Abstract
The Bolivian tin belt is a metallogenic province in the Eastern Cordillera of the Andes known for its Sn, W, Ag, and base metal deposits. Cassiterite, which is a major constituent in many magmatic-hydrothermal ore deposits from the Bolivian tin belt, can incorporate dozens of elements within its crystal lattice, making it a useful geological tracer mineral and also a potential host of critical elements. New U-Pb dating of cassiterite yields Late Triassic (Kellhuani deposit) and Late Oligocene to earliest Miocene (Viloco, Huanuni, and Llallagua deposits) ages. These ages confirm that Sn mineralization in the Bolivian tin belt occurred at least in two separate events during two major magmatic episodes apparently triggered by mantle upwelling, decompression melting, and basalt production promoting high heat flow into the overlying crust. The composition of studied hydrothermal cassiterite yields some geochemical trends that are attributed to its distance to the causative intrusion and/or level of emplacement. For example, cassiterite is generally enriched in Nb and Ta and yields higher Ti/Zr and Ti/Sc ratios in samples from xenothermal ore deposits located adjacent to intrusive complexes relative to shallow xenothermal and epithermal ore deposits. Therefore, these geochemical trends in cassiterite are useful tracers pointing to magmatic-hydrothermal centers. REE distribution in cassiterite was likely influenced by boiling processes, which resulted in tetrad-type irregularities. Cassiterite from the Bolivian tin belt is unattractive as a source for Nb (interquartile range [IQR] 4.84–0.037 ppm), Ta (IQR 0.0924–0.0126 ppm), and Ge (IQR 3.92–0.776 ppm). Some deposits, however, contain cassiterite relatively enriched in In (IQR 96.9–9.78 ppm, up to 1414 ppm) and Ga (IQR 92.1–3.03, up to 7437 ppm), that could constitute an attractive supplementary source for these elements in addition to sulfide minerals in the same deposits.
Similar content being viewed by others
References
Abdalla HM, Matsueda H, Obeid MA, Takahashi R (2008) Chemistry of cassiterite in rare metal granitoids and the associated rocks in the Eastern Desert, Egypt. J Mineral Petrol Sci 103:318–326. https://doi.org/10.2465/jmps.070528a
Ahlfeld F (1967) Metallogenetic epochs and provinces of Bolivia. Mineral Deposita 2:291–311. https://doi.org/10.1007/BF00207022
Ahlfeld F, Branisa L (1960) Geología de Bolivia. Don Bosco, Texas
Ahlfeld F, Schneider-Scherbina A (1964) Los yacimientos minerales y de hidrocarburos de Bolivia. Bolivia Departamento Nac Geol 5:1–388
Arce-Burgoa O (2009) Metalliferous ore deposits of Bolivia. SPC Impresores: La Paz
Arce-Burgoa O, Goldfarb RJ (2009) Metallogeny of Bolivia. SEG Newsletter 79:1–15
Artiaga D, Torres B, Torró L, Tauler E, Melgarejo JC, Arce-Burgoa O (2013) The Viloco Sn-W-Mo-As deposits, Bolivia: geology and mineralogy. Conference: 12th SGA Biennial Meeting “Mineral deposit research for a high-tech world”, 3:1239–1242, Uppsala
Baldellón E, Fornari M, Espinoza F, Soler P (1994) Sucesión estructural de la zona Serranía de las Minas. XI Congreso Geológico de Bolivia, Memorias, pp 238–247
Bau M (1996) Controls on the fractionation of isovalent trace elements in magmatic and aqueous systems: evidence from Y/Ho, Zr/Hf, and lanthanide tetrad effect. Contrib Mineral Petrol 123:323–333. https://doi.org/10.1007/s004100050159
Betkowski WB, Rakovan J, Harlov DE (2017) Geochemical and textural characterization of phosphate accessory phases in the vein assemblage and metasomatically altered Llallagua tin porphyry. Mineral Petrol 111:547–568. https://doi.org/10.1007/s00710-017-0510-6
Buddington AF (1935) High-temperature mineral associations at shallow to moderate depths. Econ Geol 30:205–222. https://doi.org/10.2113/gsecongeo.30.3.205
Cacho A, Melgarejo JC, Camprubí A, Torró L, Castillo-Oliver M, Torres B, Artiaga D, Tauler E, Martínez Á, Campeny M, Alfonso P, Arce-Burgoa OR (2019) Mineralogy and distribution of critical elements in the Sn–W–Pb–Ag–Zn Huanuni deposit, Bolivia. Minerals 9:753. https://doi.org/10.3390/min9120753
Chace FM (1948a) Tin-silver veins of Oruro, Bolivia, part I. Econ Geol 43:333–383. https://doi.org/10.2113/gsecongeo.43.5.333
Chace FM (1948b) Tin-silver veins of Oruro Bolivia; part II. Econ Geol 43:435–470. https://doi.org/10.2113/gsecongeo.43.6.435
Cheilletz A, Clark AH, Farrar E, Arroyo Pauca G, MacArthur JD, Pichavant M (1990) Stratigraphy and geochronology of the Macusani ignimbrite field: chronometer of the Mio-Pliocene geodynamic evolution of the Andes of SE Peru. In: Symposium international “Géodynamique andine”: résumés des communications. ORSTOM, Paris, pp 341–344
Chen LL, Ni P, Dai BZ, Li WS, Chi Z, Pan JY (2019) The genetic association between quartz vein- and greisen-type mineralization at the Maoping W–Sn deposit, southern Jiangxi, China: insights from zircon and cassiterite U–Pb ages and cassiterite trace element composition. Minerals 9:411. https://doi.org/10.3390/min9070411
Cheng Y, Spandler C, Kemp A, Mao J, Rusk B, Hu Y, Blake K (2019) Controls on cassiterite (SnO2) crystallization: evidence from cathodoluminescence, trace-element chemistry, and geochronology at the Gejiu Tin District. Am Mineral 104:118–129. https://doi.org/10.2138/am-2019-6466
