Abstract
Post-collisional porphyry Cu deposits are genetically related to the magmas generated by partial melting of sulfide-bearing lithosphere fertilized by subduction components. The ore-forming magmas are suggested to be enriched in chalcophile elements compared to the barren magmas. However, the chalcophile element contents in the post-collisional magmas and its role in controlling the porphyry ore formation remain unclear. Platinum-group element (PGE) geochemistry has been used as a proxy for Cu and Au. In this study, we report PGE concentrations of representative post-collisional ore-associated and barren suites in the eastern Tethyan metallogenic domain. The ore-associated suites have moderate Pd and Pt contents ranging from ~ 0.05 to 0.5 ppb, which are comparable to those associated with giant porphyry systems in continental arc settings. In contrast, most of the barren suites have systematically lower Pd and Pt concentrations below ~ 0.1 and 0.05 ppb, respectively. Numerical models show that the ore-forming magmas, derived from partial melting of subduction-modified lithospheric mantle, have precipitated a small amount of sulfide phases during magma differentiation, leading to the moderate depletion of Pd and Pt in the ore-associated suites. Although the sulfide segregation has depleted highly chalcophile element contents, the ore-forming magmas contain sufficient Cu to form porphyry Cu deposits. This contrasts with the barren suites, which mainly originated from partial melting of the lower crust and contain about five times lower Cu contents, unfavorable for porphyry Cu mineralization. We suggest that moderate chalcophile element contents in the ore-associated magmas have increased the porphyry ore-forming potential in the eastern Tethyan domain.
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References
Bao X, Yang L, He W, Gao X (2018) Importance of magmatic water content and oxidation state for porphyry-style Au mineralization: An example from the giant Beiya Au deposit, SW China. Minerals 8:441. https://doi.org/10.3390/min8100441
Bao X, He W, Mao J, Liang T, Wang H, Zhou Y, Wang J (2023) Redox states and genesis of Cu-and Au-mineralized granite porphyries in the Jinshajiang Cu–Au metallogenic belt, SW China: studies on the zircon chemistry. Miner Deposita 58:1123–1142. https://doi.org/10.1007/s00126-023-01168-w
Barber ND, Edmonds M, Jenner F, Audétat A, Williams H (2021) Amphibole control on copper systematics in arcs: Insights from the analysis of global datasets. Geochim Cosmochim Acta 307:192–211. https://doi.org/10.1016/j.gca.2021.05.034
Chang J, Audétat A (2018) Petrogenesis and metal content of hornblende-rich xenoliths from two Laramide-age magma systems in southwestern USA: insights into the metal budget of arc magmas. J Petrol 59:1869–1898. https://doi.org/10.1093/petrology/egy083
Chang J, Audétat A (2023a) Post-subduction porphyry Cu magmas in the Sanjiang region of southwestern China formed by fractionation of lithospheric mantle–derived mafic magmas. Geology 51:64–68. https://doi.org/10.1130/G50502.1
Chang J, Audétat A (2023b) Experimental equilibrium and fractional crystallization of a H2O, CO2, Cl and S-bearing potassic mafic magma at 1.0 GPa, with implications for the origin of porphyry Cu (Au, Mo)-forming potassic magmas. J Petrol 64:egad034. https://doi.org/10.1093/petrology/egad034
Chelle-Michou C, Rottier B, Caricchi L, Simpson G (2017) Tempo of magma degassing and the genesis of porphyry copper deposits. Sci Rep 7:1–12. https://doi.org/10.1038/srep40566
Chen L, Qin K, Li G, Li J, Xiao B, Zhao J (2020) In situ major and trace elements of garnet and scheelite in the Nuri Cu–W–Mo deposit, South Gangdese, Tibet: Implications for mineral genesis and ore-forming fluid records. Ore Geol Rev 122:103549. https://doi.org/10.1016/j.oregeorev.2020.103549
