Abstract
Raman and EELS are able to discriminate vibrations due to non-bond interaction at terahertz frequencies. Transition of vibration frequencies at the 101 meV indicates the conversion of dipole formation due to O1−, O2−, and the weakened interaction by H-bond-like formation. The events of O−1 formation, O−2 sp-hybrid bonding, non-bonding lone pair, antibonding dipole, and the H-like bonding are essential in the electronic process of oxidation, and in the reactions involving other electronegative additives as well.
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Sun, C.Q. (2014). EELS and Raman: Nonbond Interactions. In: Relaxation of the Chemical Bond. Springer Series in Chemical Physics, vol 108. Springer, Singapore. https://doi.org/10.1007/978-981-4585-21-7_6
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DOI: https://doi.org/10.1007/978-981-4585-21-7_6
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