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Synthesis of organosoluble and fluorescent aromatic polyketones bearing 1,1′-binaphthyl units through Suzuki–Miyaura coupling polymerization

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Abstract

Nanosized palladium cluster-catalyzed Suzuki–Miyaura coupling polymerization of 1,1′-binaphthyldiyl-bearing diiodides with expanded π-conjugated aromatic diboronic acid pinacol diesters affords aromatic polyketones, which have blue-emitting fluorescent properties (λ em 450–489 nm) in addition to high thermal stability (T g 190–297 °C) and excellent solubility in common organic solvents such as DMSO and NMP.

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Acknowledgments

This work was supported by the Joint Studies Programs (2011–2014) of the Institute for Molecular Science.

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Authors and Affiliations

  1. Department of Polymer Science and Engineering, Graduate School of Science and Engineering, Yamagata University, 4-3-16 Jonan, Yonezawa, Yamagata, 992-8510, Japan

    Katsuya Maeyama, Tadashi Tsukamoto & Hiroaki Kumagai

  2. Research Center of Integrative Molecular Systems, Institute for Molecular Science, Myodaiji, Okazaki, 444-8787, Japan

    Shuhei Higashibayashi

  3. Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565-0871, Japan

    Hidehiro Sakurai

Authors
  1. Katsuya Maeyama
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  2. Tadashi Tsukamoto
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  3. Hiroaki Kumagai
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  4. Shuhei Higashibayashi
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  5. Hidehiro Sakurai
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Correspondence to Katsuya Maeyama.

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Maeyama, K., Tsukamoto, T., Kumagai, H. et al. Synthesis of organosoluble and fluorescent aromatic polyketones bearing 1,1′-binaphthyl units through Suzuki–Miyaura coupling polymerization. Polym. Bull. 72, 2903–2916 (2015). https://doi.org/10.1007/s00289-015-1443-z

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  • DOI: https://doi.org/10.1007/s00289-015-1443-z

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