Chiaradia M, Caricchi L (2017) Stochastic modelling of deep magmatic controls on porphyry copper deposit endowment. Sci Rep 7:1–11. https://doi.org/10.1038/srep44523
Cocker HA, Valente DL, Park J-W, Campbell IH (2015) Using platinum group elements to identify sulfide saturation in a porphyry Cu system: the El Abra porphyry Cu deposit, Northern Chile. J Petrol 56:2491–2514. https://doi.org/10.1093/petrology/egv076
Du J, Audétat A (2020) Early sulfide saturation is not detrimental to porphyry Cu-Au formation. Geology 48:519–524. https://doi.org/10.1130/G47169.1
Gan T, Huang Z (2017) Platinum-group element and Re-Os geochemistry of lamprophyres in the Zhenyuan gold deposit, Yunnan Province, China: implications for petrogenesis and mantle evolution. Lithos 282:228–239. https://doi.org/10.1016/j.lithos.2017.03.018
Grondahl C, Zajacz Z (2022) Sulfur and chlorine budgets control the ore fertility of arc magmas. Nat Commun 13:4218. https://doi.org/10.1038/s41467-022-31894-0
Gualda GA, Ghiorso MS, Lemons RV, Carley TL (2012) Rhyolite-MELTS: a modified calibration of MELTS optimized for silica-rich, fluid-bearing magmatic systems. J Petrol 53:875–890. https://doi.org/10.1093/petrology/egr080
Hao H, Park J-W (2023) A metasomatized mantle origin for the post-collisional porphyry ore-forming magmas in the Sanjiang metallogenic belt, Southwest China. Terra Nova 35:285–293. https://doi.org/10.1111/ter.12653
Hao H, Campbell IH, Park J-W, Cooke DR (2017) Platinum-group element geochemistry used to determine Cu and Au fertility in the Northparkes igneous suites, New South Wales, Australia. Geochim Cosmochim Acta 216:372–392. https://doi.org/10.1016/j.gca.2017.05.009
Hao H, Campbell IH, Richards JP, Nakamura E, Sakaguchi C (2019) Platinum-group element geochemistry of the Escondida igneous suites, Northern Chile: implications for ore formation. J Petrol 60:487–514. https://doi.org/10.1093/petrology/egz004
Hao H, Campbell IH, Cooke DR, Nakamura E, Sakaguchi C (2021) Geochronology, petrogenesis and oxidation state of the Northparkes igneous suite, New South Wales, Australia: Implications for magma fertility. Econ Geol 116:1161–1187. https://doi.org/10.5382/econgeo.4825
Hao H, Campbell IH, Park J-W (2022a) Nd-Hf isotopic systematics of the arc mantle and their implication for continental crust growth. Chem Geol 602:120897. https://doi.org/10.1016/j.chemgeo.2022.120897
Hao H, Park J-W, Campbell IH (2022b) Role of magma differentiation depth in controlling the Au grade of giant porphyry deposits. Earth Planet Sci Lett 593:117640. https://doi.org/10.1016/j.epsl.2022.117640
Hou Z, Zaw K, Pan G, Mo X, Xu Q, Hu Y, Li X (2007) Sanjiang Tethyan metallogenesis in SW China: Tectonic setting, metallogenic epochs and deposit types. Ore Geol Rev 31:48–87. https://doi.org/10.1016/j.oregeorev.2004.12.007
Hou Z, Zheng Y, Yang Z, Rui Z, Zhao Z, Jiang S, Qu X, Sun Q (2013) Contribution of mantle components within juvenile lower-crust to collisional zone porphyry Cu systems in Tibet. Miner Deposita 48:173–192. https://doi.org/10.1007/s00126-012-0415-6
Hou Z, Yang Z, Lu Y, Kemp A, Zheng Y, Li Q, Tang J, Yang Z, Duan L (2015) A genetic linkage between subduction-and collision-related porphyry Cu deposits in continental collision zones. Geology 43:247–250. https://doi.org/10.1130/G36362.1
Huang M-L, Gao J-F, Bi X-W, Xu L-L, Zhu J-J, Wang D-P (2020) The role of early sulfide saturation in the formation of the Yulong porphyry Cu-Mo deposit: Evidence from mineralogy of sulfide melt inclusions and platinum-group element geochemistry. Ore Geol Rev 124:103644. https://doi.org/10.1016/j.oregeorev.2020.103644