Clark AH, Farrar E (1973) The Bolivian Tin Province; notes on the available geochronological data. Econ Geol 68:102–106. https://doi.org/10.2113/gsecongeo.68.1.102
Clark AH, Farrar E, Caelles JC, Haynes SJ, Lortie RB, McBride SL, Quirt GS, Robertson RCR, Zentilli M (1976) Longitudinal variations in the metallogenetic evolution of the Central Andes: a progress report. Geol S Am S 14:23–58
Clark AH, Palma VV, Archibald DA, Farrar E, Robertson RCR (1983) Occurrence and age of tin mineralization in the Cordillera Oriental, southern Peru. Econ Geol 78:514–520. https://doi.org/10.2113/gsecongeo.78.3.514
Clark AH, Farrar E, Kontak DJ, Langridge RJ, Arenas FMJ, France LJ, McBride SL, Woodman PL, Wasteneys HA, Sandeman HA, Archibald DA (1990) Geologic and geochronologic constraints on the metallogenic evolution of the Andes of southeastern Peru. Econ Geol 85:1520–1583. https://doi.org/10.2113/gsecongeo.85.7.1520
Clark AH, Chen Y, Grant JW, Kontak DJ, Wasteneys HA, Sandeman HA, Farrar E, Archibald DE (2000) Delayed inception of ore deposition in major lithophile-metal vein systems: the San Rafael tin and Pasto Bueno tungsten deposits, Peru. Geol S Am S 32:279
Claure H, Olivera L, Heuschmidt B, Arduz M, Troëng B, Ballón R (1996) Mapas temáticos de recursos minerales de Bolivia. Hoja Uncía: Bol Ser Geol Bolivia 7:184
Cordani U G (1967) Unpublished letter in library of Servicio Geológico de Bolivia, LaPaz
Cordani UG, Iriarte AR, Sato K (2019) Geochronological systematics of the Huayna Potosí, Zongo and Taquesi plutons, Cordillera Real of Bolivia, by the K/Ar, Rb/Sr and U/Pb methods. Braz J Geol 49:1–22. https://doi.org/10.1590/2317-4889201920190016
Cunningham CG, Zartman RE, McKee EH, Rye RO, Naeser CW, Sanjinés V, Ericksen GE, Tavera V (1996) The age and thermal history of Cerro Rico de Potosi, Bolivia. Mineral Deposita 31:374–385. https://doi.org/10.1007/BF00189185
de Silva SL, Kay MS (2018) Turning up the heat: high-flux magmatism in the Central Andes. Elements 14:245–250. https://doi.org/10.2138/gselements.14.4.245
DeCelles PG, Horton BK (2003) Early to middle tertiary foreland basin development and the history of Andean crustal shortening in Bolivia. Geol Soc Am Bull 115:58–77. https://doi.org/10.1130/0016-7606(2003)115%3C0058:ETMTFB%3E2.0.CO;2
Demouy S, Paquette J-L, de Saint-Blanquat M, Benoit M, Belousova EA, O'Reilly SY, García F, Tejada LC, Gallegos R, Sempere T (2012) Spatial and temporal evolution of Liassic to Paleocene arc activity in southern Peru unraveled by zircon U-Pb and Hf in-situ data on plutonic rocks. Lithos 155:183–200. https://doi.org/10.1016/j.lithos.2012.09.001
Díaz E (1997) Facies y ambientes sedimentarios de la Formación Cancañiri (Silúrico inferior) en La Cumbre de La Paz, norte de la Cordillera Oriental de Bolivia. Geogaceta 22:55–57
Dietrich A, Lehmann B, Wallianos A (2000) Bulk rock and melt inclusion geochemistry of Bolivian tin porphyry systems. Econ Geol 95:313–326. https://doi.org/10.2113/gsecongeo.95.2.313
European Commission (2017) Critical Raw Materials. https://ec.europa.eu/growth/sectors/raw-materials/specific-interest/critical_en. Accessed 14 Apr 2020
Everden JF (1961) Edades absolutas de algunas rocas ígneas en Bolivia por el método potasio-argón. Soc Geol Bol Not 2:3
Evernden JF, Kriz SJ, Cherroni CM (1977) Potassium-argon ages of some Bolivian rocks. Econ Geol 72:1042–1061. https://doi.org/10.2113/gsecongeo.72.6.1042
Farrar E, Clark AH, Kontak DJ, Archibald DA (1988) Zongo-San Gabán zone: Eocene foreland boundary of the Central Andean orogen, Northwest Bolivia and Southeast Peru. Geology 16:55–58. https://doi.org/10.1130/0091-7613(1988)016%3C0055:ZSGNZE%3E2.3.CO;2
Farrar E, Clark AH, Heinrich SM (1990) The age of the Zongo pluton and the tectonothermal evolution of the Zongo-San Gabán Zone in the Cordillera Real, Bolivia. Extended abstracts, 1st International Symposium on Andean Geodynamics, Grenoble, pp 171–174
Fontboté L (2018) Ore deposits of the Central Andes. Elements 14:257–261. https://doi.org/10.2138/gselements.14.4.257
Fornari M, Baldellón E, Espinoza F, Ibarra I, Jiménez N, Mamani M (2002) Ar-Ar dating of Late Oligocene-Early Miocene volcanism in the Altiplano. Extended abstracts, 4th International Symposium on Andean Geodynamics, Toulouse, pp 223–226
Fuchsloch W, Nex P, Kinnaird J (2019) The geochemical evolution of Nb-Ta-Sn oxides from pegmatites of the Cape Cross–Uis pegmatite belt, Namibia. Mineral Mag 83:1–56. https://doi.org/10.1180/mgm.2018.151
Gillis RJ, Horton BK, Grove M (2006) Thermochronology, geochronology, and upper crustal structure of the Cordillera Real: implications for Cenozoic exhumation of the central Andean plateau. Tectonics 25:1–22. https://doi.org/10.1029/2005TC001887
Gordon SG (1944) The mineralogy of the tin mines of Cerro de Llallagua, Bolivia. Proc Acad Nat Sci Philadelphia 96:279–359
Gorelikova NV, Khanchuk AI, Bortnikov NS, Pawlowsky-Glahn V, Tolosana-Delgado R (2004) Classification of tin deposits using trace elements in cassiterites (Far East, Russia). In: Proceedings of the Interim Iagod Conference Vladivostok, Russia. Dal’nauka, pp 590–593
Gorelikova NV, Tolosana-Delgado R, Pawlowsky-Glahn V, Khanchuk A, Gonevchuk V (2006) Discriminating geodynamical regimes of tin ore formation using trace element composition of cassiterite: the Sikhote'Alin case (Far Eastern Russia). Geol Soc Lond Spec Publ 264:43–57. https://doi.org/10.1144/GSL.SP.2006.264.01.04
