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Enhanced Dispersion of Graphene Nanoplatelets in Cementitious Materials with an Improved Stirring and Mixing Approach

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Proceedings of the 6th International Conference on Smart Monitoring, Assessment and Rehabilitation of Civil Structures (SMAR 2021)

Part of the book series: Lecture Notes in Civil Engineering ((LNCE,volume 259))

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Abstract

Carbon nano additives (CNA) enable the development of functionalized cement composites. However, a homogeneous dispersion of CNA in cement composites is always a challenging task. Herein, a practical stirring and mixing scheme was developed to promote the dispersion of CNA in cement composites. As an example, graphene nanoplatelets (GNP) was selected as a presentative CNA and incorporated into the cement with three different stirring methods and two different mixing schemes. The dispersion efficiency was measured by UV–Vis tests. The micro-structure of the cement composites with GNP prepared by different stirring and mixing schemes was characterized by scanning Electron Microscope (SEM). Mercury intrusion porosimetry (MIP) was employed to measure the pore size distributions (PSDs). The results showed that GNP in water and cement suspension can be homogeneously dispersed under direct ultrasonic stirrings (DUS) than indirect ultrasonic stirrings (IUS). The combined use of DUS and the spraying mixing method can greatly reduce the GNP agglomerations in the cement matrix. The improved stirring and mixing method enhanced compactness for the GNP-modified cement composites. This research provides an effective and practical dispersion scheme of CNA in cement-based materials with promising applicability to the development of advanced building materials.

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References

  1. Han B, Yu X, Ou J (2014) Self-sensing concrete in smart structures. Butterworth-Heinemann

    Google Scholar 

  2. Gardner D, Lark R, Jefferson T, Davies R (2018) A survey on problems encountered in current concrete construction and the potential benefits of self-healing cementitious materials. Case Stud Constr Mater 8:238–247

    Google Scholar 

  3. Al-Tabbaa A, Litina C, Giannaros P, Kanellopoulos A, Souza L (2019) First UK field application and performance of microcapsule-based self-healing concrete. Constr Build Mater 208:669–685

    Google Scholar 

  4. Papanikolaou I (2020) Multi-functional applications of graphene related materials in cementitious composites. University of Cambridge

    Google Scholar 

  5. Geim AK, Novoselov KS (2007) The rise of graphene. Nat. Mater 6:183–191

    Google Scholar 

  6. Novoselov KS, et al. (2012) A roadmap for graphene. Nature 490:192–200

    Google Scholar 

  7. Zhang Q, Sun H, Liu W, Zhou Z, Yuan L, Ren Z et al (2021) Effect of rGO on the mechanical strength, hydration, and micromorphology of cement incorporated silica fume. Constr Build Mater 300:124325

    Article  Google Scholar 

  8. Du M, Jing H, Gao Y, Su H, Fang H (2020) Carbon nanomaterials enhanced cement-based composites: advances and challenges. Nanotechnol Rev 9:115–135

    Google Scholar 

  9. Texter J (2014) Graphene dispersions. Curr Opin Colloid Interface Sci 19:163–174

    Google Scholar 

  10. Mehmood A, Mubarak NM, Khalid M et al (2020) Graphene-based nanomaterials for strain sensor application a-review. J Environ Chem Eng 8(3):103743

    Google Scholar 

  11. Sika Services AG, Sika ViscoCrete ( 2009) Technology, ZĂĽrich

    Google Scholar 

  12. Sabziparvar AM, Hosseini E, Chiniforush V, Korayem AH (2019) Barriers to achieving highly dispersed graphene oxide in cementitious composites: an experimental and computational study. Constr Build Mater 199:269–278

    Google Scholar 

  13. Tao J, Wang X, Wang Z, Zeng Q (2019) Graphene nanoplatelets as an effective additive to tune the microstructures and piezoresistive properties of cement-based composites. Constr Build Mater 209:665–678

