Abstract
The accumulation of various contaminants in water has become a threatening environmental issue, affecting all living creatures. Owing to this fact, mitigating water contamination problems by improving existing technologies and developing potential strategies has become an emerging area of research. Among several approaches for water treatment, adsorption has been attractive since it has unique advantages due to the use of natural and synthetic materials. As a natural adsorbent material, clay minerals are considered superior materials owing to their wide availability, low cost, excellent adsorption performance and cation exchangeability. To enhance the surface properties toward the removal of water pollutants, natural clays are subjected to various modifications. The surfactant-modified clay composites can remove a variety of pollutants than other composites due to the sorption of surfactant onto the external surface and interlayer spacing of clay minerals. This chapter encloses the application of surfactant-modified clay towards the removal of pollutants from water.
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References
Abdel Ghafar, H.H., et al.: Removal of hazardous contaminants from water by natural and Zwitterionic surfactant-modified clay. ACS Omega 5(12), 6834–6845 (2020). https://pubs.acs.org/doi/10.1021/acsomega.0c00166
Ahmad, N., et al.: Visible light-conducting polymer nanocomposites as efficient photocatalysts for the treatment of organic pollutants in wastewater. J. Environ. Manag. 295(June), 113362 (2021). https://doi.org/10.1016/j.jenvman.2021.113362
Almasoud, N., et at.: A solid phase extraction based UPLC-ESI-MS/MS method using surfactant-modified clay as extraction sorbent for the removal and determination of rhodamine B in industrial wastewater samples. Desalin. Water Treat. 195, 222–231 (2020). https://doi.org/10.5004/dwt.2020.25896
Barakan, S., Aghazadeh, V.: The advantages of clay mineral modification methods for enhancing adsorption efficiency in wastewater treatment: a review. Environ. Sci. Pollut. Res. (Atia 2005) (2020)
Belachew, N., Hinsene, H.: Preparation of cationic surfactant-modified kaolin for enhanced adsorption of hexavalent chromium from aqueous solution. Appl. Water Sci., 1–8 (2020). https://doi.org/10.1007/s13201-019-1121-7
Choi, N., et al.: Adsorption behaviors of modified clays prepared with structurally different surfactants for anionic dyes removal 28(2), 0–3 (2023)
Dai, W.J., et al.: Adsorption of polycyclic aromatic hydrocarbons from aqueous solution by organic montmorillonite sodium alginate nanocomposites. Chemosphere 251, 126074 (2020). https://doi.org/10.1016/j.chemosphere.2020.126074
Deng, L., et al.: Dynamic benzene adsorption performance of microporous TMA+-exchanged montmorillonite: the role of TMA+ cations. Microporous Mesoporous Mater. 296(December 2019) (2020). https://doi.org/10.1016/j.micromeso.2019.109994
Hedayati, M.S., et al.: Removal of polycyclic aromatic hydrocarbons from aqueous media using modified clinoptilolite. J. Environ. Manag. 273(March), 111113Â (2020). https://doi.org/10.1016/j.jenvman.2020.111113
Hedayati, M.S., Abida, O., Li, L.Y.: Adsorption of polycyclic aromatic hydrocarbons by surfactant-modified clinoptilolites for landfill leachate treatment. Waste Manag. 131(November 2020), 503–512 (2021)https://doi.org/10.1016/j.wasman.2021.06.033
Jiang, J.Q., Ashekuzzaman, S.M.: Development of novel inorganic adsorbent for water treatment. Curr. Opin. Chem. Eng. 1(2), 191–199 (2012).https://doi.org/10.1016/j.coche.2012.03.008
Kausar, A., et al.: Dyes adsorption using clay and modified clay: a review. J. Mol. Liq. 256, 395–407 (2018). https://doi.org/10.1016/j.molliq.2018.02.034
Krishna, B.S., et al.: Surfactant-modified clay as adsorbent for chromate. Appl. Clay Sci. 20(1–2), 65–71 (2001). https://doi.org/10.1016/s0169-1317(01)00039-4
Lazaratou, C.V., Vayenas, D.V., Papoulis, D.: The role of clays, clay minerals and clay-based materials for nitrate removal from water systems: a review. Appl. Clay Sci. 185(June), 105377 (2020). https://doi.org/10.1016/j.clay.2019.105377
Lin, S., Juang, R.: 1-s2.0-S0304389402000262-main, vol. 92, pp. 315–326 (2002)
Luo, W., et al.: Journal of Water Process Engineering Lanthanum/Gemini surfactant-modi fi ed montmorillonite for simultaneous removal of phosphate and nitrate from aqueous solution. J. Water Process Eng. 33(July 2019), 101036 (2020). https://doi.org/10.1016/j.jwpe.2019.101036
Malakul, P., Srinivasan, K.R., Wang, H.Y.: Metal adsorption and desorption characteristics of surfactant-modified clay complexes. Ind. Eng. Chem. Res. 37(11), 4296–4301 (1998). https://doi.org/10.1021/ie980057i
Mao, S., Gao, M.: Functional organoclays for removal of heavy metal ions from water: a review. J. Mol. Liq. 334, 116143 (2021). https://doi.org/10.1016/j.molliq.2021.116143