Grant JN, Halls C, Salinas WA, Snelling NJ (1979) K-Ar ages of igneous rocks and mineralization in part of the Bolivian tin belt. Econ Geol 74:838–851. https://doi.org/10.2113/gsecongeo.74.4.838
Guillong M, Hametner K, Reusser E, Wilson SA, Günther D (2005) Preliminary characterisation of new glass reference materials (GSA-1G, GSC-1G, GSD-1G and GSE-1G) by laser ablation-inductively coupled plasma-mass spectrometry using 193 nm, 213 nm and 266 nm wavelengths. Geostand Geoanal Res 29:315–331. https://doi.org/10.1111/j.1751-908x.2005.tb00903.x
Guillong M, Meier DL, Allan MM, Heinrich CA, Yardley BWD (2008) SILLS: a MATLAB-based program for the reduction of laser ablation ICP-MS data of homogeneous materials and inclusions. In: Sylvester P, (ed) laser ablation ICP-MS in the earth sciences: current practices and outstanding issues. Miner Assoc Can. Short course 40
Guillong M, Wotzlaw JF, Looser N, Laurent O (2020) Evaluating the reliability of U–Pb laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) carbonate geochronology: matrix issues and a potential calcite validation reference material. Geochronology 2:155–167. https://doi.org/10.5194/gchron-2-155-2020
Guo J, Zhang RQ, Sun WD, Ling MX, Hu YB, Wu K, Zhang LC (2018) Genesis of tin-dominant polymetallic deposits in the Dachang district, South China: insights from cassiterite U-Pb ages and trace element compositions. Ore Geol Rev 95:863–879. https://doi.org/10.1016/j.oregeorev.2018.03.023
Gupta CK, Suri AK (1994) Extractive metallurgy of niobium. CRC press inc., Florida
Harlaux M, Kouzmanov K, Gialli S, Laurent O, Rielli A, Dini A, Chauvet A, Menzies A, Kalinaj M, Fontboté L (2020) Tourmaline as a tracer of late-magmatic to hydrothermal fluid evolution: the world-class San Rafael tin (-copper) deposit, Peru. Econ Geol, in press 115:1665–1697. https://doi.org/10.5382/econgeo.4762
Hellstrom JC, Paton C, Woodhead JD, Hergt JM (2008) Iolite: software for spatially resolved LA-(quad and MC) ICP-MS analysis. In: Sylvester P (ed) laser ablation ICP-MS in the earth sciences: current practices and outstanding issues. Miner Assoc Can 40:343–348
Heuschmidt B, La Torre JB, Angels VM, Zapata MC (2002) Las áreas prospectivas de Bolivia para yacimientos metalíferos. Boletín del Servicio Nacional de Geología y Minería, 30, La Paz
Horton BK, Hampton BA, Waanders GL (2001) Paleogene synorogenic sedimentation in the Altiplano plateau and implications for initial mountain building in the Central Andes. Geol Soc Am Bull 113:1387–1400. https://doi.org/10.1130/0016-7606(2001)113%3C1387:PSSITA%3E2.0.CO;2
Hoskin PWO, Schaltegger U (2003) The composition of zircon and igneous and metamorphic petrogenesis. Rev Mineral Geochem 53:27–62. https://doi.org/10.2113/0530027
Hulsbosch N, Muchez P (2019) Tracing fluid saturation during pegmatite differentiation by studying the fluid inclusion evolution and multiphase cassiterite mineralisation of the Gatumba pegmatite dyke system (NW Rwanda). Lithos:354–355, Article 105285. https://doi.org/10.1016/j.lithos.2019.105285
Husson L, Sempere T (2003) Thickening the Altiplano crust by gravity-driven crustal channel flow. Geophys Res Lett 30:1243–1246. https://doi.org/10.1029/2002GL016877
Imai H, Lee MS, Iida K, Fujiki Y, Takenouchi S (1975) Geologic structure and mineralization of xenothermal vein-type deposits in Japan. Econ Geol 70:647–676. https://doi.org/10.2113/gsecongeo.70.4.647
Isacks BL (1988) Uplift of the central Andean plateau and bending of the Bolivian orocline. J Geophys Res 93:3211–3231. https://doi.org/10.1029/JB093iB04p03211
Ishihara S (1981) The granitoid series and mineralization. Econ Geol Anniv 75:458–484. https://doi.org/10.5382/AV75.14
Ishihara S, Murakami H, Márquez-Zavalia MF (2011) Inferred indium resources of the Bolivian tin-polymetallic deposits. Resour Geol 61:174–191. https://doi.org/10.1111/j.1751-3928.2011.00157.x
James DE (1971a) Andean crustal and upper mantle structure. J Geophys Res 76:3246–3271. https://doi.org/10.1029/JB076i014p03246
James DE (1971b) Plate tectonic model for the evolution of the Central Andes. Geol Soc Am Bull 82:3325–3346. https://doi.org/10.1130/0016-7606(1971)82[3325:PTMFTE]2.0.CO;2
Jiang SY, Yu JM, Lu JJ (2004) Trace and rare-earth element geochemistry in tourmaline and cassiterite from the Yunlong tin deposit, Yunnan, China: implication for migmatitic-hydrothermal fluid evolution and ore genesis. Chem Geol 209:193–213. https://doi.org/10.1016/j.chemgeo.2004.04.021
Jiménez-Franco A, Alfonso P, Canet C, Trujillo JE (2018) Mineral chemistry of In-bearing minerals in the Santa Fe mining district, Bolivia. Andean Geol 45:410–432. https://doi.org/10.5027/andgeoV45n3-3052
Jochum KP, Wies U, Stoll B, Kuzmin D, Yang Q, Raczek I, Jacob DE, Stracke A, Birbaum K, Frick DA, Günter D, Enzweiler J (2011) Determination of reference values for NIST SRM 610-617 glasses following ISO guidelines. Geostand Geoanal Res 35:397–429. https://doi.org/10.1111/j.1751-908X.2011.00120.x
Jolliff BL, Papike JJ, Laul JC (1987) Mineral recorders of pegmatite internal evolution: REE contents of tourmaline from the Bob Ingersoll pegmatite, South Dakota. Geochim Cosmochim Acta 51:2225–2232. https://doi.org/10.1016/0016-7037(87)90272-9
