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Effects of Cr and Cooling Rate on Segregation and Refinement of Primary Si in Al-20 WT %Si Alloy

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Abstract

The effect of Cr on segregation and refinement of primary Si in Al-20 wt %Si alloy under a different cooling rate was investigated with a wedge-shaped mould. In addition, the effects of P and a combination of P and Cr on Al-20 wt %Si were also studied. Thermal analysis techniques were used to calculate the cooling rate in the solidification range. The microstructures were examined by optical microscope and scanning electron microscope. The results showed that the segregation of primary Si exists in the castings. The optimal pouring temperature was 850°C (1562°F) with a range of 800–900°C (1472–1652°F). Segregation of primary Si could be inhibited with the addition of refiners and increasing cooling rate. The CrSi2 particles adhered to primary Si particles further reduced the segregation. The primary Si particles were well refined by Cr, P or a combination of P and Cr for CrSi2 and AlP served as heterogeneous nucleus for primary Si, but P had a better refinement effect than Cr. A combination of P and Cr into the melt improved the P refinement effect and substantially inhibited the segregation of primary Si.

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References

  1. Yoon, H., Sheiretov T., C. Cusano, C., “Scuffing Behavior of 390 Aluminum Against Steel Under Starved Lubrication Conditions,” Wear, vol. 237, pp. 163–175 (2000).

    Article  Google Scholar 

  2. Lasa, L., Rodriguez-Ibabe, J.M., “Wear Behaviour of Eutectic and Hypereutectic Al-Si-Cu-Mg Casting Alloys Tested Against a Composite Brake Pad,” Mater. Sci. Eng. A., vol. 363, pp. 193–202 (2003).

    Article  Google Scholar 

  3. Jorstad, J., Apelian, D., “Hypereutectic Al-Si alloys: Practical Casting Considerations,” Int. J. Metalcast., vol. 3, pp. 13–36 (2009).

    Article  Google Scholar 

  4. Timmermans, G., Froyen, L., “Fretting Wear Behaviour of Hypereutectic P/M Al-Si in Oil Environment,” Wear, vol. 230, pp. 105–117 (1999).

    Article  Google Scholar 

  5. Delshad-Khatibi, P., Akhlaghi, F., “Ultrafine Primary Silicon Particles in P-Refined Hypereutectic Al-Si Alloy Powders Produced by SAMD Method,” Int. J. Mod Phys B, vol. 22, pp. 3304–3310 (2008).

    Article  Google Scholar 

  6. Yu, J.B., Ren, Z.M., Deng, K., “Refinement and Migrating Behaviors in Al-Si Hypereutectic Alloys Solidified Under Electromagnetic Vibration,” Acta Metall. Sinica (Eng. Lett.), vol. 24, issue 4, pp. 301–308 (2011).

    Google Scholar 

  7. Chen, C.M., Yang, C.C., Chao, C.G., “A Novel Method for Net-Shape Forming of Hypereutectic Al-Si Alloys by Thixocasting with Powder Performs,” J. Mater. Process. Technol., vol. 167, pp. 103–109 (2005).

    Article  Google Scholar 

  8. Mahanti, R.K., Lal, K., Sinha, A.N., Sivaramakrishnan, C.S., “Novel Technique for Hyper Eutectic Aluminum-Silicon Alloy Melt Treatment,” Mater. Trans. JIM, vol. 34, pp, 1207–1211 (1993).

    Article  Google Scholar 

  9. Liang, D., Bayraktar, Y., Moir, S.A., Barkhudarov, M., Jones, H., “Primary Silicon Segregation During Isothermal Holding of Hypereutectic Al-18.3wt% Si Alloy in the Freezing Range,” Scr. Metall. Mater, vol. 31, pp. 363–367 (1994).

    Article  Google Scholar 

  10. Donahue, R.J., Hesterberg, W.G., Cleary, T.M., WO Patent No. 199012899 (Nov. 01, 1990).

  11. Eady, J.A., Heathcock, C.J., Kean, P.L., Rogers, K.P., Legge, R.A., U.S. Patent No. 5217546 (Jun. 8, 1993).

  12. Leatham, A., “Spray Forming-Alloys, Products and Markets,” Metal Powder Report, vol. 54, pp. 28–37 (1999).

    Google Scholar 

  13. Wang, W.M., Bian, X.F., Qin, J.Y., Syliusarenko, S.I., “The Atomic-Structure Changes in Al-16 pct Si Alloy Above the Liquidus,” Metall. Mater. Trans. A., vol. 31, issue 9, pp. 2163–2168 (2000).

    Article  Google Scholar 

  14. Cui, C., Schulz, A., Schimanski, K., Zoch, H.W., “Spray Forming of Hypereutectic Al-Si Alloys,” J. Mater. Process. Technol., vol. 209, pp. 5220–5228 (2009).

    Article  Google Scholar 

  15. Rooy, E.L., “Summary of Technical Information on Hypereutectic Al-Si Alloys,” AFS Trans., vol. 80, pp. 421–426 (1972).

    Google Scholar 

  16. Anuradee, T., Mawin, S., Umeda, T., Nagaumi, H., Qin, K., Cui, J.Z., “Grain Refinement of Primary Si in Continuously Cast Hypereutectic Al-Si Alloy by Electromagnetic Vibration,” Int. J. Cast Met. Res., vol. 21, pp 198–202 (2008).

    Article  Google Scholar 

  17. Srivastava, V.C., R.K. Mandal, R.K., Ojha, S.N., “Evolution of Microstructure in Spray Formed Al-18%Si Alloy,” Mater. Sci. Eng. A., vol. 383, pp. 14–20 (2004).

    Article  Google Scholar 

  18. Li, P.J., Nikitin, V.I., Kandalova, E.G., Nikitin, K.V., “Effect of Melt Overheating, Cooling and Solidification Rates on Al-16wt%Si Alloy Structure,” Mater. Sci. Eng. A., vol. 332, pp. 371–374 (2002).

    Article  Google Scholar 

  19. Liang, D., Bayraktar, Y., Jones, H., “Formation and Segregation of Primary Silicon in Bridgman Solidified Al-18.3 Wt % Si Alloy,” Acta Metall. Mater., vol. 43, pp. 579–585 (1995).

    Article  Google Scholar 

  20. Eltilib, R.A.E.E., Kayiem, H.H.A., Jaafar, A., “Investigation on The Particle Settling Velocity in Non-Newtonian Fluids,” J. Appl. Sci., vol. 11, pp. 1528–1535 (2011).

    Article  Google Scholar 

  21. Xu, C.L., Jiang, Q.C., “Morphologies of Primary Silicon in Hypereutectic Al-Si Alloys with Melt Overheating Temperature and Cooling Rate,” Mater. Sci. Eng. A., vol. 437, pp. 451–455 (2006).

    Article  Google Scholar 

  22. Filonenko, O., Falke, M., Hortenbach, H., Henning, A., Beddies, G., Hinneberg, H. J., “Structure of Thin CrSi2 Films on Si(001),” Appl. Surf. Sci., vol. 227, pp. 341–348 (2004).

    Article  Google Scholar 

  23. Vantomme, A., Nicolet, M.A., Long, R.G., Mahan, J.E., “Reactive Deposition Epitaxy of CrSi2,” Appl. Surf. Sci., vol. 73, pp. 146–152 (1993).

    Article  Google Scholar 

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Zuo, K.S., Zhang, H.T., Han, X. et al. Effects of Cr and Cooling Rate on Segregation and Refinement of Primary Si in Al-20 WT %Si Alloy. Inter Metalcast 8, 55–62 (2014). https://doi.org/10.1007/BF03355595

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