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Temperature distribution studies for light hydrocarbons (propane, n-butane, and iso-butane) adsorption on 5A molecular sieve zeolite

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Abstract

Concentration distribution represented by breakthrough curves for propane, n-butane, and iso-butane mixture on 5A molecular sieve zeolite were obtained experimentally at a constant temperature of 301 K. The temperature distribution curves were also studied. The effect of feed flow rate, feed pressure, and adsorbates composition on these breakthrough curves was examined. The spacing of the pressure waves of adsorbates (propane and n-butane) was enough to indicate that 5A molecular sieve zeolite could be used as a separating agent for these components.

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References

  1. Lee BC, Cho CH (1998) Adsorption equilibrai of light hydrocarbon–carbon dioxide mixtures on zeolite 5A using the two-dimensional equations of state. J Ind Eng Chem 4:298–307

    Google Scholar 

  2. Miano F (1996) Adsorption of hydrocarbon vapour mixtures onto zeolite 5A. Colloids Surf A 110(95):104

    Google Scholar 

  3. Ahmed MJ, Mohammed AHAK, Kadhum AAH (2011) Modeling of breakthrough curves for adsorption of propane, n-butane, and iso-butane mixture on 5A molecular sieve zeolite. Transp Porous Med 86:215–228

    Article  Google Scholar 

  4. Hu X, Do DD (1995) Comparing various multicomponent adsorption equilibrium models. AIChE J 41:1585–1592

    Article  Google Scholar 

  5. Do DD, Do HD (2000) Non-isothermal effects on adsorption kinetics of hydrocarbon mixtures in activated carbon. Sep Purif Technol 20:49–65

    Article  Google Scholar 

  6. Puértolas B, Navarro MV, Lopez JM, Murillo R, Mastral AM, Garcia T (2012) Modeling the heat and mass transfers of propane onto a ZSM-5 zeolite. Sep Purif Technol 86:127–136

    Article  Google Scholar 

  7. Grande CA, Gascon J, Kapteijn F, Rodrigues AE (2010) Propane/propylene separation with Li-exchanged zeolite 13X. Chem Eng J 160:207–214

    Article  Google Scholar 

  8. Plaza MG, Ribeiro AM, Ferreira A, Santos JC, Lee U-H, Chang J-S, Loureiro JM, Rodrigues AE (2012) Propylene/propane separation by vacuum swing adsorption using Cu-BTC spheres. Sep Purif Technol 90:109–119

    Article  Google Scholar 

  9. Granato MA, Jorge M, Vlugt TJH, Rodrigues AE (2010) Diffusion of propane, propylene and isobutene in 13X zeolite by molecular dynamics. Chem Eng Sci 65:2656–2663

    Article  Google Scholar 

  10. Grande CA, Cavenati S, Barcia P, Hammer J, Fritz HG, Rodrigues AE (2006) Adsorption of propane and propylene in zeolite 4A honeycomb monolith. Chem Eng Sci 61:3053–3067

    Article  Google Scholar 

  11. Guimaraes AP, Moller A, Staudt R, de Azevedo DCS, Lucena SMP, Cavalcante CL Jr (2010) Diffusion of linear paraffins in silicalite studied by the ZLC method in the presence of CO2. Adsorption 16:29–36

    Article  Google Scholar 

  12. Moller A, Guimaraes AP, Glaser R, Staudt R (2009) Uptake-curves for the determination of diffusion coefficients and sorption equilibria for n-alkanes on zeolites. Microporous Mesoporous Mater 125:23–29

    Article  Google Scholar 

  13. Prasetyo I, Do DD (1999) Adsorption kinetics of light paraffins in AC by a constant molar flow rate method. AIChE J 45:1892–1900

    Article  Google Scholar 

  14. Ruthven DM, Loughlin KF, Derrah RI (1973) Sorption and diffusion of light hydrocarbons and other simple nonpolar molecules in type 5A zeolites. Adv Chem 121:330–344

    Article  Google Scholar 

  15. Cooney DO (1991) The importance of axial dispersion in liquid-phase fixed-bed adsorption operations. Chem Eng Comm 110:217–231

    Article  Google Scholar 

  16. Arumngam BK, Banks JF, Wankat PC (1991) Pressure effects in adsorption system. Adsorption 5:261–278

    Article  Google Scholar 

  17. Hu X, Qiao S, Do DD (1999) Multi component adsorption kinetics of gases in activated carbon: effect of pore size distribution. Langmuir 15:6428–6437

    Article  Google Scholar 

Download references

Acknowledgments

We gratefully acknowledge the University of Baghdad and University Kebangsaan Malaysia for assist and support of this work.

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Correspondence to Muthanna J. Ahmed.

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Ahmed, M.J., Theydan, S.K. Temperature distribution studies for light hydrocarbons (propane, n-butane, and iso-butane) adsorption on 5A molecular sieve zeolite. Heat Mass Transfer 51, 33–38 (2015). https://doi.org/10.1007/s00231-014-1388-z

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  • DOI: https://doi.org/10.1007/s00231-014-1388-z

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