Huang M-L, Zhu J-J, Bi X-W, Xu L-L, Xu Y (2022) Low magmatic Cl contents in giant porphyry Cu deposits caused by early fluid exsolution: A case study of the Yulong belt and implication for exploration. Ore Geol Rev 141:104664. https://doi.org/10.1016/j.oregeorev.2021.104664
Hwang J, Park J-W, Wan B, Honarmand M (2023) Contrasting platinum-group element geochemistry of post-collisional porphyry Cu±Au ore-bearing and barren suites in the central and southeastern Urumieh-Dokhtar magmatic arc, Iran. Miner Deposita 58:1583–1603. https://doi.org/10.1007/s00126-023-01195-7
Ishihara S, Ohno T (2016) Geochemical variation of the Late Cretaceous-Paleogene granitoids across the Ehime-Hiroshima-Shimane transect, Japan. Bull Geol Surv Jpn 67:41–58. https://doi.org/10.9795/bullgsj.67.41
Jenner FE, O’Neill HSC, Arculus RJ, Mavrogenes JA (2010) The magnetite crisis in the evolution of arc-related magmas and the initial concentration of Au, Ag and Cu. J Petrol 51:2445–2464. https://doi.org/10.1093/petrology/egq063
Jiang Y-H, Jiang S-Y, Ling H-F, Dai B-Z (2006) Low-degree melting of a metasomatized lithospheric mantle for the origin of Cenozoic Yulong monzogranite-porphyry, east Tibet: geochemical and Sr–Nd–Pb–Hf isotopic constraints. Earth Planet Sci Lett 241:617–633. https://doi.org/10.1016/j.epsl.2005.11.023
Keays RR, Tegner C (2015) Magma chamber processes in the formation of the low-sulphide magmatic Au–PGE mineralization of the Platinova Reef in the Skaergaard Intrusion, East Greenland. J Petrol 56:2319–2340. https://doi.org/10.1093/petrology/egv075
Kiseeva ES, Wood BJ (2015) The effects of composition and temperature on chalcophile and lithophile element partitioning into magmatic sulphides. Earth Planet Sci Lett 424:280–294. https://doi.org/10.1016/j.epsl.2015.05.012
Large RR, Gemmell JB, Paulick H, Huston DL (2001) The alteration box plot: A simple approach to understanding the relationship between alteration mineralogy and lithogeochemistry associated with volcanic-hosted massive sulfide deposits. Econ Geol 96:957–971. https://doi.org/10.2113/gsecongeo.96.5.957
Lee C-TA, Lee TC, Wu C-T (2014) Modeling the compositional evolution of recharging, evacuating, and fractionating (REFC) magma chambers: Implications for differentiation of arc magmas. Geochim Cosmochim Acta 143:8–22. https://doi.org/10.1016/j.gca.2013.08.009
Li W, Yang Z, Chiaradia M, Lai Y, Yu C, Zhang J (2020) Redox state of southern Tibetan upper mantle and ultrapotassic magmas. Geology 48:733–736. https://doi.org/10.1130/G47411.1
Li Y, Audétat A, Liu Z, Wang F (2021) Chalcophile element partitioning between Cu-rich sulfide phases and silicate melt and implications for the formation of Earth’s continental crust. Geochim Cosmochim Acta 302:61–82. https://doi.org/10.1016/j.gca.2021.03.020
Liang HY, Sun W, Su WC, Zartman RE (2009) Porphyry copper-gold mineralization at Yulong, China, promoted by decreasing redox potential during magnetite alteration. Econ Geol 104:587–596. https://doi.org/10.2113/gsecongeo.104.4.587
Liu Y, Brenan J (2015) Partitioning of platinum-group elements (PGE) and chalcogens (Se, Te, As, Sb, Bi) between monosulfide-solid solution (MSS), intermediate solid solution (ISS) and sulfide liquid at controlled fO2–fS2 conditions. Geochim Cosmochim Acta 159:139–161. https://doi.org/10.1016/j.gca.2015.03.021
Lowczak JN, Campbell IH, Cocker H, Park J-W, Cooke DR (2018) Platinum-group element geochemistry of the Forest Reef Volcanics, southeastern Australia: Implications for porphyry Au-Cu mineralization. Geochim Cosmochim Acta 220:385–406. https://doi.org/10.1016/j.gca.2017.09.052
