Abstract
This review provides information on spark plasma sintering (SPS) as a novel approach for polymer and polymer composite manufacturing. Over the years, the potential of this technique has been widely researched and attested for fabricating different metallic and ceramic-based composite without much emphasis on polymers. However, in recent times, this process has been employed to solving numerous challenges encountered while engaging the conventional polymer processing technique such as compression, injection moulding and extrusion in processing high viscous polymers and others. The numerous merit of this process, its mode of operation and applications are thoroughly explained in this review. It also evaluated the outstanding performance and unique properties obtained from the spark plasma-sintered polymer specimen when compared to the conventional polymer processing techniques. It was hence discovered that the thermoelectric properties, thermal conductivity, thermal stability, crystallinity, microstructural, mechanical and tribological properties of the polymer can be greatly enhanced through this process compared to other conventional means. This review will help polymer scientist, industrialist and engineers to properly understand and explore this alternative route in solving many material development challenges.
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16 June 2021
A Correction to this paper has been published: https://doi.org/10.1007/s00170-021-07458-9
References
Schwertz M, Ranque P, Lemonnier S, Barraud E, Carrado A, Vallat MF, Nardin M (2015) Optimization of the spark plasma sintering processing parameters affecting the properties of polyimide. J Appl Polym Sci 132(9)
Naskar AK, Edie DD (2006) Consolidation of reactive Ultem® powder-coated carbon fiber tow for space structure composites by resistive heating. J Compos Mater 40(20):1871–1883
Liaw DJ, Wang KL, Huang YC, Lee KR, Lai JY, Ha CS (2012) Advanced polyimide materials: syntheses, physical properties and applications. Prog Polym Sci 37(7):907–974
Sébileau JC, Lemonnier S, Barraud E, Vallat MF, Carradò A, Nardin M (2017) Consolidation by spark plasma sintering (SPS) of polyetheretherketone. J Appl Polym Sci 134(23):7
Tadmor Z, Gogos CG (2006) Principles of polymer processing. In: Tadmor Z, Gogos CG (eds) , vol 1, Chapter 1. Wiley, Hoboken, p 1
Ehrenstein GW, Montagne F (2000) Matériaux Polymères: structure, Propriétés et Applications. In: Ehrenstein GW, Montagne F (eds) , vol 1, Chapter 6. Hermès Science Publications, Paris, p 211
Cavaliere P (ed) (2019) Spark plasma sintering of materials: advances in processing and applications. Springer
Omori M (2000) Sintering, consolidation, reaction and crystal growth by the spark plasma system (SPS). Mater Sci Eng A 287(2):183–188
Munir ZA, Anselmi-Tamburini U, Ohyanagi M (2006) The effect of electric field and pressure on the synthesis and consolidation of materials: a review of the spark plasma sintering method. J Mater Sci 41:763–777
Suárez M, Fernández A, Menéndez JL, Torrecillas R, Kessel HU, Hennicke J, Kirchner R, Kessel T (2013) Challenges and opportunities for spark plasma sintering: a key technology for a new generation of materials. In: Sintering applications. IntechOpen 13:319–342
Matizamhuka WR (2016) Spark plasma sintering (SPS)-an advanced sintering technique for structural nanocomposite materials. J South Afr Inst Min Metall 116(12):1171–1180
Khalil KA (2012) "Advanced sintering of nano-ceramic materials." Ceramic Materials-Progress in Modern Ceramics 65–82
Sharma, N., Alam, S.N. and Ray, B.C., 2019. Fundamentals of spark plasma sintering (SPS): an ideal processing technique for fabrication of metal matrix. Spark Plasma Sintering of Materials: Advances in Processing and Applications, Cham 21–59
Guillon O, Gonzalez-Julian J, Dargatz B, Kessel T, Schierning G, Räthel J, Herrmann M (2014) Field-assisted sintering technology/spark plasma sintering: mechanisms, materials, and technology developments. Adv Eng Mater 16(7):830–849
Saheb N, Iqbal Z, Khalil A, Hakeem AS, Al Aqeeli N, Laoui T, Al-Qutub A, Kirchner R (2012) Spark plasma sintering of metals and metal matrix nanocomposites: a review. J Nanomater 2012:18
Chen G, Xu W, Zhu D (2017) Recent advances in organic polymer thermoelectric composites. J Mater Chem C 5(18):4350–4360
