effect of various nanoclay loading levels on the properties of unsaturated polyester/clay nanocomposites was investigated. Nanocomposites containing 1, 3, 5, and 7 wt% organically modified nanoclay were prepared via in situ polymerization. Success of the polymerization reaction was demonstrated by the FTIR spectra. The morphological structure of the samples was examined by XRD measurements. Moreover, TEM micrograph of one of the samples was also studied. Density and water absorption measurements revealed that the incorporation of the nanoclay to the polymeric matrix could reduce the volume shrinkage of UP resin during the curing process and could improve the resistance of the material against water diffusion. DSC analysis showed that the initiation temperature and the curing temperature range decreased after the addition of nanoclay. Improvement in the thermal and corrosion resistance of the nanocomposites compared to the pure UP polymer was shown by TGA and electrochemical resistance measurements, respectively, and the best properties were observed for the nanocomposite containing 5 wt% nanoclay. Finally, the effect of electron beam irradiation on the properties of the nanocomposite samples was investigated. Irradiation with doses up to 500 kGy leads to an increase in water absorption resistance, corrosion resistance, and density of the nanocomposite. However, higher examined dose of irradiation (1000 kGy) had a deteriorating effect on the nanocomposite properties.
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References
Ray SS, Okamoto M (2003) Polymer/layered silicate nanocomposites: a review from preparation to processing. Prog Polym Sci 28:1539–1641
Hassan M, Reddy KR, Haque E, Minett AI, Gomes VG (2013) High-yield aqueous phase exfoliation of grapheme for facile nanocomposite synthesis via emulsion polymerization. J Colloid Interface Sci 410:43–51
Han SJ, Lee HI, Jeonga HM, Kim BK, Raghu AV, Reddy KR (2014) Graphene modified lipophilically by stearic acid and its composite with low density polyethylene. J Macromol Sci Part B Phys 53:1193–1204
Choi SH, Kim DH, Raghu AV, Reddy KR, Lee HI, Yoon KS, Jeong HM, Kim BK (2012) Properties of graphene/waterborne polyurethane nanocomposites cast from colloidal dispersion mixtures. J Macromol Sci Part B Phys 51:197–207
Hassana M, Reddya KR, Haqueb E, Faisalb SN, Ghasemia S, Minettb AI, Gomes VG (2014) Hierarchical assembly of graphene/polyaniline nanostructures to synthesize free-standing supercapacitor electrode. Compos Sci Technol 98:1–8
Zhang YP, Lee SH, Reddy KR, Gopalan AI, Lee KP (2007) Synthesis and characterization of core-shell SiO2 nanoparticles/poly(3-aminophenylboronic acid) composites. J Appl Polym Sci 104:2743–2750
Reddy KR, Hassan M, Gomes VG (2015) Hybrid nanostructures based on titanium dioxide for enhanced photocatalysis. Appl Catal A 489:1–16
Lee YR, Kim SC, Lee HI, Jeong HM, Raghu AV, Reddy KR, Kim BK (2011) Graphite oxides as effective fire retardants of epoxy resin. Macromol Res 19:66–71
Reddy KR, Lee KP, Gopalan AI, Md Showkat A (2006) Synthesis and properties of magnetite/poly (aniline-co-8-amino-2-naphthalenesulfonic acid) (SPAN) nanocomposites. Polym Adv Technol 18:38–43
Reddy KR, Sin BC, Ryu KS, Kim JC, Chung H, Lee Y (2009) Conducting polymer functionalized multi walled carbon nanotubes with noble metal nanoparticles: synthesis, morphological characteristics and electrical properties. Synth Met 159:595–603
Versavaud S, Régnier G, Gouadec G, Vincent M (2014) Influence of injection molding on the electrical properties of polyamide 12 filled with multi-walled carbon nanotubes. Polymer 55:6811–6818
Pavlidou S, Papaspyrides CD (2008) A review on polymer–layered silicate nanocomposites. Prog Polym Sci 33:1119–1198
de Azeredo HMC (2009) Nanocomposites for food packaging applications. Food Res Int 42:1240–1253
Chirayil CJ, Mathew L, Hassan PA, Mozetic M, Thomas S (2014) Rheological behaviour of nanocellulose reinforced unsaturated polyester nanocomposites. Int J Biol Macromol 69:274–281
Sudirman Anggaravidya M, Budianto E, Gunawan I (2012) Synthesis and characterization of polyester-based nanocomposite. Proc Chem 4:107–113
Pereira CMC, Herrero M, Labajos FM, Marques AT, Rives V (2009) Preparation and properties of new flame retardant unsaturated polyester nanocomposites based on layered double hydroxides. Polym Degrad Stab 94:939–946
Jo BW, Park SK, Kim DK (2008) Mechanical properties of nano-MMT reinforced polymer composite and polymer concrete. Constr Build Mater 22:14–20
Tsai TY, Kuo CH, Chen WC, Hsu CH, Chung CH (2010) Reducing the print-through phenomenon and increasing the curing degree of UP/ST/organo-montmorillonite nanocomposites. Appl Clay Sci 49:224–228
Kornmann X, Berglund LA, Sterte J, Giannelis EP (1998) Nanocomposites based on montmorillonite and unsaturated polyester. Polym Eng Sci 38:1351–1358
Bharadwaj RK, Mehrabi AR, Hamilton C, Trujillo C, Murga M, Fan R, Chavira A, Thompson AK (2002) Structure–property relationships in cross-linked polyester–clay nanocomposites. Polymer 43:3699–3705
Dhakal HN, Zhang ZY, Richardson MOW (2006) Nanoindentation behaviour of layered silicate reinforced unsaturated polyester nanocomposites. Polym Test 25:846–852