Kelly WC, Turneaure FS (1970) Mineralogy, paragenesis and geothermometry of the tin and tungsten deposits of the Eastern Andes, Bolivia. Econ Geol 65:609–680. https://doi.org/10.2113/gsecongeo.65.6.609
Kempe U, Lehmann B, Wolf D, Rodionov N, Bombach K, Schwengfelder U, Dietrich A (2008) U–Pb SHRIMP geochronology of Th-poor, hydrothermal monazite: An example from the Llallagua tin-porphyry deposit, Bolivia. Geochim Cosmochim Ac 72:4352–4366. https://doi.org/10.1016/j.gca.2008.05.059
Kendall-Langley L, Kemp A, Grigson J, Hammerli J (2019) U-Pb and reconnaissance Lu-Hf isotope analysis of cassiterite and columbite group minerals from Archean Li-Cs-Ta type pegmatites of Western Australia. Lithos 352–353. Article 105231. https://doi.org/10.1016/j.lithos.2019.105231
Kessel R, Ulmer P, Pettke T, Schmidt MW, Thompson AB (2005) The water-basalt system at 4 to 6 GPa: phase relations and second critical endpoint in a K-free eclogite at 700 to 1400 °C. Earth Planet Sci Lett 237:873–892. https://doi.org/10.1016/j.epsl.2005.06.018
Keutsch F, De Brodtkorb MK (2008) Metalliferous paragenesis of the San José mine, Oruro, Bolivia. J S Am Earth Sci 25:485–491. https://doi.org/10.1016/j.jsames.2007.12.003
Koeppen RP, Smith RL, Kunk MJ, Flores AM, Luedke RG, Sutter JF (1987) The Morococala volcanics: highly peraluminous rhyolite ash flow magmatism in the Cordillera Oriental, Bolivia. Geol S Am S 19:731
Kohn MJ, Vervoort JD (2008) U-Th-Pb dating of monazite by single collector ICP-MS: pitfalls and potential. Geochem Geophys Geosyst 9:1–16. https://doi.org/10.1029/2007GC001899
Kono M, Fukao Y, Yamamoto A (1989) Mountain building in the Central Andes. J Geophys Res 94:3891–3905. https://doi.org/10.1029/JB094iB04p03891
Kontak DJ, Clark AH (2002) Genesis of the giant, bonanza San Rafael lode tin deposit, Peru: origin and significance of pervasive alteration. Econ Geol 97:1741–1777. https://doi.org/10.2113/gsecongeo.97.8.1741
Kontak DJ, Clark AH, Farrar E, Strong DF (1984) The rift-associated Permo-Triassic magmatism of the Eastern Cordillera: a precursor to the Andean orogeny. In: Pitcher WS, Atherton MP, Cobbing EJ, Beckinsale RD (eds) Magmatism at a plate edge: the Peruvian Andes. Blackie, Glasgow-London
Kontak DJ, Clark AH, Pearce TH, Strong DF, Baadsgaard H (1986) Petrogenesis of a Neogene shoshonite suite, Cerro Moromoroni, Puno, southeastern Peru. Can Mineral 24:117–135
Kontak DJ, Clark AH, Farrar E, Archibald DA, Baadsgaard H (1987) Geochronological data for tertiary granites of the Southeast Peru segment of the central Andean tin belt. Econ Geol 82:1711–1618. https://doi.org/10.2113/gsecongeo.82.6.1611
Kontak DJ, Farrar E, Clark AH, Archibald DA (1990) Eocene tectono-thermal rejuvenation of an upper Paleozoic-lower Mesozoic terrane in the Cordillera de Carabaya, Puno, southeastern Peru, revealed by K-Ar and 40Ar/39Ar dating. J S Am Earth Sci 3:231–246. https://doi.org/10.1016/0895-9811(90)90005-L
Lamb S, Hoke L (1997) Origin of the high plateau in the Central Andes, Bolivia, South America. Tectonics 16:623–649. https://doi.org/10.1029/97TC00495
Lancelot JR, Laubacher G, Marocco R, Renaud U (1978) U/Pb radiochronology of two granitic plutons from the Eastern Cordillera (Peru): extent of Permian magmatic activity and consequence. Geol Rundsch 67:286–248. https://doi.org/10.1007/BF01803263
Legros H, Harlaux M, Mercadier J, Romer RL, Poujol M, Camacho A, Marignac C, Cuney M, Wang RC, Charles N, Lespinasse MY (2020) The world-class Nanling metallogenic belt (Jiangxi, China): W and Sn deposition at 160 Ma followed by 30 m.y. of hydrothermal metal redistribution. Ore Geol Rev 117. Article 103302. https://doi.org/10.1016/j.oregeorev.2019.103302
Lehmann B (1985) Formation of the strata-bound Kellhuani tin deposits, Bolivia. Mineral Deposita 20:169–176. https://doi.org/10.1007/BF00204561
Lehmann B, Ishihara S, Michel H, Miller J, Rapela C, Sanchez A, Tistl M, Winkelmann L (1990) The Bolivian tin province and regional tin distribution in the Central Andes: a reassessment. Econ Geol 85:1044–1058. https://doi.org/10.2113/gsecongeo.85.5.1044
Lehmann B, Dietrich A, Heinhorst J, Métrich N, Mosbah M, Palacios C, Schneider HJ, Wallianos A, Webster J, Winkelmann L (2000) Boron in the Bolivian tin belt. Mineral Deposita 35:223–232. https://doi.org/10.1007/s001260050017
Lehmann B, Zoheir B, Neymark L, Zeh A, Emam A, Radwan A, Zhang R, Moscati R (2020) Monazite and cassiterite U-Pb dating of the Abu Dabbab rare-metal granite, Egypt: Late Cryogenian metalliferous granite magmatism in the Arabian-Nubian Shield. Gondwana Res 84:71–80. https://doi.org/10.1016/j.gr.2020.03.001
Lentz D, McAllister A (1990) The petrogenesis of tin- and sulfide-lode mineralization at True Hill, southwestern New Brunswick. Atl Geol 26:136–155. https://doi.org/10.4138/1698
Lerouge C, Gloaguen E, Wille G, Bailly L (2017) Distribution of In and other rare metals in cassiterite and associated minerals in Sn±W ore deposits of the western Variscan Belt. Eur J Mineral 29:739–753. https://doi.org/10.1127/ejm/2017/0029-2673
Luvizotto GL, Zack T, Meyer HP, Ludwig T, Triebold S, Kronz A, Münker C, Stockli DF, Prowatke S, Klemme S, Jacob DE, von Eynatten H (2009) Rutile crystals as potential trace element and isotope mineral standards for microanalysis. Chem Geol 261:346–369. https://doi.org/10.1016/j.chemgeo.2008.04.012
