Abstract
The large Hebaoshan gold deposit (41.5 t Au, average grade: 3.5 g/t) is located in a hitherto poorly documented gold province in the northeastern part of the South China Block. It is hosted by Precambrian metasedimentary rocks that experienced Triassic greenschist- to amphibolite-facies metamorphism. Three hydrothermal stages can be distinguished: quartz + sericite + pyrite + pyrrhotite (stage I), quartz + magnetite + sulfide (stage II), and quartz + carbonate + pyrite + hematite (stage III). Auriferous pyrite samples yielded a Rb-Sr isochron age of 234 ± 3 Ma (2σ, MSWD = 0.24), and ore-related hydrothermal sericite yielded a 40Ar-39Ar plateau age of 226.4 ± 2.0 Ma (2σ, MSWD = 1.01), which are distinctly younger than ca. 430 Ma granitic rocks in the mining district and older than 170–130 Ma granites in the region, ruling out any genetic link between granite emplacement and gold mineralization. The mineralizing fluid system can be described as carbonic-aqueous with low to moderate salinity (2.2–10.1 wt% NaCl equiv.) and medium temperature of 290 to 350 °C (stage I) and 230 to 280 °C (stage II). The δ18O quartz ranges from 13.3 to 15.4 ‰, and the δD values for fluid inclusions in quartz range from − 97 to − 60 ‰. The calcite has C-isotopes ranging from − 6.1 to − 3.8 ‰ and O-isotopes from 2.8 to 13.6 ‰. H-O-C isotope data are consistent with a metamorphic fluid derived from devolatilization of Neoproterozoic basement rocks during regional metamorphism in the Late Triassic Indosinian period. The δ34S values of sulfides for stages I, II, and III are 0.1 to 7.8 ‰, − 10.6 to 5.1 ‰, and − 18.9 to − 14.1 ‰, respectively, indicating an increase in oxygen fugacity during fluid ascent which resulted in more negative sulfur isotope values of sulfides and precipitation of gold. Pyrite separates have 206Pb/204Pb ratios of 17.340 to 17.687, 207Pb/204Pb ratios of 15.539 to 15.604, and 208Pb/204Pb ratios of 37.749 to 38.094. The S-Pb isotope data suggest derivation of S and Pb from the Precambrian metasedimentary country rocks. Auriferous pyrite yielded elevated 3He/4He ratios (0.78–1.46 Ra), which suggest a mantle component as can be expected from fluids derived from a subduction setting. It is concluded that Hebaoshan is an orogenic gold deposit that formed during Triassic flat-slab subduction of the paleo-Pacific plate beneath the South China Block and thus constitutes the first Triassic deposit of this type recognized in the coastal area of Southeast China.
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Acknowledgements
We thank Mr. Zhuang Lin and Jianwen Du from the Fujian Institute of Geological Survey and Research for invaluable assistance during the fieldwork. Drs. Kui-Dong Zhao, De-Fang Wan, Zeng-Jie Zhang, Mou-Chun He, Wei Chen, Hai-Xiang Zhao, Yao-Ming Xu, Rui-Chun Duan, Jia-Xin She, and Xu Dai are also thanked for their kind help with lab work. This paper has been greatly improved by a thorough review from two anonymous reviewers, associate editor Prof. Ruizhong Hu, and editor Prof. Bernd Lehmann.
Funding
This study was supported by the National Natural Science Foundation of China (grant no. 41973044), the National 111 Project (B20045), the MOST Special Fund from the State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences (No. MSFGPMR03-2), and the Fundamental Research Funds for National Universities, China University of Geosciences (Wuhan) (grant no 2201610076). Mr. Ying Ma gratefully acknowledges financial support from the China Scholarship Council (grant no. 201906410039).
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Ma, Y., Jiang, SY., Frimmel, H.E. et al. Genesis of the Hebaoshan gold deposit in Fujian Province of Southeast China: constraints from a combined fluid inclusion, H-O-C-S-Pb-He-Ar isotope and geochronological study. Miner Deposita 57, 13–34 (2022). https://doi.org/10.1007/s00126-021-01046-3
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DOI: https://doi.org/10.1007/s00126-021-01046-3