Chieruzzi M, Miliozzi A, Kenny JM (2013) Effects of the nanoparticles on the thermal expansion and mechanical properties of unsaturated polyester/clay nanocomposites. Compos A 45:44–48
Ollier R, Rodriguez E, Alvarez V (2013) Unsaturated polyester/bentonite nanocomposites: influence of clay modification on final performance. Compos A 48:137–143
Şen S, Gündem HB, Ortaç B (2013) Property enhancement in unsaturated polyester nanocomposites by using a reactive intercalant for clay modification. J Appl Polym Sci 129:3247–3254
Inceoglu AB, Yilmazer U (2003) Synthesis and mechanical properties of unsaturated polyester based nanocomposites. Polym Eng Sci 43:661–669
Jawahar P, Gnanamoorthy R, Balasubramanian M (2006) Tribological behaviour of clay– thermoset polyester nanocomposites. Wear 261:835–840
Nazare S, Kandola BK, Horrocks AR (2006) Flame-retardant unsaturated polyester resin incorporating nanoclays. Polym Adv Technol 17:294–303
Iseghem PV (2012) Corrosion issues of radioactive waste packages in geological disposal systems. In: Féron D (ed) Nuclear corrosion science and engineering. Woodhead, Oxford, pp 939–987
Ruban YJV, Mon SG, Roy DV (2014) Chemical resistance/thermal and mechanical properties of unsaturated polyester-based nanocomposites. Appl Nanosci 4:233–240
Miller AA (1959) Effects of high-energy radiation on polymers. Ann N Y Acad Sci 82:774–781
Wilski H (1992) The radiation resistance of thermoset plastics VI. Unsaturated polyester plastics. Radiat Phys Chem 39:407–411
Ismail MR, Ali MAM, Afifi MS, El-Miligy AA (1999) Studies on sand-unsaturated polyester composite materials. Polym Plast Technol Eng 38:351–369
Urban MW, Gaboury SR, Provder T (1991) Spectroscopic evidence for styrene homopolymerization during polyester/styrene crosslinking. Polym Commun 32:171–175
Malik M, Choudhary V, Varma IK (2000) Current status of unsaturated polyester resins. J Macromol Sci Part C Polym Rev 40:139–165
Yang YS, Lee LJ, Tom Lo SK, Menardi PJ (1989) Monitoring the cure of unsaturated polyester resins by pressure DSC and FTIR-PLC. J Appl Polym Sci 37:2313–2330
Huang YJ, Leu JS (1993) Curing of unsaturated polyester resins. Effects of temperature and initiator: 1. Low temperature reactions. Polymer 34:295–304
Grunden BL, Sung CSP (2003) Cure characterization of unsaturated polyester resin by near-IR and mid-IR spectroscopy. Macromolecules 36:3166–3173
Chen CY, Huang CK, Lin SP, Han JL, Hsieh KH, Lin CP (2008) Low-shrinkage visible-light-curable urethane-modified epoxy acrylate/SiO2 composites as dental restorative materials. Compos Sci Technol 68:2811–2817
Xu L, Lee LJ (2004) Effect of nanoclay on shrinkage control of low profile unsaturated polyester (UP) resin cured at room temperature. Polymer 45:7325–7334
Pomies F, Carlsson LA, Gillespie JW (1995) In: Martin RH (ed) Marine environmental effects on polymer matrix composites. ASTM, Philadelphia
Davies P, MazÉas F, Casari P (2001) Sea water aging of glass reinforced composites: shear behaviour and damage modelling. J Compos Mater 35:1343–1372
Ben Daly H, Ben Brahim H, Hfaied N, Harchay M, Boukhili R (2007) Investigation of water absorption in pultruded composites containing fillers and low profile additives. Polym Compos 28:355–364
Md Akil H, Cheng LW, Mohd Ishak ZA, Abu Bakar A, Abd Rahman MA (2009) Water absorption study on pultruded jute fibre reinforced unsaturated polyester composites. Compos Sci Technol 69:1942–1948
Zhou Y, Yang X, Jia D (2007) Cure behavior of unsaturated polyester/modified montmorillonite nanocomposites. Polym Int 56:267–274
Xie W, Gao Z, Liu K, Pan WP, Vaia R, Hunter D, Singh A (2001) Thermal characterization of organically modified montmorillonite. Thermochim Acta 367–368:339–350
Rashmi Renukappa NM, Chikkakuntappa R, Kunigal NS (2011) Montmorillonite nanoclay filler effects on electrical conductivity, thermal and mechanical properties of epoxy-based nanocomposites. Polym Eng Sci 51:1827–1836
Park SJ, Seo DI, Lee JR (2002) Surface modification of montmorillonite on surface acid–base characteristics of clay and thermal stability of epoxy/clay nanocomposites. J Colloid Interface Sci 251:160–165
Khezri K, Haddadi-Asl V, Roghani-Mamaqani H, Salami-Kalajahi M (2011) Synthesis and characterization of exfoliated poly(styrene-co-methyl methacrylate) nanocomposite via miniemulsion atom transfer radical polymerization: an activators generated by electron transfer approach. Polym Compos 32:1979–1987
Lu H, Hu Y, Kong Q, Chen Z, Fan W (2005) Gamma irradiation of high density poly(ethylene)/ethylene-vinyl acetate/clay nanocomposites: possible mechanism of the influence of clay on irradiated nanocomposites. Polym Adv Technol 16:688–692
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Salehoon, E., Ahmadi, S.J., Razavi, S.M. et al. Thermal and corrosion resistance properties of unsaturated polyester/clay nanocomposites and the effect of electron beam irradiation. Polym. Bull. 74, 1629–1647 (2017). https://doi.org/10.1007/s00289-016-1793-1
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DOI: https://doi.org/10.1007/s00289-016-1793-1