Yu C, Choi K, Yin L, Grunlan JC (2011) Light-weight flexible carbon nanotube based organic composites with large thermoelectric power factors. ACS Nano 5(10):7885–7892
Ge ZH, Chang Y, Li F, Luo J, Fan P (2018) Improved thermoelectric properties of PEDOT: PSS polymer bulk prepared using spark plasma sintering. Chem Commun 54(19):2429–2431
Wei K, Nolas GS (2018) Enhanced thermoelectric properties of polymer/inorganic bulk composites through EG treatment and spark plasma sintering processing. Scr Mater 150:70–73
Omori M, Okubo A, Hirai T (1998) Fabrication and thermal properties of polyimide/Cu functionally graded material. J Jpn Soc Powder Powder Metall 45(3):216–219
Adesina OT, Sadiku ER, Jamiru T, Ogunbiyi OF, Adesina OS (2020) Thermal properties of spark plasma-sintered polylactide/graphene composites. Mater Chem Phys 242:122545
Tanaka A, Umeda K, Yudasaka M, Suzuki M, Ohana T, Yumura M, Iijima S (2005) Friction and wear of carbon nanohorn-containing polyimide composites. Tribol Lett 19(2):135–142
Tanaka A, Umeda K, Takatsu S (2004) Friction and wear of diamond-containing polyimide composites in water and air. Wear 257(11):1096–1102
Schwertz M, Lemonnier S, Barraud E, Carradò A, Vallat MF, Nardin M (2015) Spark plasma sintering technology applied to polymer-based composites for structural light weighting. Powder Metall 58(2):87–90
Bonnefont G, Mdarhri A, Lahlali H, El Aboudi I, El Haouzi F, El Azhari M, Lame O, Fabregue D (2015) The spark plasma sintering (sps) as a high rapid and eficient method to elaborete dense materials: application for high viscous polymer. Verres Céramiques Composites 4(2):5–8
Adesina OT, Sadiku ER, Jamiru T, Ogunbiyi OF, Beneke LW, Adegbola AT (2019) Optimization of SPS processing parameters on the density and hardness properties of graphene reinforced polylactic acid nanocomposite. Int J Adv Manuf Technol 102(9-12):4047–4058
Schwertz M, Lemonnier S, Barraud E, Carradò A, Vallat MF, Nardin M (2014) Consolidation by spark plasma sintering of polyimide and polyetheretherketone. J Appl Polym Sci 131(18)
Bao RY, Yang W, Wei XF, Xie BH, Yang MB (2014) Enhanced formation of stereocomplex crystallites of high molecular weight poly (l-lactide)/poly (d-lactide) blends from melt by using poly (ethylene glycol). ACS Sustain Chem Eng 2(10):2301–2309
Sun Y, He C (2012) Synthesis and stereocomplex crystallization of poly (lactide)−graphene oxide nanocomposites. ACS Macro Lett 709–713
Sun Y, He C (2013) Synthesis, stereocomplex crystallization, morphology and mechanical property of poly (lactide)-carbon nanotube nanocomposites. RSC Adv 3(7):2219–2226
Tsuji H (2003) In vitro hydrolysis of blends from enantiomeric poly (lactide)s. Part 4: Well-homo-crystallized blend and nonblended films. Biomaterials 24(4):537–547
Taubner V, Shishoo R (2001) Influence of processing parameters on the degradation of poly(l-lactide) during extrusion. J Appl Polym Sci 79:2128–2135
Bai D, Liu H, Bai H, Zhang Q, Fu Q (2016) Powder metallurgy inspired low-temperature fabrication of high-performance stereocomplexed polylactide products with good optical transparency. Sci Rep 6:20260
Adesina OT, Sadiku ER, Jamiru T, Adesina OS, Ogunbiyi OF, Obadele BA, Salifu S (2020) Polylactic acid/graphene nanocomposite consolidated by SPS technique. J Mater Res Technol 9(5):11801–11812
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This work is supported by Tshwane University of Technology, Pretoria, South Africa.
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Adesina Oluwagbenga Tobi contributed significantly in performing the analyses and writing the manuscript. Adesina Olanrewaju Seun and Ogunbiyi Olugbenga helped perform the analysis with constructive discussions. Sadiku Emmanuel Rotimi and Jamiru Tamba helped in revising the paper. Babatunde Abiodun Obadele contributed in attending to reviewers’ comments and final proofreading of the review manuscript.
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Adesina, O.T., Sadiku, E.R., Adesina, O.S. et al. Spark plasma sintering of polymer and polymer-based composites: a review. Int J Adv Manuf Technol 116, 759–775 (2021). https://doi.org/10.1007/s00170-021-07349-z
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DOI: https://doi.org/10.1007/s00170-021-07349-z