Mudzielwana, R., Gitari, M.W., Ndungu, P.: Performance evaluation of surfactant modified kaolin clay in As(III) and As(V) adsorption from groundwater: adsorption kinetics, isotherms and thermodynamics. Heliyon 5(11), e02756 (2019). https://doi.org/10.1016/j.heliyon.2019.e02756
Mukhopadhyay, R., et al.: Comparison of properties and aquatic arsenic removal potentials of organically modified smectite adsorbents. J. Hazard. Mater. 377, 124–131 (2019). https://doi.org/10.1016/j.jhazmat.2019.05.053
Mundkur, N., et al.: Environmental Nanotechnology, Monitoring & Management Synthesis and characterization of clay-based adsorbents modified with alginate, surfactants, and nanoparticles for methylene blue removal. Environ. Nanotechnol. Monitor. Manag. 17(September 2021), 100644 (2022). https://doi.org/10.1016/j.enmm.2022.100644
Munir, M., et al.: Effective adsorptive removal of methylene blue from water by didodecyldimethylammonium bromide-modified brown clay. ACS Omega 5(27), 16711–16721 (2020). https://pubs.acs.org/doi/10.1021/acsomega.0c01613
Mustapha, S., et al.: Application of TiO2 and ZnO nanoparticles immobilized on clay in wastewater treatment: a review. Appl. Water Sci. (2020)https://doi.org/10.1007/s13201-019-1138-y
Najafi, H., et al.: A comprehensive study on modified-pillared clays as an adsorbent in wastewater treatment processes. Process Saf. Environ. Prot. 147, 8–36 (2021). https://doi.org/10.1016/j.psep.2020.09.028
Nasrollahpour, S., et al.: Application of organically modified clay in removing BTEX from produced water. In: Geo-Congress 2020 GSP, vol. 319, pp. 275–283 (2020)
Nassar, M.Y., et al.: Adsorptive removal of manganese ions from polluted aqueous media by glauconite clay—Functionalized chitosan nanocomposites. J. Inorg. Organomet. Polym. Mater. (Ii) (2021). https://doi.org/10.1007/s10904-021-02028-8
Onwuka, K., et al.: Hexadecyltrimethyl ammonium (HDTMA) and trimethylphenyl ammonium (TMPA) cations intercalation of Nigerian bentonite clay for multi-component adsorption of benzene, toluene, ethylbenzene and xylene (BTEX) from aqueous solution: equilibrium and kinetic stud. J. Anal. Tech. Res. 02(02), 70–95 (2020). https://doi.org/10.26502/jatri.013
Oussalah, A., Boukerroui, A.: Removal of cationic dye using alginate–organobentonite composite beads. Euro-Mediterr. J. Environ. Integr. 3, 1–10 (2020). https://doi.org/10.1007/s41207-020-00199-3
Rahmani, S., et al.: Removal of cationic methylene blue dye using magnetic and anionic-cationic modified montmorillonite: kinetic isotherm and thermodynamic studies. Appl. Clay Sci. 184(July 2019), 105391Â (2020). https://doi.org/10.1016/j.clay.2019.105391
Ren, S., et al.: Comparison of Cd2+ adsorption onto amphoteric, amphoteric-cationic and amphoteric-anionic modified magnetic bentonites. ECSN, p. 124840 (2019). https://doi.org/10.1016/j.chemosphere.2019.124840
Satouh, S., et al.: Adsorption of polycyclic aromatic hydrocarbons by natural, synthetic and modified clays. Environ.—MDPI 8(11) (2021). https://www.mdpi.com/2076-3298/8/11/124
Tamjidi, S., et al.: Improving the surface properties of adsorbents by surfactants and their role in the removal of toxic metals from wastewater: a review study. Process Saf. Environ. Prot. 148, 775–795 (2021). https://doi.org/10.1016/j.psep.2021.02.003
Tohdee, K., Kaewsichan, L., Asadullah: Enhancement of adsorption efficiency of heavy metal Cu(II) and Zn(II) onto cationic surfactant modified bentonite. J. Environ. Chem. Eng. 6(2), 2821–2828 (2018). https://doi.org/10.1016/j.jece.2018.04.030
Wang, H., et al.: Colloids and Surfaces A: Physicochemical and Engineering Aspects Cationic surfactant modified attapulgite for removal of phenol from wastewater. Colloids Surf. A Physicochem. Eng. Aspects 641(February), 128479 (2022). https://doi.org/10.1016/j.colsurfa.2022.128479
Wasewar, K.L., et al.: Process intensification of treatment of inorganic water pollutants. In: Inorganic Pollutants in Water. INC (2020). https://doi.org/10.1016/B978-0-12-818965-8.00013-5
Xiao, T., et al.: Colloids and Surfaces A: Physicochemical and Engineering Aspects Adsorption of tungstate using cationic Gemini surfactant-modified montmorillonite: influence of alkyl chain length. Colloids Surf. A Physicochem. Eng. Aspects. 629(September), p. 127484 (2021). https://doi.org/10.1016/j.colsurfa.2021.127484
Zhang, T., et al.: Removal of heavy metals and dyes by clay-based adsorbents: from natural clays to 1D and 2D nano-. Chem. Eng. J., 127574 (2020). https://doi.org/10.1016/j.cej.2020.127574
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Perera, M.D.R., Amarasena, R.A.L.R., Bandara, W.M.A.T., Weerasooriya, R., Jayarathna, L. (2023). Surfactant-Modified Clay Composites: Water Treatment Applications. In: Vithanage, M., Lazzara, G., Rajapaksha, A.U. (eds) Clay Composites. Advances in Material Research and Technology. Springer, Singapore. https://doi.org/10.1007/978-981-99-2544-5_11
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DOI: https://doi.org/10.1007/978-981-99-2544-5_11
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