    Article  Google Scholar 

  14. Zhang B, Chen T (2019) Study of ultrasonic dispersion of graphene nanoplatelets. Materials 12(11):1757

    Article  Google Scholar 

  15. Muthoosamy K, Manickam S (2017) State of the art and recent advances in the ultrasonic-assisted synthesis, exfoliation, and functionalization of graphene derivatives. Ultrason Sonochem 39:478–493

    Article  Google Scholar 

  16. Konsta-Gdoutos MS, Metaxa ZS, Shah SP (2010) Highly dispersed carbon nanotube reinforced cement-based materials. Cem Concr Res 40(7):1052–1059

    Article  Google Scholar 

  17. Papanikolaou I, de Souza LR, Litina C, Al-Tabbaa A (2021) Investigation of the dispersion of multi-layer graphene nanoplatelets in cement composites using different superplasticiser treatments. Constr Build Mater 293:123543

    Article  Google Scholar 

  18. Al-Dahawi A, Öztürk O, Emami F, Yıldırım G, Şahmaran M (2016) Effect of mixing methods on the electrical properties of cementitious composites incorporating different carbon-based materials. Constr Build Mater 104:160–168

    Article  Google Scholar 

  19. Dang N, Tao J, Zeng Q, Zhao W (2021) May the piezoresistivity of GNP-modified cement mortar be related to its fractal structure? Fractal Fractional 5(4):148

    Article  Google Scholar 

  20. Ozbulut OE, Jiang Z, Harris DK (2018) Exploring scalable fabrication of self-sensing cementitious composites with graphene nanoplatelets. Smart Mater Struct 27(11):115029

    Article  Google Scholar 

  21. Zhu X, Kang X (2020) Effect of graphene oxide (GO) on the hydration and dissolution of the elite in a synthetic cement system. J Mater Sci 55(8):3419–3433

    Article  Google Scholar 

  22. Dong W, Li W, Wang K, Shah SP (2021) Physicochemical and Piezoresistive properties of smart cementitious composites with graphene nanoplates and graphite plates. Constr Build Mater 286:122943

    Article  Google Scholar 

  23. Haeri SZ, Ramezanzadeh B, Asghari M (2017) A novel fabrication of a high performance SiO2-graphene oxide (GO) nanohybrids: characterization of thermal properties of epoxy nanocomposites filled with SiO2-GO nanohybrids. J Colloid Interface Sci 493:111–122

    Article  Google Scholar 

  24. Lu Z, Hou D, Hanif A, Hao W, Li Z, Sun G (2018) Comparative evaluation on the dispersion and stability of graphene oxide in water and cement pore solution by incorporating silica fume. Cement Concr Compos 94:33–42

    Article  Google Scholar 

  25. Pan Z, He L, Qiu L, Korayem AH, Li G, Zhu et al (2015) Mechanical properties and microstructure of a graphene oxide–cement composite. Cement Concr Compos 58:140–147

    Article  Google Scholar 

  26. Lv S, Liu J, Sun T, Ma Y, Zhou Q (2014) Effect of GO nanosheets on shapes of cement hydration crystals and their formation process. Constr Build Mater 64:231–239

    Article  Google Scholar 

  27. Lv S, Ma Y, Qiu C, Zhou Q (2013) Regulation of GO on cement hydration crystals and its toughening effect. Mag Concr Res 65(20):1246–1254

    Article  Google Scholar 

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Correspondence to Qiang. Zeng .

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Dang, N., Zhao, W., Zeng, Q. (2024). Enhanced Dispersion of Graphene Nanoplatelets in Cementitious Materials with an Improved Stirring and Mixing Approach. In: Gu, XL., Motavalli, M., Ilki, A., Yu, QQ. (eds) Proceedings of the 6th International Conference on Smart Monitoring, Assessment and Rehabilitation of Civil Structures. SMAR 2021. Lecture Notes in Civil Engineering, vol 259. Springer, Singapore. https://doi.org/10.1007/978-981-99-3362-4_24

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  • DOI: https://doi.org/10.1007/978-981-99-3362-4_24

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  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-99-3361-7

  • Online ISBN: 978-981-99-3362-4

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