Skip to main content
Log in

Measurements and Distribution of Atmospheric Particulate-Bound Mercury: A Review

  • Focused Review
  • Published:
Bulletin of Environmental Contamination and Toxicology Aims and scope Submit manuscript

A Correction to this article was published on 05 July 2019

This article has been updated

Abstract

Atmospheric particulate-bound mercury (PBM) plays an important role in the geochemical cycling of mercury (Hg). This study reviewed research progress of the PBM, including the possible emission and deposition pathways, measurement methods and the global distribution. The primary PBM sources are anthropogenic sources, but natural sources could be also a considerable contributor, for instance, chemical transport and dust in the arid and desert area. Different filter methods, such as quartz fibre filters, have been applied to the PBM measurement, and PBM can also be real-time monitored automatically. Generally, the average PBM concentrations were higher in the Northern Hemisphere than in the Southern Hemisphere. However, the PBM level of Antarctica is quite high. PBM concentrations were higher in the urban areas than in the remote areas, and there was a high PBM level in the developing countries. Moreover, high PBM concentrations were observed in the range 20°–60° of northern latitude.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

Change history

  • 05 July 2019

    The original version of this article unfortunately contained a mistake in units.

References

  • AMAP/UNEP (2013) Technical background report for the Global Mercury Assessment 2013, Arctic Monitoring and Assessment Programme, Oslo. Norway. UNEP Chemicals Branch, Geneva, pp 1–263

    Google Scholar 

  • Arimoto R, Schloesslin C, Davis D, Hogan A, Grube P, Fitzgerald W, Lamborg C (2004) Lead and mercury in aerosol particles collected over the South Pole during ISCAT-2000. Atmos Environ 38(32):5485–5491

    Article  CAS  Google Scholar 

  • Ariya PA, Amyot M, Dastoor A, Deeds D, Feinberg A, Kos G, Poulain A, Ryjkov A, Semeniuk K, Subir M, Toyota K (2015) Mercury physicochemical and biogeochemical transformation in the atmosphere and at atmospheric interfaces: a review and future directions. Chem Rev 115(10):3760–3802

    Article  CAS  Google Scholar 

  • Carpi A (1997) Mercury from combustion sources: a review of the chemical species emitted and their transport in the atmosphere. Water Air Soil Pollut 98(3–4):241–254

    CAS  Google Scholar 

  • Chand D, Jaffe D, Prestbo E, Swartzendruber PC, Hafner W, Weiss-Penzias P, Kato S, Takami A, Hatakeyama S, Kajii YZ (2008) Reactive and particulate mercury in the Asian marine boundary layer. Atmos Environ 42(34):7988–7996

    Article  CAS  Google Scholar 

  • De Simone F, Artaxo P, Bencardino M, Cinnirella S, Carbone F, D'Amore F, Dommergue A, Xin XB, Gencarelli CN, Hedgecock IM, Landis MS, Sprovieri F, Suzuki N, Wangberg I, Pirrone N (2017) Particulate-phase mercury emissions from biomass burning and impact on resulting deposition: a modelling assessment. Atmos Chem Phys 17(3):1881–1899

    Article  CAS  Google Scholar 

  • Fang GC, Yang IL, Liu CK (2010) Estimation of atmospheric particulates and dry deposition particulate-bound mercury Hg(p) in Sha-Lu, Taiwan. Aerosol Air Qual Res 10(5):403–413

    Article  CAS  Google Scholar 

  • Fang GC, Tsai JH, Lin YH, Chang CY (2012a) Dry deposition of atmospheric particle-bound mercury in the middle Taiwan. Aerosol Air Qual Res 12(6):1298–1308

    Article  CAS  Google Scholar 

  • Fang GC, Zhang L, Huang CS (2012b) Measurements of size-fractionated concentration and bulk dry deposition of atmospheric particulate bound mercury. Atmos Environ 61:371–377

    Article  CAS  Google Scholar 

  • Fu XW, Feng XB, Sommar J, Wang SF (2012) A review of studies on atmospheric mercury in China. Sci Total Environ 421:73–81

    Article  CAS  Google Scholar 

  • Fu XW, Zhang H, Yu B, Wang X, Lin CJ, Feng XB (2015) Observations of atmospheric mercury in China: a critical review. Atmos Chem Phys 15(16):9455–9476

    Article  CAS  Google Scholar 

  • Fu XW, Yang X, Lang XF, Zhou J, Zhang H, Yu B, Yan HY, Lin CJ, Feng XB (2016) Atmospheric wet and litterfall mercury deposition at urban and rural sites in China. Atmos Chem Phys 16(18):11547–11562

    Article  CAS  Google Scholar 

  • Fu XW, Zhang H, Feng XB, Tan QY, Ming LL, Liu C, Zhang LM (2019) Domestic and transboundary sources of atmospheric particulate bound mercury in remote areas of China: evidence from mercury isotopes. Environ Sci Technol 53(4):1947–1957

