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Nanocutting mechanism of 6H-SiC investigated by scanning electron microscope online observation and stress-assisted and ion implant-assisted approaches

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Abstract

Nanocutting mechanism of single crystal 6H-SiC is investigated through a novel scanning electron microscope setup in this paper. Various undeformed chip thicknesses on (0001) < 1–100 > orientation are adopted in the nanocutting experiments. Phase transformation and dislocation activities involved in the 6H-SiC nanocutting process are also characterized and analyzed. Two methods of stress-assisted and ion implant-assisted nanocutting are studied to improve 6H-SiC ductile machining ability. Results show that stress-assisted method can effectively decrease the hydrostatic stress and help to activate dislocation motion and ductile machining; ion implant-induced damages are helpful to improve the ductile machining ability from MD simulation and continuous nanocutting experiments under the online observation platform.

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Abbreviations

SiC:

silicon carbide

SEM:

scanning electron microscope

EBSD:

electron backscatter diffraction

FIB:

focused ion beam

ABOP:

analytical bond order potential

DXA:

dislocation extraction algorithm

SRIM:

Stopping and Range of Ions in Matter

MD:

molecular dynamics

References

  1. Khuat V, Ma Y, Si J, Chen T, Chen F, Hou X (2014) Fabrication of through holes in silicon carbide using femtosecond laser irradiation and acid etching. Appl Surf Sci 289:529–532

    Google Scholar 

  2. Zhang Z, Cui J, Wang B, Jiang H, Chen G, Yu J (2018) In situ TEM observation of rebonding on fractured silicon carbide. Nanoscale 10:6261–6769

    Google Scholar 

  3. Cui J, Zhang Z, Jiang H, Jiang H, Zou L, Guo X, Yao L, Ivan PP, Guo D (2019b) Ultrahigh recovery of fracture strength on mismatched fractured amorphous surfaces of silicon carbide. ACS Nano 13:7483–7492

    Google Scholar 

  4. Mélinon P, Masenelli B, Tournus F, Perez A (2007) Playing with carbon and silicon at the nanoscale. Nat Mater 6:479–490

    Google Scholar 

  5. Guo X, Li Q, Liu T, Kang R, Jin Z, Guo D (2017) Advances in molecular dynamics simulation of ultra-precision machining of hard and brittle materials. Front Mech Eng 12:89–98

    Google Scholar 

  6. Eker S, Durandurdu M (2009) Pressure-induced phase transformation of 4H-SiC: an ab initio constant-pressure study. Europhys Lett 87:36001

    Google Scholar 

  7. Loan PRV (1967) A study of polytypism in silicon carbide. The American Mineralogist 52:946–956

    Google Scholar 

  8. Fang FZ, VenkateshV C (1998) Diamond cutting of silicon with nanometric finish. CIRP Annals-Manufacturing Technology 47:45–49

    Google Scholar 

  9. Fang F. Z., Wu H., Zhou W., Hu X. T (2007) A study on mechanism of nano-cutting single crystal silicon. J Mater Process Technol 184:407–410

    Google Scholar 

  10. Lai M, Zhang X, Fang F, Wang Y, Feng M (2013) Study on nanometric cutting of germanium by molecular dynamics simulation. Nanoscale Res Lett 8:13

    Google Scholar 

  11. Fang F, Xu F, Lai M (2015) Size effect in material removal by cutting at nano scale. Int J Adv Manuf Technol 80:591–598

    Google Scholar 

  12. Li Z, Zhang X (2017) Subsurface deformation of germanium in ultra-precision cutting: characterization of micro-Raman spectroscopy. Int J Adv Manuf Technol 91(1–4):213–225

    Google Scholar 

  13. Zhang ZY, Huo YX, Guo DM (2013) A model for nanogrinding based on direct evidence of ground chips of silicon wafers. Science China-Technological Sciences 56(9):2099–2108

    Google Scholar 

  14. Zhang Z, Song Y, Xu C, Guo D (2012) A novel model for undeformed nanometer chips of soft-brittle HgCdTe films induced by ultrafine diamond grits. Scr Mater 67(2):197–200