Lu Y-J, Loucks RR, Fiorentini ML, Yang Z-M, Hou Z-Q (2015) Fluid flux melting generated postcollisional high Sr/Y copper ore–forming water-rich magmas in Tibet. Geology 43:583–586. https://doi.org/10.1130/G36734.1
Matjuschkin V, Blundy JD, Brooker RA (2016) The effect of pressure on sulphur speciation in mid-to deep-crustal arc magmas and implications for the formation of porphyry copper deposits. Contrib Miner Petrol 171:1–25. https://doi.org/10.1007/s00410-016-1274-4
McFall K, McDonald I, Wilkinson JJ (2021) Assessing the role of tectono-magmatic setting in the precious metal (Au, Ag, PGE) and critical metal (Te, Se, Bi) endowment of porphyry Cu deposits. SEG Spec Publ 24:277–295. https://doi.org/10.5382/SP.24.15
Meisel T, Fellner N, Moser J (2003) A simple procedure for the determination of platinum group elements and rhenium (Ru, Rh, Pd, Re, Os, Ir and Pt) using ID-ICP-MS with an inexpensive on-line matrix separation in geological and environmental materials. J Anal At Spectrom 18:720–726. https://doi.org/10.1039/B301754K
Metcalfe I (2021) Multiple Tethyan ocean basins and orogenic belts in Asia. Gondwana Res 100:87–130. https://doi.org/10.1016/j.gr.2021.01.012
Misztela MA, Campbell IH, Arculus RJ (2022) Platinum-group element geochemistry and magma evolution of the Mount Hagen (Papua New Guinea) magmatic system. J Petrol 63:egad023. https://doi.org/10.1093/petrology/egac023
Mungall JE, Brenan JM (2014) Partitioning of platinum-group elements and Au between sulfide liquid and basalt and the origins of mantle-crust fractionation of the chalcophile elements. Geochim Cosmochim Acta 125:265–289. https://doi.org/10.1016/j.gca.2013.10.002
Park J-W, Campbell IH, Eggins SM (2012) Enrichment of Rh, Ru, Ir and Os in Cr spinels from oxidized magmas: evidence from the Ambae volcano, Vanuatu. Geochim Cosmochim Acta 78:28–50. https://doi.org/10.1016/j.gca.2011.11.018
Park J-W, Campbell IH, Kim J, Moon J-W (2015) The role of late sulfide saturation in the formation of a Cu-and Au-rich magma: Insights from the platinum group element geochemistry of Niuatahi-Motutahi lavas, Tonga rear arc. J Petrol 56:59–81. https://doi.org/10.1093/petrology/egu071
Park J-W, Campbell IH, Kim J (2016) Abundances of platinum group elements in native sulfur condensates from the Niuatahi-Motutahi submarine volcano, Tonga rear arc: implications for PGE mineralization in porphyry deposits. Geochim Cosmochim Acta 174:236–246. https://doi.org/10.1016/j.gca.2015.11.026
Park J-W, Campbell IH, Malaviarachchi SP, Cocker H, Hao H, Kay SM (2019) Chalcophile element fertility and the formation of porphyry Cu±Au deposits. Miner Deposita 54:657–670. https://doi.org/10.1007/s00126-018-0834-0
Park J-W, Campbell IH, Chiaradia M, Hao H, Lee C-T (2021) Crustal magmatic controls on the formation of porphyry copper deposits. Nat Rev Earth Environ 2:542–557. https://doi.org/10.1038/s43017-021-00182-8
Profeta L, Ducea MN, Chapman JB, Paterson SR, Gonzales SMH, Kirsch M, Petrescu L, DeCelles PG (2015) Quantifying crustal thickness over time in magmatic arcs. Sci Rep 5:1–7. https://doi.org/10.1038/srep17786
Rezeau H, Jagoutz O (2020) The importance of H2O in arc magmas for the formation of porphyry Cu deposits. Ore Geol Rev 126:103744. https://doi.org/10.1016/j.oregeorev.2020.103744
Richards J (2003) Tectono-magmatic precursors for porphyry Cu-(Mo-Au) deposit formation. Econ Geol 98:1515–1533. https://doi.org/10.2113/gsecongeo.98.8.1515
Richards JP (2009) Postsubduction porphyry Cu-Au and epithermal Au deposits: Products of remelting of subduction-modified lithosphere. Geology 37:247–250. https://doi.org/10.1130/G25451A.1
Richards JP (2011) High Sr/Y arc magmas and porphyry Cu±Mo±Au deposits: Just add water. Econ Geol 106:1075–1081. https://doi.org/10.2113/econgeo.106.7.1075