    Article  CAS  Google Scholar 

  • Hong QQ, Xie ZQ, Liu C, Wang FY, Xie PH, Kang H, Xu J, Wang JC, Wu FC, He PZ, Mou FS, Fan SD, Dong YS, Zhan HC, Yu XW, Chi XY, Liu JG (2016) Speciated atmospheric mercury on haze and non-haze days in an inland city in China. Atmos Chem Phys 16(21):13807–13821

    Article  CAS  Google Scholar 

  • Huang Q, Chen JB, Huang WL, Reinfelder JR, Fu PQ, Yuan SL, Wang ZW, Yuan W, Cai HM, Ren H, Sun YL, He L (2019) Diel variation in mercury stable isotope ratios records photoreduction of PM2.5-bound mercury. Atmos Chem Phys 19(1):315–325

    Article  CAS  Google Scholar 

  • Kim PR, Han YJ, Holsen TM, Yi SM (2012) Atmospheric particulate mercury: concentrations and size distributions. Atmos Environ 61:94–102

    Article  CAS  Google Scholar 

  • Li S, Cheng CM, Chen B, Cao Y, Vervynckt J, Adebambo A, Pan WP (2007) Investigation of the relationship between particulate-bound mercury and properties of fly ash in a full-scale 100 MWe pulverized coal combustion boiler. Energy Fuels 21(6):3292–3299

    Article  CAS  Google Scholar 

  • Lin CJ, Pehkonen SO (1999) The chemistry of atmospheric mercury: a review. Atmos Environ 33(13):2067–2079

    Article  CAS  Google Scholar 

  • Lindberg SE, Stratton WJ (1998) Atmospheric mercury speciation: concentrations and behavior of reactive gaseous mercury in ambient air. Environ Sci Technol 32:49–57

    Article  CAS  Google Scholar 

  • Lu JY, Schroeder WH (1999) Sampling and determination of particulate mercury in ambient air: a review. Water Air Soil Pollut 112(3–4):279–295

    Article  CAS  Google Scholar 

  • Morel FMM, Kraepiel AML, Amyot M (1998) The chemical cycle and bioaccumulation of mercury. Annu Rev Ecol Syst 29:543–566

    Article  Google Scholar 

  • Munthe J, Wangberg I, Pirrone N, Iverfeldt A, Ferrara R, Ebinghaus R, Feng X, Gardfeldt K, Keeler G, Lanzillotta E, Lindberg SE, Lu J, Mamane Y, Prestbo E, Schmolke S, Schroeder WH, Sommar J, Sprovieri F, Stevens RK, Stratton W, Tuncel G, Urba A (2001) Intercomparison of methods for sampling and analysis of atmospheric mercury species. Atmos Environ 35(17):3007–3017

    Article  CAS  Google Scholar 

  • Murphy DM, Thomson DS, Mahoney TMJ (1998) In situ measurements of organics, meteoritic material, mercury, and other elements in aerosols at 5 to 19 kilometers. Science 282(5394):1664–1669

    Article  CAS  Google Scholar 

  • Obrist D, Moosmuller H, Schurmann R, Chen LWA, Kreidenweis SM (2008) Particulate-phase and gaseous elemental mercury emissions during biomass combustion: controlling factors and correlation with particulate matter emissions. Environ Sci Technol 42(3):721–727

    Article  CAS  Google Scholar 

  • Pfaffhuber KA, Berg T, Hirdman D, Stohl A (2012) Atmospheric mercury observations from Antarctica: seasonal variation and source and sink region calculations. Atmos Chem Phys 12(7):3241–3251

    Article  CAS  Google Scholar 

  • Pirrone N, Cinnirella S, Feng X, Finkelman RB, Friedli HR, Leaner J, Mason R, Mukherjee AB, Stracher GB, Streets DG, Telmer K (2010) Global mercury emissions to the atmosphere from anthropogenic and natural sources. Atmos Chem Phys 10(13):5951–5964

    Article  CAS  Google Scholar 

  • Qie GH, Wang Y, Wu C, Mao HT, Zhang P, Li T, Li YX, Talbot R, Hou CX, Yue TX (2018) Distribution and sources of particulate mercury and other trace elements in PM2.5 and PM10 atop Mount Tai, China. J Environ Manag 215:195–205

    Article  CAS  Google Scholar 

  • Rothenberg SE, Mckee L, Gilbreath A, Yee D, Connor M, Fu XW (2010) Evidence for short-range transport of atmospheric mercury to a rural, inland site. Atmos Environ 44(10):1263–1273

    Article  CAS  Google Scholar 

  • Sakata M, Asakura K (2007) Estimating contribution of precipitation scavenging of atmospheric particulate mercury to mercury wet deposition in Japan. Atmos Environ 41(8):1669–1680

    Article  CAS  Google Scholar 

  • Sprovieri F, Pirrone N, Hedgecock IM, Landis MS, Stevens RK (2002) Intensive atmospheric mercury measurements at Terra Nova Bay in Antarctica during November and December 2000. J Geophys Res Atmos 107(D23):4722