Maffione M, Speranza F, Faccenna C (2009) Bending and growth of the Central Andean plateau: Paleomagnetic and structural constraints from the Eastern Cordillera (22-24°S, NW Argentina). Tectonics 28. https://doi.org/10.1029/2008TC002402
Mamani M, Wörner G, Sempere T (2010) Geochemical variations in igneous rocks of the Central Andean orocline (13°S to 18°S): Tracing crustal thickening and magma generation through time and space. GSA Bull 122:162–182. https://doi.org/10.1130/B26538.1
Mao W, Zhong H, Yang J, Tang Y, Liu L, Fu Y, Zhang X, Sein K, Soe MA, Li J, Le Z (2020) Combined zircon, molybdenite, and cassiterite geochronology and cassiterite geochemistry of the Kuntabin tin-tungsten deposit in Myanmar. Econ Geol 115:603–625. https://doi.org/10.5382/econgeo.4713
Martinez C, Vargas E (1990) Sobre las deformaciones sinsedimentarias mesozoicas de la región de Macha-Pocoata-Colquechaca (Norte de Potosí – Cordillera Oriental de Bolivia). YPFB 11:13–20
McBride SL, Robertson RCR, Clark AH, Farrar E (1983) Magmatic and metallogenetic episodes in the northern tin belt, Cordillera Real, Bolivia. Geol Rundsch 72:685–671. https://doi.org/10.1007/BF01822089
Migdisov A, Williams-Jones AE, Brugger J, Caporuscio FA (2016) Hydrothermal transport, deposition, and fractionation of the REE: experimental data and thermodynamic calculations. Chem Geol 439:13–42. https://doi.org/10.1016/j.chemgeo.2016.06.005
Mišković A, Spikings RA, Chew DM, Kosler J, Ulianov A, Schaltegger U (2009) Tectonomagmatic evolution of Western Amazonia: geochemical characterization and zircon U-Pb geochronologic constraints from the Peruvian Eastern Cordilleran granitoids. Geol Soc Am Bull 121:1298–1324. https://doi.org/10.1130/B26488.1
Mlynarczyk MSJ, Williams-Jones AE (2005) The role of collisional tectonics in the metallogeny of the Central Andean tin belt. Earth Planet Sc Lett 240:656–667. https://doi.org/10.1016/j.epsl.2005.09.047
Möller P, Dulski P, Szacki W, Malow G, Riedel E (1988) Substitution of tin in cassiterite by tantalum, niobium, tungsten, iron and manganese. Geochim Cosmochim Acta 52:1497–1503. https://doi.org/10.1016/0016-7037(88)90220-7
Monecke T, Kempe U, Trinkler M, Thomas R, Dulski P, Wagner T (2011) Unusual rare earth element fractionation in a tin-bearing magmatic-hydrothermal system. Geology 39:295–298. https://doi.org/10.1130/G31659.1
Moore F, Howie RA (1979) Geochemistry of some Cornubian cassiterites. Mineral Deposita 14:103–107. https://doi.org/10.1007/BF00201869
Morgan GB, London D, Luedke RG (1998) Petrochemistry of Late Miocene peraluminous silicic volcanic rocks from the Morococala field, Bolivia. J Petrol 39:601–632. https://doi.org/10.1093/petroj/39.4.601
Moscati R, Neymark L (2019) U–Pb geochronology of tin deposits associated with the Cornubian Batholith of southwest England: direct dating of cassiterite by in situ LA-ICPMS. Mineral Deposita 55:1–20. https://doi.org/10.1007/s00126-019-00870-y
Müller B, Frischknecht R, Seward T, Heinrich C, Camargo Gallegos W (2001) A fluid inclusion reconnaissance study of the Huanuni tin deposit (Bolivia), using LA-ICP-MS micro-analysis. Mineral Deposita 36:680–688. https://doi.org/10.1007/s001260100195
Murakami H, Ishihara S (2013) Trace elements of Indium-bearing sphalerite from tin- polymetallic deposits in Bolivia, China and Japan: a femto-second LA-ICPMS study. Ore Geol Rev 53:223–243. https://doi.org/10.1016/j.oregeorev.2013.01.010
Murciego A, Sanchez AG, Dusausoy Y, Pozas JM, Ruck R (1997) Geochemistry and EPR of cassiterites from the Iberian Hercynian Massif. Mineral Mag 61:357–365. https://doi.org/10.1180/minmag.1997.061.406.03
Nascimento T, Souza V (2017) Mineralogy, stable isotopes (δ18O and δ34S) and 40Ar-39Ar geochronology studies on the hydrothermal carapace of the Igarapé Manteiga W-Sn deposit, Rondônia. Braz J Geol 47:591–613. https://doi.org/10.1590/2317-4889201720170068
Neiva A (2008) Geochemistry of cassiterite and wolframite from tin and tungsten quartz veins in Portugal. Ore Geol Rev 33:221–238. https://doi.org/10.1016/j.oregeorev.2006.05.013
Neymark L, Holm-Denoma C, Moscati R (2018) In situ LA-ICPMS U–Pb dating of cassiterite without a known-age matrix-matched reference material: examples from worldwide tin deposits spanning the Proterozoic to the tertiary. Chem Geol 483:410–425. https://doi.org/10.1016/j.chemgeo.2018.03.008
Nupen S (2019) Mineral resource estimates for the Falchani lithium project in the Puno district of Peru. Prepared for Plateau Energy Metals Inc. under the Guidelines of National Instrument 43-101 and accompanying documents NI 43-101.F1 and NI 43-101.CP. Report No: C-MYI-EXP-1727-1134
Pastor M, Pastor A, Torró L, Martínez A, Artiaga D, Torres B, Tauler E, Melgarejo JC, Paillo F, Arce-Burgoa OR, Alfonso P (2015) The San José-Itos mines, Oruro, Bolivia: structure and Ag-Sn mineralization. Abstracts, 13th SGA Biennial Meeting, Nancy, 1:327–330
Paton C, Woodhead JD, Hellstrom JC, Hergt JM, Greig A, Maas R (2010) Improved laser ablation U-Pb zircon geochronology through robust downhole fractionation correction. Geochem Geophys Geosyst 11:1–36. https://doi.org/10.1029/2009GC002618
Pavlova GG, Palessky SV, Borisenko AS, Vladimirov AG, Seifert T, Phan L (2015) Indium in cassiterite and ores of tin deposits. Ore Geol Rev 66:99–113. https://doi.org/10.1016/j.oregeorev.2014.10.009