Sillitoe RH (2010) Porphyry copper systems. Econ Geol 105:3–41. https://doi.org/10.2113/gsecongeo.105.1.3
Singer DA (1995) World class base and precious metal deposits; a quantitative analysis. Econ Geol 90:88–104. https://doi.org/10.2113/gsecongeo.90.1.88
Smythe DJ, Wood BJ, Kiseeva ES (2017) The S content of silicate melts at sulfide saturation: new experiments and a model incorporating the effects of sulfide composition. Am Miner 102:795–803. https://doi.org/10.2138/am-2017-5800CCBY
Tassara S, Ague JJ (2022) A role for crustal assimilation in the formation of copper-rich reservoirs at the base of continental arcs. Econ Geol 117:1481–1496. https://doi.org/10.5382/econgeo.4975
Wan B, Deng C, Najafi A, Hezareh MR, Talebian M, Dong L, Chen L, Xiao W (2018) Fertilizing porphyry Cu deposits through deep crustal hot zone melting. Gondwana Res 60:179–185. https://doi.org/10.1016/j.gr.2018.04.006
Wang R, Richards JP, Hou Z-q, Yang Z-m, Gou Z-b, DuFrane SA (2014a) Increasing magmatic oxidation state from paleocene to miocene in the eastern Gangdese Belt, Tibet: implication for collision-related porphyry Cu-Mo±Au mineralization. Econ Geol 109:1943–1965. https://doi.org/10.2113/econgeo.109.7.1943
Wang R, Richards JP, Hou Z, Yang Z, DuFrane SA (2014b) Increased magmatic water content—the key to Oligo-Miocene porphyry Cu-Mo±Au formation in the eastern Gangdese belt, Tibet. Econ Geol 109:1315–1339. https://doi.org/10.2113/econgeo.109.5.1315
Wang X, Zhang J, Rushmer T, Adam J, Turner S, Xu W (2019) Adakite-like potassic magmatism and crust-mantle interaction in a postcollisional setting: An experimental study of melting beneath the Tibetan Plateau. J Geophys Res: Solid Earth 124:12782–12798. https://doi.org/10.1029/2019JB018392
Wang R, Zhu D, Wang Q, Hou Z, Yang Z, Zhao Z, Mo X (2020) Porphyry mineralization in the Tethyan orogeny. Sci China Earth Sci 63:2042–2067. https://doi.org/10.1007/s11430-019-9609-0
Wang R, Luo CH, Xia WJ, He WY, Liu B, Huang ML, Hou ZQ, Zhu DC (2021) Role of alkaline magmatism information of porphyry deposits in nonarc settings: Gangdese and Sanjiang metallogenic belts. Soc Econ Geol Spec Publ 24:205–229. https://doi.org/10.5382/SP.24.12
Wang X, Wang Z, Cheng H, Zong K, Wang CY, Ma L, Cai Y-C, Foley S, Hu Z (2022) Gold endowment of the metasomatized lithospheric mantle for giant gold deposits: Insights from lamprophyre dykes. Geochim Cosmochim Acta 316:21–40. https://doi.org/10.1016/j.gca.2021.10.006
Woodland SJ, Pearson DG, Thirlwall MF (2002) A platinum group element and Re–Os isotope investigation of siderophile element recycling in subduction zones: comparison of Grenada, Lesser Antilles Arc, and the Izu-Bonin Arc. J Petrol 43:171–198. https://doi.org/10.1093/petrology/43.1.171
Xu B, Hou ZQ, Griffin WL, Zhou Y, Zhang YF, Lu YJ, Belousova E, Xu JF, O’Reilly SY (2021a) Elevated magmatic chlorine and sulfur concentrations in the Eocene-Oligocene Machangqing Cu-Mo porphyry systems. Soc Econ Geol Spec Publ 24:257–276. https://doi.org/10.5382/SP.24.14
Xu B, Hou ZQ, Griffin WL, Lu Y, Belousova E, Xu JF, O’Reilly SY (2021b) Recycled volatiles determine fertility of porphyry deposits in collisional settings. Am Miner 106:656–661. https://doi.org/10.2138/am-2021-7714
Xu LL, Zhu JJ, Huang ML, Pan LC, Hu R, Bi XW (2023) Genesis of hydrous-oxidized parental magmas for porphyry Cu (Mo, Au) deposits in a postcollisional setting: examples from the Sanjiang region, SW China. Miner Deposita 58:161–196. https://doi.org/10.1007/s00126-022-01143-x
Yang ZM, Lu YJ, Hou ZQ, Chang ZS (2015) High-Mg diorite from Qulong in southern Tibet: Implications for the genesis of adakite-like intrusions and associated porphyry Cu deposits in collisional orogens. J Petrol 56:227–254. https://doi.org/10.1093/petrology/egu076
