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Mercury Fractionation in Superficial Sediment and Paddy Soil Samples from Tianjin, Northern China

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Abstract

Sediment and soil samples from the Beitang River (BR) and the Haihe River (HR) in Tianjin were analyzed to investigate the extent of mercury contamination. The results show that total mercury (THg) contents in the BR and HR sediments were 2241 ± 1024 and 653 ± 450 ng g−1, and THg in rice paddy soils were 907 ± 345 and 328 ± 286 ng g−1, respectively. Industrial and domestic sewage were regarded as the main sources of mercury in the two river basins. Sediment-bound mercury in the BR and the HR were found to be predominantly associated with the organic-bound fraction (55 %) and residual fraction and (54 %), while soil-bound mercury was mainly in organic-bound fraction in paddy soils (61 % and 57 %, respectively). The availability of this element (soluble and exchangeable and specifically sorbed fraction) seemed restricted, but significantly higher in the paddy soils than in sediments. Higher soluble and exchangeable, specifically sorbed fraction and organic-bound fraction may promote the higher toxic methylmercury and bioavailable fraction formation in the soils during the rice cultivation.

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Acknowledgments

This research was financially supported by special funds for environmental protection industry research for public welfare program of China’s Ministry of Environmental Protection (No. 201309004).

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Authors and Affiliations

  1. Institute of Hydrogeology and Environmental Geology, Chinese Academy of Geological Sciences, No. 268 Zhonghua Street, Shijiazhuang, 050061, Hebei, China

    Chao Wu, Zhaoji Zhang, Yuhong Fei, Guoqing Wu & Yong Qian

  2. Hebei Key Laboratory of Groundwater Remediation, Shijiazhuang, 050061, Hebei, China

    Chao Wu, Yuhong Fei, Guoqing Wu & Yong Qian

Authors
  1. Chao Wu
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  2. Zhaoji Zhang
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  3. Yuhong Fei
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  4. Guoqing Wu
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  5. Yong Qian
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Correspondence to Zhaoji Zhang.

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Wu, C., Zhang, Z., Fei, Y. et al. Mercury Fractionation in Superficial Sediment and Paddy Soil Samples from Tianjin, Northern China. Bull Environ Contam Toxicol 97, 225–231 (2016). https://doi.org/10.1007/s00128-016-1847-y

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  • DOI: https://doi.org/10.1007/s00128-016-1847-y

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