Skip to main content
Log in

Rare-metal mineralization potential and petrogenesis of Early Cretaceous I-type granitic rocks in the Lizikeng volcanic basin of Jiangxi Province, South China: evidence from mineralogy, geochemistry, and geochronology

  • Article
  • Published:
Mineralium Deposita Aims and scope Submit manuscript

Abstract

The North Wuyi area is an important metallogenic belt in South China and hosts many Pb–Zn–Ag deposits within the Jurassic–Cretaceous volcanic basins. These deposits are mostly genetically associated with Late Jurassic magmatism. The Cretaceous granitic rocks in the Lizikeng basin, at the eastern part of the North Wuyi area, were investigated for their mineralogical and geochemical characteristics in this study. Three types of granitic rocks, quartz monzonite, granite porphyry, and monzogranite, occur, and zircon U–Pb dating reveals that they all formed during the short period of 133–129 Ma, corresponding to the early Cretaceous volcanic-intrusive activities in South China. The whole-rock geochemistry indicates that all three granitic rocks have I-type affinity. The quartz monzonite and granite porphyry have consistently low whole-rock εNd(t) values of − 10.4 to − 9.6 and zircon εHf(t) values of − 14.2 to − 8.2, and they were likely derived from Proterozoic crustal sources without any significant contribution of mantle-derived material. The monzogranite, which shows also negative but slightly higher εNd(t) and εHf(t) values of − 7.6 to − 7.1 and − 9.3 to − 7.0, respectively, might also be derived from a major Proterozoic crustal source but with some input of mantle magma. The geochemical data show that the monzogranite belongs to tungsten-bearing granite with highly evolved characteristics, and with high Nb and W contents similar to the typical rare-metal and W-bearing granites in South China. A large number of typical hydrothermal rare-metal minerals are identified in the monzogranite, such as W-bearing rutile, niobian rutile, and columbite-group minerals as well as ferberite. The discovery of the early Cretaceous granitic rocks with tungsten mineralization potential indicates that the North Wuyi area is prospective for rare-metal mineralization, which opens a new window for rare-metal prospecting in the volcanic basins, as this type of ore deposit was previously thought to occur in granites from mountain range areas in South China, such as the Nanling Range.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  • Armstrong JT (1995) CITZAF: a package of correction programs for the quantitative electron microbeam X-ray analysis of thick polished materials, thin films, and particles. Microbeam Anal 4:177–200

    Google Scholar 

  • Ballouard C, Poujol M, Boulvais P, Branquet Y, Tartèse R, Vigneresse J (2016) Nb-Ta fractionation in peraluminous granites: a marker of the magmatic-hydrothermal transition. Geology 44:231–234

    Google Scholar 

  • Belkasmi M, Cuney M, Pollard PJ, Bastoul A (2000) Chemistry of the Ta-Nb-Sn-W oxide minerals from the Yichun rare metal granite (SE China): genetic implications and comparison with Moroccan and French Hercynian examples. Mineral Mag 64:507–523

    Google Scholar 

  • Belousova EA, Griffin WL, O'Reilly SY, Fisher NI (2002) Igneous zircon: trace element composition as an indicator of source rock type. Contrib Mineral Petrol 143:602–622

    Google Scholar 

  • Chappell BW, White AJR (1992) I- and S-type granites in the Lachlan Fold Belt. Trans Roy Soc Edinb Earth Sci 83:1–26

    Google Scholar 

  • Chen YX, Zheng YF (2015) Extreme Nb/Ta fractionation in metamorphic titanite from ultrahigh-pressure metagranite. Geochim Cosmochim Acta 150:53–73

    Google Scholar 

  • Chen JF, Foland KA, Xing FM, Xu X, Zhou TX (1991) Magmatism along the southeast margin of the Yangtze block: Precambrian collision of the Yangtze and Cathysia blocks of China. Geology 19:815–818

    Google Scholar 

  • Chen GH, Shu LS, Shu LM, Zhang C, Ouyang YP (2016a) Geological characteristics and mineralization setting of the Zhuxi tungsten (copper) polymetallic deposit in the Eastern Jiangnan Orogen. Sci China Ser D Earth Sci 59:803–823

    Google Scholar 

  • Chen YX, Li H, Sun WD, Ireland T, Tian XF, Hu YB, Yang WB, Chen C, Xu DR (2016b) Generation of Late Mesozoic Qianlishan A2-type granite in Nanling Range, South China: implications for Shizhuyuan W–Sn mineralization and tectonic evolution. Lithos 266–267:435–452