Yang Z, Yang L-Q, He W-Y, Gao X, Liu X-D, Bao X-S, Lu Y-G (2017) Control of magmatic oxidation state in intracontinental porphyry mineralization: A case from Cu (Mo–Au) deposits in the Jinshajiang-Red River metallogenic belt, SW China. Ore Geol Rev 90:827–846. https://doi.org/10.1016/j.oregeorev.2016.11.026
Yi JK, Zhu DC, Weinberg RF, Wang Q, Xie JC, Zhang LL, Zhao ZD (2022) Origin of Tibetan post-collisional high-K adakitic granites: Anatexis of intermediate to felsic arc rocks. Geology 50:771–775. https://doi.org/10.1130/G49818.1
Zhang J, Chang J, Wang R, Audétat A (2022) Can post-subduction porphyry Cu magmas form by partial melting of typical lower crustal amphibole-rich cumulates? Petrographic and experimental constraints from samples of the Kohistan and Gangdese arc roots. J Petrol 63:egac101. https://doi.org/10.1093/petrology/egac101
Zheng Y-C, Hou Z-Q, Li Q-Y, Sun Q-Z, Liang W, Fu Q, Li W, Huang K-X (2012) Origin of Late Oligocene adakitic intrusives in the southeastern Lhasa terrane: evidence from in situ zircon U-Pb dating, Hf–O isotopes, and whole-rock geochemistry. Lithos 148:296–311. https://doi.org/10.1016/j.lithos.2012.05.026
Zheng W, Tang J, Zhong K, Ying L, Leng Q, Ding S, Lin B (2016) Geology of the Jiama porphyry copper–polymetallic system, Lhasa Region, China. Ore Geol Rev 74:151–169. https://doi.org/10.1016/j.oregeorev.2015.11.024
Zheng Y-C, Liu S-A, Wu C-D, Griffin WL, Li Z-Q, Xu B, Yang Z-M, Hou Z-Q, O’Reilly SY (2019) Cu isotopes reveal initial Cu enrichment in sources of giant porphyry deposits in a collisional setting. Geology 47:135–138. https://doi.org/10.1130/G45362.1
Zheng YC, Tian SH, Hou ZQ, Fu Q, Zhu DC (2020) Magmatic and structural controls on the tonnage and metal associations of collision-related porphyry copper deposits in southern Tibet. Ore Geol Rev 122:103509. https://doi.org/10.1016/j.oregeorev.2020.103509
Zheng YC, Shen Y, Wang L, Griffin WL, Hou ZQ (2021) Collision-related porphyry Cu deposits formed by input of ultrapotassic melts into the sulfide-rich lower crust. Terra Nova 33:582–589. https://doi.org/10.1111/ter.12550
Zhou Y, Xu B, Hou ZQ, Wang R, Zheng YC, He WY (2019) Petrogenesis of Cenozoic high–Sr/Y shoshonites and associated mafic microgranular enclaves in an intracontinental setting: implications for porphyry Cu-Au mineralization in western Yunnan, China. Lithos 324:39–54. https://doi.org/10.1016/j.lithos.2018.10.031
Zhu DC, Wang Q, Cawood PA, Zhao ZD, Mo XX (2017) Raising the Gangdese mountains in southern Tibet. J Geophys Res: Solid Earth 122:214–223. https://doi.org/10.1002/2016JB013508
Acknowledgements
This work was supported by the National Natural Science Foundation of China (Grant Nos. 92155305 and 42125204), the “Huang Jiqing” Young Scholar Project (J2322) from Institute of Geology, Chinese Academy of Geological Sciences, the National Research Foundation of Korea funded by the Ministry of Science and ICT (2022R1A2C1011741, 2022R1A5A1085103 and 2022R1I1A1A01068921) and the Brain Korea 21 FOUR Project through the School of Earth and Environmental Sciences, Seoul National University. We appreciate the suggestions from Prof. Rui Wang and constructive comments from Jia Chang and an anonymous reviewer.
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Hao, H., Park, JW., Zheng, YC. et al. Role of chalcophile element fertility in the formation of the eastern Tethyan post-collisional porphyry Cu deposits. Miner Deposita (2024). https://doi.org/10.1007/s00126-024-01280-5
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DOI: https://doi.org/10.1007/s00126-024-01280-5