    Article  CAS  Google Scholar 

  • Sprovieri F, Pirrone N, Bencardino M, D'Amore F, Carbone F, Cinnirella S, Mannarino V, Landis M, Ebinghaus R, Weigelt A, Brunke EG, Labuschagne C, Martin L, Munthe J, Wangberg I, Artaxo P, Morais F, Barbosa HDJ, Brito J, Cairns W, Barbante C, Dieguez MD, Garcia PE, Dommergue A, Angot H, Magand O, Skov H, Horvat M, Kotnik J, Read KA, Neves LM, Gawlik BM, Sena F, Mashyanov N, Obolkin V, Wip D, Bin Feng X, Zhang H, Fu XW, Ramachandran R, Cossa D, Knoery J, Marusczak N, Nerentorp M, Norstrom C (2016) Atmospheric mercury concentrations observed at ground-based monitoring sites globally distributed in the framework of the GMOS network. Atmos Chem Phys 16(18):11915–11935

    Article  CAS  Google Scholar 

  • Wang ZW, Zhang XS, Chen ZS, Zhang Y (2006) Mercury concentrations in size-fractionated airborne particles at urban and suburban sites in Beijing, China. Atmos Environ 40(12):2194–2201

    Article  CAS  Google Scholar 

  • Wang SX, Zhang L, Li GH, Wu Y, Hao JM, Pirrone N, Sprovieri F, Ancora MP (2010) Mercury emission and speciation of coal-fired power plants in China. Atmos Chem Phys 10(3):1183–1192

    Article  CAS  Google Scholar 

  • Wang X, Zhang H, Lin CJ, Fu XW, Zhang YP, Feng XB (2015) Transboundary transport and deposition of Hg emission from springtime biomass burning in the Indo-China Peninsula. J Geophys Res Atmos 120(18):9758–9771

    Article  CAS  Google Scholar 

  • Wang X, Lin CJ, Yuan W, Sommar J, Zhu W, Feng XB (2016) Emission-dominated gas exchange of elemental mercury vapor over natural surfaces in China. Atmos Chem Phys 16(17):11125–11143

    Article  CAS  Google Scholar 

  • Xiao ZF, Munthe J, Lindqvist O (1991) Sampling and Determination of gaseous and particulate mercury in the atmosphere using gold-coated denuders. Water Air Soil Pollut 56:141–151

    Article  CAS  Google Scholar 

  • Xiu GL, Cai J, Zhang WY, Zhang DN, Bueler A, Lee SC, Shen Y, Xu LH, Huang XJ, Zhang P (2009) Speciated mercury in size-fractionated particles in Shanghai ambient air. Atmos Environ 43(19):3145–3154

    Article  CAS  Google Scholar 

  • Zhang H, Fu XW, Lin CJ, Wang X, Feng XB (2015a) Observation and analysis of speciated atmospheric mercury in Shangri-La, Tibetan Plateau, China. Atmos Chem Phys 15(2):653–665

    Article  CAS  Google Scholar 

  • Zhang L, Wang SX, Wang L, Wu Y, Duan L, Wu QR, Wang FY, Yang M, Yang H, Hao JM, Liu X (2015b) Updated emission inventories for speciated atmospheric mercury from anthropogenic sources in China. Environ Sci Technol 49(5):3185–3194

    Article  CAS  Google Scholar 

  • Zhang LM, Wu ZY, Cheng I, Wright LP, Olson ML, Gay DA, Risch MR, Brooks S, Castro MS, Conley GD, Edgerton ES, Holsen TM, Luke W, Tordon R, Weiss-Penzias P (2016) The estimated six-year mercury dry deposition across North America. Environ Sci Technol 50(23):12864–12873

    Article  CAS  Google Scholar 

  • Zhu J, Wang T, Talbot R, Mao H, Yang X, Fu C, Sun J, Zhuang B, Li S, Han Y, Xie M (2014) Characteristics of atmospheric mercury deposition and size-fractionated particulate mercury in urban Nanjing, China. Atmos Chem Phys 14(5):2233–2244

    Article  CAS  Google Scholar 

  • Zikang Cui ZL, Zhang Y, Wang X, Li Q, Zhang L, Feng X, Li X, Shang L, Yao Z (2019) Atmospheric mercury emissions from residential coal combustion in Guizhou Province, Southwest China. Energy Fuels 33(3):1937–1943

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was funded by the National Natural Science Foundation of China (41703134) and the National Key R&D Program of China (2017YFC0212001).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Hui Zhang.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary file1 (DOCX 614 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhang, H., Fu, X., Wang, X. et al. Measurements and Distribution of Atmospheric Particulate-Bound Mercury: A Review. Bull Environ Contam Toxicol 103, 48–54 (2019). https://doi.org/10.1007/s00128-019-02663-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00128-019-02663-5

Keywords

Navigation