    Google Scholar 

  15. Zhang Z, Huo F, Zhang X, Guo D (2012) Fabrication and size prediction of crystalline nanoparticles of silicon induced by nanogrinding with ultrafine diamond grits. Scr Mater 67(7–8):657–660

    Google Scholar 

  16. Zhang Z, Wang B, Kang R, Zhang B, Guo D (2015) Changes in surface layer of silicon wafers from diamond scratching. CIRP Ann 64:349–352

    Google Scholar 

  17. Zhang Z, Guo D, Wang B, Kang R, Zhang B (2015) A novel approach of high speed scratching on silicon wafers at nanoscale depths of cut. Sci Rep 5:16395

    Google Scholar 

  18. Wang B, Zhang Z, Chang K, Cui J, Rosenkranz A, Yu J, Guo D (2018) New deformation-induced nanostructure in silicon. Nano Lett 18:4611–4617

    Google Scholar 

  19. Zhang Z, Du Y, Wang B, Wang Z, Kang R, Guo D (2017) Nanoscale wear layers on silicon wafers induced by mechanical chemical grinding. Tribol Lett 65:132

    Google Scholar 

  20. Zhang Z, Cui J, Wang B, Wang Z, Kang R, Guo D (2017) A novel approach of mechanical chemical grinding. J Alloys Compd 72:6514–6524

    Google Scholar 

  21. Patten J, Gao W, Yasuto K (2005) Ductile regime nanomachining of single-crystal silicon carbide. J Manuf Sci Eng 127:522–532

    Google Scholar 

  22. Wu ZH, Liu WD, Zhang LC (2017) Revealing the deformation mechanisms of 6H-silicon carbide under nano-cutting. Comput Mater Sci 137:282–288

    Google Scholar 

  23. Meng BB, Zhang Y, Zhang FH (2016) Material removal mechanism of 6H-SiC studied by nanoscratching with Berkovich indenter. Applied Physics A 122:247

    Google Scholar 

  24. Zhang F, Meng B, Geng Y, Zhang Y (2016) Study on the machined depth when nanoscratching on 6H-SiC using Berkovich indenter: Modelling and experimental study. Appl Surf Sci 368:449–455

    Google Scholar 

  25. Li Z, Zhang F, Luo X (2018) Subsurface damages beneath fracture pits of reaction-bonded silicon carbide after ultra-precision grinding. Appl Surf Sci 448:341–350

    Google Scholar 

  26. Goel S, Luo XC, Comley P, Reuben RL, Cox A (2013) Brittle-ductile transition during diamond turning of single crystal silicon carbide. Int J Mach Tool Manu 65:15–21

    Google Scholar 

  27. Xiao GB, To S, Zhang GQ (2015) The mechanism of ductile deformation in ductile regime machining of 6H SiC. Comput Mater Sci 98:178–188

    Google Scholar 

  28. Xiao G, To, S, Zhang G (2015) A study of chip formation in ductile-regime machining of 6H silicon carbide by molecular dynamics. International Journal of Nanomanufacturing 11:64–77

    Google Scholar 

  29. Goel, S., Luo, X., Reuben, R. L., & Rashid, W. B (2011) Atomistic aspects of ductile responses of cubic silicon carbide during nanometric cutting. Nanoscale Res Lett 6:589

  30. Gao B, Zhai W, Zhai Q, Zhang M (2019) Novel polystyrene/CeO2-TiO2 multicomponent core/shell abrasives for high-efficiency and high-quality photocatalytic-assisted chemical mechanical polishing of reaction-bonded silicon carbide. Appl Surf Sci 484:534–541

    Google Scholar 

  31. Fang FZ, Chen YH, Zhang XD, Hu XT, Zhang GX (2011) Nanometric cutting of single crystal silicon surfaces modified by ion implantation. CIRP Annals-Manufacturing Technology 60:527–530

    Google Scholar 

  32. Zhou Z, Guo D (1987) Pre-stressed machining: combined use of heuristics and optimization methods. Proceedings of IX the ICPR 11:257–262