Petersen U (1970) Metallogenic provinces in South America. Geol Rundsch 59:834–897. https://doi.org/10.1007/bf02042275
Petrus JA, Kamber BS (2012) VizualAge: a novel approach to laser ablation ICP-MS U-Pb geochronology data reduction. Geostand Geoanal Res 36:247–270. https://doi.org/10.1111/j.1751-908X.2012.00158.x
Picard D, Sempere T, Plantard O (2008) Direction and timing of uplift propagation in the Peruvian Andes deduced from molecular phylogenetics of highland biotaxa. Earth Planet Sc Lett 271:326–336. https://doi.org/10.1016/j.epsl.2008.04.024
Pichavant M, Herrera JV, Boulmier S, Briqueu L, Joron JL, Juteau M, Marin L, Michard A, Sheppard MFS, Treuil M, Vernet M (1987) The Macusani glasses, SE Peru: evidence of chemical fractionation in peraluminous magmas. In: Mysen BO (ed) Magmatic Processes: Physicochemical Principles, vol 1. Geo Soc S P, pp 359–374
Pichavant M, Kontak DJ, Briqueu L, Herrera JV, Clark AH (1988a) The Miocene-Pliocene Macusani Volcanics, SE Peru I. Mineralogy and magmatic evolution of a two-mica aluminosilicate-bearing ignimbrite suite. Contrib Mineral Petrol 100:300–324. https://doi.org/10.1007/BF00379742
Pichavant M, Kontak DJ, Briqueu L, Herrera JV, Clark AH (1988b) The Miocene-Pliocene Macusani Volcanics, SE Peru II. Geochemistry and origin of a felsic peraluminous magma. Contrib Mineral Petrol 100:325–338. https://doi.org/10.1007/BF00379742
Plimer IR, Lu J, Kleeman JD (1991) Trace and rare earth elements in cassiterite - sources of components for the tin deposits of the Mole Granite, Australia. Mineral Deposita 26:267–274. https://doi.org/10.1007/BF00191072
Pollard PJ, Pichavant M, Charoy B (1987) Contrasting evolution of fluorine- and boron-rich tin systems. Mineral Deposita 22:315–321. https://doi.org/10.1007/BF00204525
Poupeau G, Labrin E, Sabil N, Bigazzi G, Arroyo G, Vatin-Pérignon N (1993) Fission-track dating of 15 macusanite glass pebbles from the Macusani volcanic field (SE Peru). Nucl Tracks Radiat Meas 21:499–506. https://doi.org/10.1016/1359-0189(93)90189-G
Pring A, Wade B, McFadden A, Lenehan CE, Cook NJ (2020) Coupled substitutions of minor and trace elements in co-existing sphalerite and wurtzite. Minerals 10:147. https://doi.org/10.3390/min10020147
Rakovan J, McDaniel DK, Reeder RJ (1997) Use of surface-controlled REE sectoral zoning in apatite from Llallagua, Bolivia, to determine a single-crystal SmNd age. Earth Planet Sci Lett 146:329–336. https://doi.org/10.1016/S0012-821X(96)00226-9
Redwood S (1993) The Metallogeny of the Bolivian Andes. Mineral Deposit Research Unit Short Course No. 15 University of British Columbia, Vancouver
Redwood SD, MacIntyre RM (1989) K-Ar dating of Miocene magmatism and related epithermal mineralization of the northeastern Altiplano of Bolivia. Econ Geol 84:618–630. https://doi.org/10.2113/gsecongeo.84.3.618
Reitsma MJ (2012) Reconstructing the Late Paleozoic–Early Mesozoic plutonic and sedimentary record of South-East Peru: orphaned back-arcs along the western margin of Gondwana. PhD thesis Terre & Environment 111. University of Geneva, Switzerland
Revollo R (1967) Geología de la Cordillera de Santa Vera Cruz: Tesis de Grado, Universidad Mayor San Andrés, La Paz
Rivas S, Carrasco R (1968) Geología y yacimientos minerales de la Region de Potosi. Bol Geol Bol 11
Roperch P, Sempere T, Macedo O, Arriagada C, Fornari M, Tapia C, García M, Laj C (2006) Counterclockwise rotation of late Eocene–Oligocene fore-arc deposits in southern Peru and its significance for oroclinal bending in the Central Andes. Tectonics 25:TC3010. https://doi.org/10.1029/2005TC001882
Samson IM, Wood SA (2004) The rare earth elements: behaviour in hydrothermal fluids and concentration in hydrothermal mineral deposits, exclusive of alkaline settings. In: Linnen RL, Samson IM (eds) Rare element geochemistry and mineral deposits. Geological Association of Canada Short Course Notes, vol 17. Geol Assoc Can, pp 269–298
Sandeman HA, Clark AH, Farrar E (1995) An integrated tectono-magmatic model for the evolution of the southern Peruvian Andes (13°-20°S) since 55 Ma. Int Geol Rev 37:1039–1073. https://doi.org/10.1080/00206819509465439
Sandeman HA, Clark AH, Farrar E, Arroyo G (1997) Lithostratigraphy, petrology and 40Ar/39Ar geochronology of the Crucero Supergroup, Puno Department, SE Peru. J S Am Earth Sci 10:223–245. https://doi.org/10.1016/S0895-9811(97)00023-0
Schildgen FT, Hoke DG (2018) The topographic evolution of the Central Andes. Elements 14:231–236. https://doi.org/10.2138/gselements.14.4.231
Schulz KJ, DeYoung JH Jr, Seal RR II, Bradley DC (2017) Critical mineral resources of the United States—economic and environmental geology and prospects for future supply. Geol Surv Prof Pap 1802:797. https://doi.org/10.3133/pp1802
Schwarz-Schampera U, Herzig PM (2002) Indium: geology, mineralogy and economics. Springer, Heidelberg
Sciuba M, Beaudoin G, Makvandi S (2020) Chemical composition of tourmaline in orogenic gold deposits. Miner Deposita, In Press https://doi.org/10.1007/s00126-020-00981-x
Scotese CR (2009) Late Proterozoic plate tectonics and palaeogeography: A tale of two supercontinents, Rodinia and Pannotia. In: Craig J, Thurow J, Thusu B, Whitham A, Abutarruma Y (eds) Global Neoproterozoic Petroleum Systems: The Emerging Potential in North Africa, vol 326. Geological Society, Special Publications, London, pp 67–83