    Google Scholar 

  • Chu NC, Taylor RN, Chavagnac V, Nesbitt RW, Boella RM, Milton JA, German CR, Bayon G, Burton K (2002) Hf isotope ratio analysis using multi-collector inductively coupled plasma mass spectrometry: an evaluation of isobaric interference corrections. J Anal At Spectrom 17:1567–1574

    Google Scholar 

  • Dai YP, Yu XQ, Zhang LC, Cao WT, Zhu YD, Li CL (2014) Geology, isotopes and geochronology of the Caijiaping Pb–Zn deposit in the North Wuyi area, South China: implications for petrogenesis and metallogenesis. Ore Geol Rev 57:116–131

    Google Scholar 

  • Dostal J, Kontak DJ, Gerel O, Gregory Shellnutt J, Fayek M (2015) Cretaceous ongonites (topaz-bearing albite-rich microleucogranites) from Ongon Khairkhan, Central Mongolia: products of extreme magmatic fractionation and pervasive metasomatic fluid: rock interaction. Lithos 236-237:173–189

    Google Scholar 

  • Foster MD (1960) Interpretation of the composition of trioctahedral micas. U S Geol Surv Prof Pap 354-B:11–48

    Google Scholar 

  • Graham J, Morris RC (1973) Tungsten and antimony-substituted rutile. Mineral Mag 39:470–473

    Google Scholar 

  • Harris DC (1988) Mineralogy and geochemistry of the Main Hemlo gold deposit, Hemlo, Ontario, Canada. Geol Surv Res 4:259–270

    Google Scholar 

  • Hu RZ, Zhou MF (2012) Multiple Mesozoic mineralization events in South China—an introduction to the thematic issue. Mineral Deposita 47:579–588

    Google Scholar 

  • Hu RZ, Bi XW, Jiang GH, Chen HW, Peng JT, Qi YQ, Wu LY, Wei WF (2012) Mantle-derived noble gases in ore-forming fluids of the granite-related Yaogangxian tungsten deposit, Southeastern China. Mineral Deposita 47:623–632

    Google Scholar 

  • Huang LC, Jiang SY (2013) Geochronology, geochemistry and petrogenesis of the tungsten-bearing porphyritic granite in the Dahutang tungsten deposit, Jiangxi Province. Acta Petrol Sin 29:4323–4335 in Chinese with English abstract

    Google Scholar 

  • Huang LC, Jiang SY (2014) Highly fractionated S-type granites from the giant Dahutang tungsten deposit in Jiangnan Orogen, Southeast China: geochronology, petrogenesis and their relationship with W-mineralization. Lithos 202(203):207–226

    Google Scholar 

  • Huang ZZ, Lou FS (2002) The geochemistry of Tongboshan volcanic-intrusive complex, northern Wuyishan. Res Sur Environ 23:140–148 in Chinese with English abstract

    Google Scholar 

  • Irber W (1999) The lanthanide tetrad effect and its correlation with K/Rb, Eu/Eu*, Sr/Eu, Y/Ho, and Zr/Hf of evolving peraluminous granite suites. Geochim Cosmochim Acta 63:489–508

    Google Scholar 

  • Jahn B, Wu FY, Capdevila R, Martineau F, Zhao ZH, Wang YX (2001) Highly evolved juvenile granites with tetrad REE patterns: the Woduhe and Baerzhe granites from the Great Xing'an Mountains in NE China. Lithos 59:171–198

    Google Scholar 

  • Jiang SY, Peng NJ, Huang LC, Xu YM, Zhan GL, Dan XH (2015) Geological characteristic and ore genesis of the giant tungsten deposits from the Dahutang ore-concentrated district in northern Jiangxi Province. Acta Petrol Sin 31:639–655 in Chinese with English abstract

    Google Scholar 

  • JXNJGP (Northeastern Jiangxi Geological Party of Jiangxi Province) (2012) 1:100,000 regional geological map of the Lizikeng ore deposit, Jiangxi Province. Unpublished map in Chinese

  • Lan HF, Ling HF, Sun LQ, Wang KX, Ouyang PN, Liu JW, Wang HZ (2016) Study on petrogenesis and uranium mineralization potential of Taojindong granite in southern Zhuguangshan composite pluton. Geol J China Univ 22:12–29 in Chinese with English abstract