    Google Scholar 

  33. Fang FZ, Liu B, Xu ZW (2015) Nanometric cutting in a scanning electron microscope. Precis Eng 41:145–152

    Google Scholar 

  34. Bing L, Fengzhou F, Rui L, Zongwei X, Yanshu L (2018) Experimental study on size effect of tool edge and subsurface damage of single crystal silicon in nano-cutting. Int J Adv Manuf Technol 98:1093–1101

    Google Scholar 

  35. Tupitsyn EY, Arulchakkaravarthi A, Drachev RV, Sudarshan TS (2007) Controllable 6h-sic to 4h-sic polytype transformation during pvt growth. J Cryst Growth 299:70–76

    Google Scholar 

  36. Nakashima S, Harima H (2004) Characterization of defects in SiC crystals by Raman scattering. Springer Berlin Heidelberg 585–605

    Google Scholar 

  37. Nakashima S, Nakatake Y, Harima H, Katsuno M (2000) Detection of stacking faults in 6H-SiC by Raman scattering. Applied Physics Letter 77:3612–3614

    Google Scholar 

  38. Xu ZW, He ZD, Song Y, Xiu F, Mathias R, Xichun L (2018) Topic review: application of Raman spectroscopy characterization in micro/nano-machining. Micromachines 9:361

    Google Scholar 

  39. Niihara K (1979) Slip systems and plastic deformation of silicon carbide single crystals at high temperatures. Journal of the Less Common Metals 65:155–166

    Google Scholar 

  40. Fujita S, Maeda K, Hyodo S (2016) Dislocation glide motion in 6H SiC single crystals subjected to high-temperature deformation. Philosophical Magazine A 55:203–215

    Google Scholar 

  41. Plimpton S (1995) Fast parallel algorithms for short-range molecular dynamics. J Comput Phys 117:1–19

    MATH  Google Scholar 

  42. Erhart P, Albe K (2005) Analytical potential for atomistic simulations of silicon, carbon, and silicon carbide. Phys Rev B 71:035211

    Google Scholar 

  43. Goel S, Stukowski A, Luo X, Agrawal A, Reuben R (2013) Anisotropy of single-crystal 3C-SiC during nanometric cutting. Model Simul Mater Sci Eng 21:065004

    Google Scholar 

  44. Fang FZ, Xu F (2018) Recent advances in micro/nano-cutting: effect of tool edge. Nanomanufacturing and Metrology 1:4–31

    Google Scholar 

  45. Yoshida M, Akifumi O, Masaki U, Kenichi T, Osamu S (1993) Pressure-induced phase transition in SiC. Phys Rev B 48:10587

    Google Scholar 

  46. Devanathan R, Rubia TDDL, Weber WJ (1998) Displacement threshold energies in β-SiC. J Nucl Mater 253:47–52

    Google Scholar 

  47. Fu X, Xu ZW, He ZD, Hartmaier A, Fang FZ (2018) Molecular dynamics simulation of silicon ion implantation into diamond and subsequent annealing. Nuclear Instruments & Methods in Physics Research In press

  48. Xie W, Fang F (2019) Cutting-based single atomic layer removal mechanism of monocrystalline copper: atomic sizing effect. Int J Adv Manuf Technol 1:12

    Google Scholar 

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Acknowledgements

The authors thank Dr. B. Liu, Dr. H.S. Jiao, and Prof. C. Wang for valuable discussions.

Funding

The study is supported by the National Natural Science Foundation of China (No. 51575389, 51761135106), National Key Research and Development Program of China (2016YFB1102203), State Key Laboratory of Precision Measuring Technology and Instruments (Pilt1705), and the “111” Project by the State Administration of Foreign Experts Affairs and the Ministry of Education of China (Grant No. B07014).

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Correspondence to Zongwei Xu.

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Xu, Z., Liu, L., He, Z. et al. Nanocutting mechanism of 6H-SiC investigated by scanning electron microscope online observation and stress-assisted and ion implant-assisted approaches. Int J Adv Manuf Technol 106, 3869–3880 (2020). https://doi.org/10.1007/s00170-019-04886-6

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