Sempere T (1994) Kimmeridgian? To Paleocene tectonic evolution of Bolivia. In Salfity JA (ed) Cretaceous tectonics in the Andes. Vieweg Publications, Earth Evolution Sciences Monograph Series, Wiesbaden, pp. 168–212
Sempere T (1995) Phanerozoic evolution of Bolivia and adjacent regions. In: Tankard AJ, Suárez R, Welsink HJ (eds) Petroleum Basins of South America. AAPG Mem 62:207–230. https://doi.org/10.1306/M62593C9
Sempere T (2000) Discussion of “sediment accumulation on top of the Andean orogenic wedge: Oligocene to late Miocene basins of the eastern Cordillera, southern Bolivia” (Horton, 1998). Geol Soc Am Bull 112:1752–1755
Sempere T, Hérail G, Oller, Bonhomme MG (1990) Late Oligocene- Early Miocene major tectonic crisis and related basins in Bolivia. Geology 18:946–949. https://doi.org/10.1130/0091-7613(1990)018<0946:LOEMMT>2.3.CO;2
Sempere T, Butler RF, Richards DR, Marshall LG, Sharp W, Swisher CC III (1997) Stratigraphy and chronology of Late Cretaceous – Early Paleogene strata in Bolivia and Northwest Argentina. Geol Soc Am Bull 109:709–727. https://doi.org/10.1130/0016-7606(1997)109%3C0709:SACOUC%3E2.3.CO;2
Sempere T, Carlier G, Soler P, Fornari M, Carlotto V, Jacay J, Arispe O, Néraudeau D, Cárdenas J, Rosas S, Jiménez N (2002) Late Permian–Middle Jurassic lithospheric thinning in Peru and Bolivia, and its bearing on Andean-age tectonics. Tectonophysics 345:153–181. https://doi.org/10.1016/S0040-1951(01)00211-6
Sempere T, Folguera A, Gerbault M (2008) New insights into the Andean evolution: an introduction to contributions from the 6th ISAG symposium (Barcelona, 2005). Tectonophysics 459:1–13. https://doi.org/10.1016/j.tecto.2008.03.011
Serranti S, Ferrini V, Umberto M, Cabri LJ (2002) Trace-element distribution in cassiterite and sulfides from rubané and massive ores of the Corvo deposit, Portugal. Can Mineral 40:815–835. https://doi.org/10.2113/gscanmin.40.3.815
Sillitoe RH (1972) Relation of metal provinces in western America to subduction of oceanic lithosphere. Geol Soc Am Bull 83:813–818. https://doi.org/10.1130/0016-7606
Sillitoe RH (1976) Andean mineralization: a model for the metallogeny of convergent plate margins. Geol Assoc Can Spec Pap 14:59–100
Sillitoe RH, Halls C, Grant JN (1975) Porphyry tin deposits in Bolivia. Econ Geol 70:913–927. https://doi.org/10.2113/gsecongeo.70.5.913
Sillitoe RH, Steele GB, Thompson JFH, Lang JR (1998) Advanced argillic lithocaps in the Bolivian tin-silver belt. Mineral Deposita 33:539–546. https://doi.org/10.1007/s001260050170
Skirrow RG, Huston DL, Mernagh TP, Thorne JP, Dulfer H, Senior AB (2013) Critical commodities for a high-tech world: Australia’s potential to supply global demand. Geoscience Australia, Canberra
Slater ET, Kontak DJ, Mcdonald AM, Fayek M (2020) Origin of a multi-stage epithermal Ag-Zn-Pb-Sn deposit: the Miocene Cortaderas breccia body, Pirquitas mine, NW Argentina. Miner Deposita, in press https://doi.org/10.1007/s00126-020-00976-8
Soler P, Jiménez N (1993) Magmatic constraints upon the evolution of the Bolivian Andes since Late Oligocene times. Extended abstracts, 2nd International Symposium on Andean Geodynamics, Oxford, pp. 447–451
Spikings R, Reitsma MJ, Boekhout F, Mišković A, Ulianov A, Chiaradia M, Gerdes A, Schaltegger U (2016) Characterisation of Triassic rifting in Peru and implications for the early disassembly of western Pangaea. Gondwana Res 35:124–143. https://doi.org/10.1016/j.gr.2016.02.008
Stewart JW, Evernden JF, Snelling NJ (1974) Age determinations from Andean Peru: a reconnaissance survey. Geol Soc Am Bull 85:1107–1116. https://doi.org/10.1130/0016-7606(1974)85%3C1107:ADFAPA%3E2.0.CO;2
Sugaki A, Ueno H, Shimada N, Kitakaze A, Hayashi K, Shima H, Sanjines O, Saavedra M (1981) Geological study on the polymetallic hydrothermal deposits in the Oruro district, Bolivia. Sci Rep Tohoku Univ Series III 15:1–52
Sugaki A, Ueno H, Shimada N, Kusachi I, Kitakaze A, Hayashi K, Kojima S, Sanjines VO (1983) Geological study on the polymetallic ore deposits in the Potosi district, Bolivia. Sci Rep Tohoku Univ Series III 15(3):409–460
Sugaki A, Ueno H, Kitakaze A, Hayashi K, Shimada N, Kusachi I, Sanjunes VO (1985) Geological study on the ore deposits in the La Paz district, Bolivia. Sci Rep Tohoku Univ Series III 16(2):132–198
Sugaki A, Kusachi I, Shimada N (1988a) Granite-series and -type of igneous rocks in the Bolivian Andes and their genetic relation to tin-tungsten mineralization. Min Geol 38:121–130. https://doi.org/10.11456/shigenchishitsu1951.38.121
Sugaki A, Kojima S, Shimada N (1988b) Fluid inclusion studies of the polymetallic hydrothermal ore deposits in Bolivia. Mineral Deposita 23:9–15. https://doi.org/10.1007/BF00204221
Sugaki A, Ueno H, Hayashi K (1990) Sulfur isotope reconnaissance of Bolivian hydrothermal deposits. Min Geol 40:299–312. https://doi.org/10.11456/shigenchishitsu1951.40.299
Sugaki A, Shimada N, Ueno H, Kano S (2003) K–Ar ages of tin-polymetallic mineralization in the Oruro mining district, central Bolivian tin belt. Resour Geol 53:273–282. https://doi.org/10.1111/j.1751-3928.2003.tb00176.x
Sun SS, McDonough WF (1989) Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes. Geol Soc Lond Spec Publ 42:313–345. https://doi.org/10.1144/GSL.SP.1989.042.01.19
Taylor RG (1979) Geology of tin deposits. Elsevier, The Netherlands