    Google Scholar 

  • Lerouge C, Eschamps Y, Piantone P, Gilles C, Breton J (2007) Metal-carrier accessory minerals associated with W ± Sn mineralization, La Châtaigneraie tungsten ore district, Massif Central, France. Can Mineral 45:875–889

    Google Scholar 

  • Li XH, Long WG, Li QL, Liu Y, Zheng YF, Yang YH, Chamberlain KR, Wan DF, Guo CH, Wang XC, Tao H (2010) Penglai zircon megacrysts: a potential new working reference material for microbeam determination of Hf-O isotopes and U-Pb age. Geostand Geoanal Res 34:117–134

    Google Scholar 

  • Li J, Huang XL, He PL, Li WX, Yu Y, Chen LL (2015) In situ analyses of micas in the Yashan granite, South China: constraints on magmatic and hydrothermal evolutions of W and Ta–Nb bearing granites. Ore Geol Rev 65:793–810

    Google Scholar 

  • Liu YS, Hu ZC, Gao S, Günther D, Xu J, Gao CG, Chen HH (2008) In situ analysis of major and trace elements of anhydrous minerals by LA-ICP-MS without applying an internal standard. Chem Geol 257:34–43

    Google Scholar 

  • Liu P, Mao JW, Santosh M, Xu LG, Zhang RQ, Jia LH (2018) The Xiling Sn deposit, eastern Guangdong Province, Southeast China: a new genetic model from 40Ar/39Ar muscovite and U-Pb cassiterite and zircon geochronology. Econ Geol 113:511–530

    Google Scholar 

  • Ludwig KR (2003) User’s manual for Isoplot/Ex version 3.00—a geochronology toolkit for Microsoft Excel. Berkeley Geochronological Center, Special Publication 4: 1–70

  • Mao JW, Pirajno F, Cook N (2011) Mesozoic metallogeny in East China and corresponding geodynamic settings—an introduction to the special issue. Ore Geol Rev 43:1–7

    Google Scholar 

  • Mao JW, Cheng YB, Chen MH, Franco P (2013) Major types and time–space distribution of Mesozoic ore deposits in South China and their geodynamic settings. Mineral Deposita 48:267–294

    Google Scholar 

  • Mao ZH, Liu JJ, Mao JW, Deng J, Zhang F, Meng XY, Xiong BK, Xiang XK, Luo XH (2015) Geochronology and geochemistry of granitoids related to the giant Dahutang tungsten deposit, middle Yangtze River region, China: implications for petrogenesis, geodynamic setting, and mineralization. Gondwana Res 28:816–836

    Google Scholar 

  • Meinhold G (2010) Rutile and its applications in earth sciences. Earth-Sci Rev 102:1–28

    Google Scholar 

  • Michailidis KM (1997) An EPMA and SEM study of niobian-tungstenian rutile from the Fanos aplitic granite, Central Macedonia, Northern Greece. Neues Jb Mineral Monat 12:549–563

    Google Scholar 

  • Miller CF, Stoddard EF (1981) The role of manganese in the paragenesis of magmatic garnet: an example from the old Woman Piute range California. J Geol 89:233–246

    Google Scholar 

  • Müller A, Halls C (2005) Rutile—the tin-tungsten host in the intrusive tourmaline breccia at Wheal Remfry, SW England. In: Mao J, Bierlein FP (eds) Mineral deposit research: meeting the global challenge: proceedings of the eighth biennial SGA meeting Beijing, China, 18–21 August 2005. Springer Berlin Heidelberg, Berlin, pp 441–444

    Google Scholar 

  • Pei RF, Hong DW (1995) The granites of South China and their metallogeny. Episodes 18:77–86

    Google Scholar 

  • Pu W, Gao JF, Zhao KD, Ling HF, Jiang SY (2005) Separation method of Rb-Sr, Sm-Nd using DCTA and HIBA. J Nanjing Univ (Nat Sci) 41:445–450 in Chinese with English abstract

    Google Scholar 

  • Qiu JT, Yu XQ, Wu GG, Liu JG, Xiao MZ (2013) Geochronology of igneous rocks and nappe structures in Lengshuikeng deposit, Jiangxi Province, China. Acta Petrol Sin 29:812–826 in Chinese with English abstract

    Google Scholar 

  • Rice CM, Darke KE, Still JW, Lachowski EE (1998) Tungsten-bearing rutile from the Kori Kollo gold mine, Bolivia. Mineral Mag 62:421–429

    Google Scholar 

  • Rudnick RL, Gao S (2014) 4.1—Composition of the continental crust, treasite on geochemistry, 2nd edn. Elsevier, Oxford, pp 1–51

    Google Scholar 

  • Schiano P, Monzier M, Eissen JP, Martin H, Koga KT (2010) Simple mixing as the major control of the evolution of volcanic suites in the Ecuadorian Andes. Contrib Mineral Petrol 160:297–312

    Google Scholar 

  • Shen WZ, Wang DZ, Liu CS (1995) Isotope geochemical characteristics and material sources of tin-bearing porphyries in South China. Acta Geol Sin 69:349–359 in Chinese with English abstract

    Google Scholar 

  • Shu XJ, Wang XL, Sun T, Chen WF, Shen WZ (2013) Crustal formation in the Nanling Range, South China Block: Hf isotope evidence of zircons from Phanerozoic granitoids. J Asian Earth Sci 74:210–224

    Google Scholar 

  • Sláma J, Košler J, Condon DJ, Crowley JL, Gerdes A, Hanchar JM, Horstwood MSA, Morris GA, Nasdala L, Norberg N (2008) Plešovice zircon—a new natural reference material for U–Pb and Hf isotopic microanalysis. Chem Geol 249:1–35

    Google Scholar 

  • Srivastava PK, Sinha AK (1997) Geochemical characterization of tungsten-bearing granites from Rajasthan, India. J Geochem Explor 60:173–184

    Google Scholar 

  • Stepanov A, Mavrogenes JA, Meffre S, Davidson P (2014) The key role of mica during igneous concentration of tantalum. Contrib Mineral Petrol 167:1009

    Google Scholar 

  • Su HM, Jiang SY (2017) A comparison study of tungsten-bearing granite and related mineralization in the northern Jiangxi–southern Anhui provinces and southern Jiangxi Province in South China. Sci China Ser D Earth Sci 60:1942–1958

    Google Scholar 

  • Su HM, Mao JW, He XR, Lu R (2013) Timing of the formation of the Tianhuashan Basin in northern Wuyi as constrained by geochronology of volcanic and plutonic rocks. Sci China Ser D Earth Sci 56:940–955

    Google Scholar 

  • Su HM, Mao JW, Santosh M, Xie GQ (2014) Petrogenesis and tectonic significance of Late Jurassic–Early Cretaceous volcanic-intrusive complex in the Tianhuashan basin, South China. Ore Geol Rev 56:566–583

    Google Scholar 

  • Sun SS, McDonough WF (1989) Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes. Geol Soc Lond, Spec Publ 42:313–345

    Google Scholar 

  • Tappert MC, Rivard B, Giles D, Tappert R, Mauger A (2013) The mineral chemistry, near-infrared, and mid-infrared reflectance spectroscopy of phengite from the Olympic Dam IOCG deposit, South Australia. Ore Geol Rev 53:26–38

    Google Scholar 

  • Taylor SR, McLennan SM (1985) The continental crust: its composition and evolution. Blackwell Scientific Publications, pp. 1–312

  • Wang CM, Zhang D, Wu GG, Xu YG, Carranza EJM, Zhang YY, Li HK, Geng JZ (2013) Zircon U–Pb geochronology and geochemistry of rhyolitic tuff, granite porphyry and syenogranite in the Lengshuikeng ore district, SE China: implications for a continental arc to intra-arc rift setting. J Earth Syst Sci 122:809–830

    Google Scholar 

  • Wang CM, Zhang D, Wu GG, Santosh M, Zhang J, Xu YG, Zhang YY (2014a) Geological and isotopic evidence for magmatic-hydrothermal origin of the Ag–Pb–Zn deposits in the Lengshuikeng District, east-central China. Mineral Deposita 49:733–749

    Google Scholar 

  • Wang XL, Zhou JC, Griffin WL, Zhao GC, Yu JH, Qiu JS, Zhang YJ, Xing GF (2014b) Geochemical zonation across a Neoproterozoic orogenic belt: isotopic evidence from granitoids and metasedimentary rocks of the Jiangnan orogen, China. Precambrian Res 242:154–171

    Google Scholar 

  • Wang XG, Liu ZQ, Liu SB, Wang CH, Liu JG, Wan HZ, Chen GH, Zhang SD, Liu XL (2015) LA-ICP-MS zircon U-Pb dating and petrologic geochemistry of fine-grained granite from Zhuxi Cu-W deposit, Jiangxi Province and its geological significance. Rock Miner Anal 34:592–599 in Chinese with English abstract