Thormann W (1966) Investigaciones preliminares sobre la geotectónica y metalogénesis de la zona Challapata-Caxata. Bol Serv Geol Bolivia 7:118
Tindle AG, Breaks FW (1998) Oxide minerals of the separation rapids rare-element granitic pegmatite group, northwestern Ontario. Can Mineral 36:609–635
Torres B, Melgarejo JC, Torró L, Camprubí A, Castillo-Oliver M, Artiaga D, Campeny M, Tauler E, Jiménez-Franco A, Alfonso P, Arce-Burgoa OR (2019) The Poopó polymetallic epithermal deposit, Bolivia: mineralogy, genetic constraints, and distribution of critical elements. Minerals 9:472. https://doi.org/10.3390/min9080472
Torró L, Melgarejo JC, Gemmrich L, Mollinedo D, Cazorla M, Martínez Á, Pujol-Solà N, Farré de Pablo J, Camprubí A, Artiaga D, Torres B, Alfonso P, Arce-Burgoa OR (2019a) Spatial and temporal controls on the distribution of indium in xenothermal vein deposits: the Huari Huari district, Potosí, Bolivia. Minerals 9:304. https://doi.org/10.3390/min9050304
Torró L, Cazorla M, Melgarejo JC, Camprubí A, Tarrés M, Gemmrich L, Campeny M, Castillo-Oliver M, Artiaga D, Torres B, Martínez A, Molliendo D, Alonso P, Arce-Burgoa OR (2019b) Indium mineralization in the volcanic dome-hosted Ánimas–Chocaya–Siete Suyos polymetallic deposit, Potosí, Bolivia. Minerals 9:604. https://doi.org/10.3390/min9100604
Tshijik Karumb E (2016) The recovery of indium from mining wastes. PhD thesis, Colorado School of Mines
Turneaure FS (1935) The tin deposits of Llallagua, Bolivia. Econ Geol 30:14–60. https://doi.org/10.2113/gsecongeo.30.1.14
Turneaure FS (1971) The Bolivian tin-silver province. Econ Geol 66:215–225. https://doi.org/10.2113/gsecongeo.66.2.215
U.S. Geological Survey (2020) Mineral commodity summaries 2020. U.S. Geological Survey. https://pubs.usgs.gov/periodicals/mcs2020/mcs2020.pdf. Accessed 19 Jun 2020
Vermeesch P (2018) IsoplotR: a free and open toolbox for geochronology. Geosci Front 9:1479–1493. https://doi.org/10.1016/j.gsf.2018.04.001
Wise M, Brown C (2011) Chemical composition of coexisting columbite-group minerals and cassiterite from the Black Mountain pegmatite, Maine. Eur J Mineral 23:817–828. https://doi.org/10.1127/0935-1221/2011/0023-2102
Wörner G, Schildgen TF, Reich M (2018a) The Central Andes: elements of an extreme land. Elements 14:225–230. https://doi.org/10.2138/gselements.14.4.225
Wörner G, Mamani M, Blum-Oeste M (2018b) Magmatism in the Central Andes. Elements 14:237–244. https://doi.org/10.2138/gselements.14.4.237
Zhang DL, Peng JT, Hu RZ, Yuan SD, Zheng DS (2011) The closure of U-Pb system in cassiterite and its reliability for dating. Dizhi Lunping <Geol Rev> 57:549–554 (in Chinese with English abstract)
Zhang R, Lu J, Lehmann B, Li C, Li G, Zhang L, Guo J, Sun W (2017) Combined zircon and cassiterite U–Pb dating of the Piaotang granite-related tungsten–tin deposit, southern Jiangxi tungsten district, China. Ore Geol Rev 82:268–284. https://doi.org/10.1016/j.oregeorev.2016.10.039
Zhang S, Zhang R, Lu J, Ma D, Ding T, Gao S, Zhang Q (2019) Neoproterozoic tin mineralization in South China: geology and cassiterite U–Pb age of the Baotan tin deposit in northern Guangxi. Mineral Deposita 54:1125–1142. https://doi.org/10.1007/s00126-019-00862-y
Zhao Y, Chen S, Huang Y, Zhao J, Xiang T, Chen X (2019) U-Pb ages, O isotope compositions, Raman spectrum, and geochemistry of cassiterites from the Xi’ao copper-tin polymetallic deposit in Gejiu District, Yunnan Province. Minerals 9:212. https://doi.org/10.3390/min9040212
Zoheir B, Lehmann B, Emam A, Radwan A, Zhang R, Bain WM, Steele-MacInnis M, Nolte N (2020) Extreme fractionation and magmatic–hydrothermal transition in the formation of the Abu Dabbab rare-metal granite, Eastern Desert, Egypt. Lithos:352–353. Article 105329. https://doi.org/10.1016/j.lithos.2019.105329
Acknowledgments
This study was economically supported by the Peruvian CONCYTEC-FONDECYT-World Bank project 107-2018-FONDECYT-BM-IADT-AV and the Catalan project 2017-SGR-00707. We gratefully acknowledge Pura Alfonso (Polytechnic University of Catalonia) for providing cassiterite samples from the Llallagua deposit. The Bolivian State Mining Company (Corporación Minera de Bolivia (COMIBOL)) granted its permission to the authors to access the Huanuni mine and to perform the necessary sampling; J.C. Ayaviri, J. Araca, R. Condori, N. Guevara, and all individuals at COMIBOL are cordially thanked for their kind and efficient help during field work. The help and hospitality extended by the miners from mining cooperatives during sampling and field work are most gratefully acknowledged. We appreciate the technical support by Xavier Llovet (CCiT-UB) during the acquisition of EPMA data and by Peter Tollan (ETH) during the acquisition of LA-ICP-MS data. We are grateful to Daniel Kontak, Matthieu Harlaux, and Editor-in-Chief Bernd Lehmann for their constructive comments which significantly improved the manuscript.
Author information
Authors and Affiliations
Corresponding author
Additional information
Editorial handling: B. Lehmann
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Gemmrich, L., Torró, L., Melgarejo, J.C. et al. Trace element composition and U-Pb ages of cassiterite from the Bolivian tin belt. Miner Deposita 56, 1491–1520 (2021). https://doi.org/10.1007/s00126-020-01030-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00126-020-01030-3