    Google Scholar 

  • Whalen JB, Currie KL, Chappell BW (1987) A-type granites: geochemical characteristics, discrimination and petrogenesis. Contrib Mineral Petrol 95:407–419

    Google Scholar 

  • Wiedenbeck M, Allé P, Corfu F, Griffin WL, Meier M, Oberli F, Von Quadt A, Roddick JC, Spiegel W (1995) Three nature zircon standards for U-Th-Pb, Lu-Hf, trace element and REE analyses. Geostand Newslett 19:1–23

    Google Scholar 

  • Wu FY, Sun DY, Li HM, Jahn B, Wilde S (2002) A-type granites in northeastern China: age and geochemical constraints on their petrogenesis. Chem Geol 187:143–173

    Google Scholar 

  • Xie L, Wang RC, Zhu JC, Lu JJ, Zhang WL, Che XD, Zhang RQ, Huang FF (2013) Felsic dykes in the metallogenic area of Southern Hunan Province and their implications for mineralization and exploration. Acta Petrol Sin 29:4261–4280 in Chinese with English abstract

    Google Scholar 

  • Xu P, Wu FY, Xie LW, Yang YH (2004) Hf isotopic compositions of the standard zircons for U-Pb dating. Chin Sci Bull 49:1642–1648

    Google Scholar 

  • Xu XB, Zhang YQ, Jia D, Shu LS, Wang RR (2009) Early Mesozoic geotectonic processes in South China. Geol China 36:573–593 in Chinese with English abstract

    Google Scholar 

  • Xu QS, Wei YW, Huang AJ, Luo P, Wu CL, Zhao HS, Di YJ (2014) Geochemical features, zircon U-Pb ages and relationship to Pb-Zn mineralization of the subvolcanic rocks in Lizikeng volcanic basin, Shangrao, Jiangxi. Geol Rev 60:932–944 in Chinese with English abstract

    Google Scholar 

  • Zhang RQ, Lu JJ, Wang RC, Yao Y, Ding TP, Hu JB, Zhang HF (2016) Petrogenesis of W-and Sn-bearing granites and the mechanism of their metallogenic diversity in the Wangxianling area, southern Hunan Province. Geochimica 45:105–132 in Chinese with English abstract

    Google Scholar 

  • Zhao GC, Cawood PA (2012) Precambrian geology of China. Precambrian Res 222(223):13–54

    Google Scholar 

  • Zhou MF, Ma Y, Yan D, Xia X, Zhao J, Sun M (2006) The Yanbian Terrane (Southern Sichuan Province, SW China): a Neoproterozoic arc assemblage in the western margin of the Yangtze Block. Precambrian Res 144:19–38

    Google Scholar 

  • Zhou J, Ge WY, Jiang YH, Xu SF, Fu JZ (2015) Petrochemistry and mineralogy of Dongyuan tungsten-bearing pluton in eastern Jiangnan Orogen. Geochemica 44:117–130 in Chinese with English abstract

    Google Scholar 

  • Zuo LY, Hou ZQ, Meng XJ, Yang ZM, Song YC, Li Z (2010) SHRIMP U-Pb zircon geochronology of the ore-bearing rock in the Lengshuikeng porphyry type Ag-Pb-Zn deposit. Geol China 37:1450–1456 in Chinese with English abstract

    Google Scholar 

Download references

Acknowledgments

Thanks are given to Linhai Hong from Northeastern Jiangxi Geological Survey for assistance with the field work. This study was financially supported by projects from the National Key R&D Program of China (no. 2017YFC0602405), the National Natural Science Foundation of China (No. 41503019), and the MOST Special Fund from the State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences (No. MSFGPMR03-2). We thank Prof. Mao Jingwen, Prof. Hu Ruizhong, two anonymous reviewers, and chief editor Prof. Bernd Lehmann for their valuable suggestions that helped to improve this manuscript significantly.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Shao-Yong Jiang.

Additional information

Editorial handling: R. Hu

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

ESM 1

(PDF 843 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Su, HM., Jiang, SY., Cao, MY. et al. Rare-metal mineralization potential and petrogenesis of Early Cretaceous I-type granitic rocks in the Lizikeng volcanic basin of Jiangxi Province, South China: evidence from mineralogy, geochemistry, and geochronology. Miner Deposita 55, 453–468 (2020). https://doi.org/10.1007/s00126-019-00894-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00126-019-00894-4

Keywords

Navigation